| Literature DB >> 21861490 |
Katsuhiko Tomooka1, Masaki Suzuki, Maki Shimada, Runyan Ni, Kazuhiro Uehara.
Abstract
Intermolecular reactions of planar chiral 9-membered diallylic amides provide a variety of bicyclic compounds with central chiralities in a stereospecific fashion with high group selectivity. Lewis-acid-promoted intramolecular reactions of the obtained bicyclic compounds provide transannular products in a stereospecific fashion. Furthermore, a direct transannular reaction of diallylic amide involving sequential intermolecular-intramolecular reactions has been developed.Entities:
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Year: 2011 PMID: 21861490 DOI: 10.1021/ol202009x
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005