Intense 2.7 μm and broadband 2.0 μm emission from diode-pumped Er3+/Tm3+/Ho(3+)-doped fluorophosphate glass.

This Letter reports intense emission at 2.7 μm and broadband emission at 2.0 μm from Er(3+)/Tm(3+)/Ho(3+)-doped fluorophosphate glass. The fluorescence characteristics and energy transfer upon excitation of a conventional 980 nm laser diode are investigated. Based on the fluorescence spectra and lifetime measurement, the effect of Tm(3+) and Ho(3+) ions on intense 2.7 μm emission in fluorophosphate glass is demonstrated. It is also found that the effective bandwidth of 2.0 μm emission due to Tm(3+) and Ho(3+) ions can reach as high as 196 nm. These results indicate that the advantageous spectroscopic characteristics of Er(3+)/Tm(3+)/Ho(3+) triply doped fluorophosphate glass together with the outstanding thermal properties may become an attractive host for the mid-IR solid state lasers.