Literature DB >> 21838273

One-step preparation of functionalized (E)-vinylsilanes from aldehydes.

Diane S W Lim1, Edward A Anderson.   

Abstract

Functionalized (E)-vinylsilanes have been prepared in one step from a wide range of aldehydes, via a chromium(II)-mediated olefination with novel dihalomethylsilane reagents, in moderate to excellent yields and with excellent stereoselectivity.
© 2011 American Chemical Society

Entities:  

Mesh：

Substances：

Year:  2011        PMID： 21838273     DOI： 10.1021/ol201833u

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Preparation of allyl and vinyl silanes by the palladium-catalyzed silylation of terminal olefins: a silyl-Heck reaction.

Authors:  Jesse R McAtee; Sara E S Martin; Derek T Ahneman; Keywan A Johnson; Donald A Watson
Journal:  Angew Chem Int Ed Engl       Date:  2012-03-01       Impact factor: 15.336

2.  Activation of Si-Si Bonds for Copper(I)-Catalyzed Conjugate Silylation.

Authors:  Laura Iannazzo; Gary A Molander
Journal:  European J Org Chem       Date:  2012-09

3.  Preparation of vinyl silyl ethers and disiloxanes via the silyl-Heck reaction of silyl ditriflates.

Authors:  Sara E S Martin; Donald A Watson
Journal:  J Am Chem Soc       Date:  2013-08-28       Impact factor: 15.419

4.  Synthesis and purification of iodoaziridines involving quantitative selection of the optimal stationary phase for chromatography.

Authors:  Tom Boultwood; Dominic P Affron; James A Bull
Journal:  J Vis Exp       Date:  2014-05-16       Impact factor: 1.355

5.  (Z)-Selective Takai olefination of salicylaldehydes.

Authors:  Stephen M Geddis; Caroline E Hagerman; Warren R J D Galloway; Hannah F Sore; Jonathan M Goodman; David R Spring
Journal:  Beilstein J Org Chem       Date:  2017-02-20       Impact factor: 2.883

6.  Synthesis of cis-C-iodo-N-tosyl-aziridines using diiodomethyllithium: reaction optimization, product scope and stability, and a protocol for selection of stationary phase for chromatography.

Authors:  Tom Boultwood; Dominic P Affron; Aaron D Trowbridge; James A Bull
Journal:  J Org Chem       Date:  2013-06-18       Impact factor: 4.354
  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.