Literature DB >> 21860861

Phosphirenium-borate zwitterion: formation in the 1,1-carboboration reaction of phosphinylalkynes.

Olga Ekkert1, Gerald Kehr, Roland Fröhlich, Gerhard Erker.   

Abstract

Reaction of the acetylene Mes(2)P-C≡C-Ar with B(C(6)F(5))(3) at rt gives a zwitterionic phosphirenium product, which reacts further at >100 °C to complete the 1,1-carboboration reaction. This journal is © The Royal Society of Chemistry 2011

Entities:  

Year:  2011        PMID: 21860861     DOI: 10.1039/c1cc13008k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Advanced 1,1-carboboration reactions with pentafluorophenylboranes.

Authors:  Gerald Kehr; Gerhard Erker
Journal:  Chem Sci       Date:  2015-10-08       Impact factor: 9.825

  1 in total

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