Literature DB >> 21842836

Nickel-catalyzed tetramerization of alkynes: synthesis and structure of octatetraenes.

Tsun-Cheng Wu1, Jheng-Jhih Chen, Yao-Ting Wu.   

Abstract

In the presence of a catalytic system comprised of NiBr(2)(dppe) and Zn, arylacetylenes undergo tetramerization to form linear octatetraenes, generally in good to excellent yields. The structure of the coupling products was verified by X-ray crystallography.
© 2011 American Chemical Society

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Year:  2011        PMID: 21842836     DOI: 10.1021/ol201814q

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Mechanistic Versatility at Ir(PSiP) Pincer Catalysts: Triflate Proton Shuttling from 2-Butyne to Diene and [3]Dendralene Motifs.

Authors:  José L Andrés; Elizabeth Suárez; Marta Martín; Eduardo Sola
Journal:  Organometallics       Date:  2022-09-13       Impact factor: 3.837

2.  Stereoselective synthesis of pentasubstituted 1,3-dienes via Ni-catalyzed reductive coupling of unsymmetrical internal alkynes.

Authors:  Zhijun Zhou; Jiachang Chen; Herong Chen; Wangqing Kong
Journal:  Chem Sci       Date:  2020-09-10       Impact factor: 9.825

3.  Allylic alcohol synthesis by Ni-catalyzed direct and selective coupling of alkynes and methanol.

Authors:  Herong Chen; Zhijun Zhou; Wangqing Kong
Journal:  Chem Sci       Date:  2021-06-07       Impact factor: 9.825

  3 in total

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