| Literature DB >> 21848326 |
Tetsuro Murahashi1, Kohei Takase, Masa-aki Oka, Sensuke Ogoshi.
Abstract
We report the oxidative dinuclear addition of a Pd(I)-Pd(I) bond to arenes. The oxidative dinuclear addition products, which have a bi-π-allyl-type arene dipalladium(II) structure, were obtained from [2.2]paracyclophane, anthracene, tetracene, and pentacene. A systematic study of the reaction of [Pd(2)(CH(3)CN)(6)][BF(4)](2) with benzene and polyacenes showed that the larger polyacenes, tetracene and pentacene, afforded the oxidative dinuclear addition products, while benzene, naphthalene, and anthracene gave the π-sandwich Pd(I)-Pd(I) complexes.Entities:
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Year: 2011 PMID： 21848326 DOI： 10.1021/ja206076u
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419