Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Coexistence of magnetic and electric orderings in the metal-formate frameworks of [NH4][M(HCOO)3].

Literature DB >> 21870842

Coexistence of magnetic and electric orderings in the metal-formate frameworks of [NH4][M(HCOO)3].

Guan-Cheng Xu¹, Wen Zhang, Xiao-Ming Ma, Yi-Hong Chen, Li Zhang, Hong-Ling Cai, Zhe-Ming Wang, Ren-Gen Xiong, Song Gao.

Abstract

A family of three-dimensional chiral metal-formate frameworks of [NH(4)][M(HCOO)(3)] (M = Mn, Fe, Co, Ni, and Zn) displays paraelectric to ferroelectric phase transitions between 191 and 254 K, triggered by disorder-order transitions of NH(4)(+) cations and their displacement within the framework channels, combined with spin-canted antiferromagnetic ordering within 8-30 K for the magnetic members, providing a new class of metal-organic frameworks showing the coexistence of magnetic and electric orderings.

Entities: Chemical

Mesh：

Substances：

Year: 2011 PMID： 21870842 DOI： 10.1021/ja206891q

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

Keyword Cloud
Cited

23 in total

1. NH4FeCl2(HCOO): synthesis, structure, and magnetism of a novel low-dimensional magnetic material.

Authors: Joshua T Greenfield; Saeed Kamali; Nezhueyotl Izquierdo; Michael Chen; Kirill Kovnir
Journal: Inorg Chem Date: 2014-02-26 Impact factor: 5.165

2. Metal-organic frameworks as a tunable platform for designing functional molecular materials.

Authors: Cheng Wang; Demin Liu; Wenbin Lin
Journal: J Am Chem Soc Date: 2013-08-28 Impact factor: 15.419

3. An extended Tolerance Factor approach for organic-inorganic perovskites.

Authors: Gregor Kieslich; Shijing Sun; Anthony K Cheetham
Journal: Chem Sci Date: 2015-04-14 Impact factor: 9.825

4. Uniaxial Negative Thermal Expansion and Mechanical Properties of a Zinc-Formate Framework.

Authors: Hongqiang Gao; Wenjuan Wei; Yizhang Li; Rong Wu; Guoqiang Feng; Wei Li
Journal: Materials (Basel) Date: 2017-02-10 Impact factor: 3.623

5. Dielectric and ferroelectric sensing based on molecular recognition in Cu(1,10-phenlothroline)₂SeO₄·(diol) systems.

Authors: Heng-Yun Ye; Wei-Qiang Liao; Qionghua Zhou; Yi Zhang; Jinlan Wang; Yu-Meng You; Jin-Yun Wang; Zhong-Ning Chen; Peng-Fei Li; Da-Wei Fu; Songping D Huang; Ren-Gen Xiong
Journal: Nat Commun Date: 2017-02-20 Impact factor: 14.919

6. Thermo- and light-triggered reversible interconversion of dysprosium-anthracene complexes and their responsive optical, magnetic and dielectric properties.

Authors: Xin-Da Huang; Ge-Hua Wen; Song-Song Bao; Jia-Ge Jia; Li-Min Zheng
Journal: Chem Sci Date: 2020-11-11 Impact factor: 9.825

Coexistence of magnetic and electric orderings in the metal-formate frameworks of [NH4][M(HCOO)3].

1. NH4FeCl2(HCOO): synthesis, structure, and magnetism of a novel low-dimensional magnetic material.

2. Metal-organic frameworks as a tunable platform for designing functional molecular materials.

3. An extended Tolerance Factor approach for organic-inorganic perovskites.

4. Uniaxial Negative Thermal Expansion and Mechanical Properties of a Zinc-Formate Framework.

5. Dielectric and ferroelectric sensing based on molecular recognition in Cu(1,10-phenlothroline)₂SeO₄·(diol) systems.

6. Thermo- and light-triggered reversible interconversion of dysprosium-anthracene complexes and their responsive optical, magnetic and dielectric properties.

7. Order-disorder transition of a rigid cage cation embedded in a cubic perovskite.

8. Acoustic Properties of Metal-Organic Frameworks.

9. Coexistence of magnetic and electric orderings in a divalent Cr²⁺-based multiaxial molecular ferroelectric.

10. Magnetically-induced ferroelectricity in the (ND4)2[FeCl5(D2O)] molecular compound.