2-(4-Methyl-phen-yl)benzonitrile.

In the title compound, C(14)H(11)N, the dihedral angle between the mean planes of the two benzene rings is 44.6 (7)°. The crystal packing is stabilized by weak inter-molecular π-π stacking inter-actions, the centroid-centroid distances being 3.8172 (12) and 3.9349 (12) Å.

Related literature

For the synthesis of pharmaceutically active compounds, see: Gillis & Markham (1997 ▶); Markham & Goa (1997 ▶). For related structures, see: Gerkin (1998 ▶); Narasegowda et al. (2005 ▶); Yathirajan et al. (2005 ▶). For standard bond lengths, see Allen et al. (1987 ▶).

Experimental

Crystal data

C14H11N

M = 193.24

Orthorhombic,

a = 7.6726 (4) Å

b = 11.4037 (5) Å

c = 12.2426 (5) Å

V = 1071.18 (9) Å3

Z = 4

Mo Kα radiation

μ = 0.07 mm−1

T = 173 K

0.30 × 0.25 × 0.20 mm

Data collection

Oxford Diffraction Xcalibur Eos Gemini diffractometer

Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2010 ▶) T min = 0.979, T max = 0.986

3786 measured reflections

1546 independent reflections

1322 reflections with I > 2σ(I)

R int = 0.017

Refinement

R[F 2 > 2σ(F 2)] = 0.040

wR(F 2) = 0.105

S = 1.07

1546 reflections

137 parameters

H-atom parameters constrained

Δρmax = 0.22 e Å−3

Δρmin = −0.14 e Å−3

Data collection: CrysAlis PRO (Oxford Diffraction, 2010 ▶); cell refinement: CrysAlis PRO; data reduction: CrysAlis RED (Oxford Diffraction, 2010 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S160053681101988X/xu5222sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S160053681101988X/xu5222Isup2.hkl

Supplementary material file. DOI: 10.1107/S160053681101988X/xu5222Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C14H11N	F(000) = 408
Mr = 193.24	Dx = 1.198 Mg m−3
Orthorhombic, P212121	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2ab	Cell parameters from 2201 reflections
a = 7.6726 (4) Å	θ = 3.3–32.3°
b = 11.4037 (5) Å	µ = 0.07 mm−1
c = 12.2426 (5) Å	T = 173 K
V = 1071.18 (9) Å3	Block, colorless
Z = 4	0.30 × 0.25 × 0.20 mm

Oxford Diffraction Xcalibur Eos Gemini diffractometer	1546 independent reflections
Radiation source: Enhance (Mo) X-ray Source	1322 reflections with I > 2σ(I)
graphite	Rint = 0.017
Detector resolution: 16.1500 pixels mm-1	θmax = 28.3°, θmin = 3.3°
ω scans	h = −10→10
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2010)	k = −7→15
Tmin = 0.979, Tmax = 0.986	l = −16→16
3786 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.040	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.105	H-atom parameters constrained
S = 1.07	w = 1/[σ2(Fo2) + (0.0516P)2 + 0.1272P] where P = (Fo2 + 2Fc2)/3
1546 reflections	(Δ/σ)max = 0.008
137 parameters	Δρmax = 0.22 e Å−3
0 restraints	Δρmin = −0.14 e Å−3

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
N1	0.2954 (3)	0.53397 (15)	0.51932 (16)	0.0599 (5)
C1	0.2409 (3)	0.45620 (16)	0.56640 (15)	0.0403 (4)
C2	0.1730 (2)	0.36058 (15)	0.62994 (15)	0.0350 (4)
C3	0.1706 (3)	0.37476 (16)	0.74343 (15)	0.0413 (4)
H3A	0.2117	0.4456	0.7751	0.050*
C4	0.1091 (3)	0.28649 (19)	0.80918 (16)	0.0484 (5)
H4A	0.1060	0.2963	0.8862	0.058*
C5	0.0518 (3)	0.1835 (2)	0.76255 (16)	0.0498 (5)
H5A	0.0090	0.1223	0.8079	0.060*
C6	0.0559 (3)	0.16831 (18)	0.65050 (16)	0.0427 (5)
H6A	0.0171	0.0962	0.6202	0.051*
C7	0.1155 (2)	0.25620 (15)	0.58127 (13)	0.0331 (4)
C8	0.1185 (2)	0.23705 (15)	0.46123 (13)	0.0333 (4)
C9	0.1780 (3)	0.13095 (16)	0.41890 (16)	0.0412 (4)
H9A	0.2178	0.0715	0.4672	0.049*
C10	0.1798 (3)	0.11109 (17)	0.30733 (16)	0.0459 (5)
H10A	0.2211	0.0381	0.2804	0.055*
C11	0.1230 (3)	0.19495 (18)	0.23447 (15)	0.0441 (5)
C12	0.0627 (3)	0.30048 (18)	0.27609 (16)	0.0432 (5)
H12A	0.0224	0.3595	0.2275	0.052*
C13	0.0604 (2)	0.32112 (16)	0.38739 (15)	0.0383 (4)
H13A	0.0183	0.3941	0.4139	0.046*
C14	0.1238 (4)	0.1727 (2)	0.11270 (17)	0.0671 (7)
H14A	0.1788	0.2391	0.0753	0.101*
H14B	0.0038	0.1637	0.0867	0.101*
H14C	0.1895	0.1009	0.0972	0.101*

	U11	U22	U33	U12	U13	U23
N1	0.0834 (14)	0.0413 (9)	0.0550 (10)	−0.0116 (10)	0.0026 (11)	0.0037 (8)
C1	0.0460 (10)	0.0356 (8)	0.0393 (9)	0.0018 (9)	−0.0010 (9)	−0.0051 (8)
C2	0.0344 (9)	0.0356 (8)	0.0349 (8)	0.0027 (8)	0.0011 (7)	0.0004 (7)
C3	0.0423 (10)	0.0424 (9)	0.0391 (10)	0.0009 (9)	−0.0028 (8)	−0.0043 (8)
C4	0.0542 (12)	0.0583 (12)	0.0328 (8)	−0.0027 (11)	0.0002 (9)	0.0020 (9)
C5	0.0559 (12)	0.0539 (11)	0.0395 (9)	−0.0100 (11)	0.0019 (9)	0.0107 (9)
C6	0.0454 (10)	0.0414 (9)	0.0414 (10)	−0.0099 (9)	−0.0005 (8)	0.0031 (8)
C7	0.0298 (8)	0.0367 (8)	0.0329 (8)	0.0023 (8)	−0.0003 (7)	0.0009 (7)
C8	0.0303 (8)	0.0358 (8)	0.0337 (8)	−0.0045 (7)	−0.0004 (7)	0.0000 (7)
C9	0.0448 (10)	0.0347 (9)	0.0441 (10)	−0.0005 (8)	−0.0020 (9)	0.0007 (8)
C10	0.0526 (11)	0.0380 (9)	0.0472 (11)	−0.0031 (9)	0.0032 (10)	−0.0092 (8)
C11	0.0489 (11)	0.0468 (10)	0.0366 (8)	−0.0151 (10)	0.0036 (9)	−0.0039 (8)
C12	0.0477 (11)	0.0449 (10)	0.0370 (8)	−0.0057 (9)	−0.0049 (8)	0.0056 (8)
C13	0.0391 (9)	0.0359 (8)	0.0397 (9)	0.0017 (8)	−0.0019 (8)	−0.0009 (8)
C14	0.0991 (19)	0.0644 (13)	0.0378 (10)	−0.0186 (16)	0.0036 (13)	−0.0095 (11)

N1—C1	1.137 (2)	C8—C9	1.393 (2)
C1—C2	1.437 (2)	C9—C10	1.385 (3)
C2—C3	1.399 (2)	C9—H9A	0.9500
C2—C7	1.402 (2)	C10—C11	1.378 (3)
C3—C4	1.373 (3)	C10—H10A	0.9500
C3—H3A	0.9500	C11—C12	1.386 (3)
C4—C5	1.378 (3)	C11—C14	1.512 (3)
C4—H4A	0.9500	C12—C13	1.383 (3)
C5—C6	1.383 (3)	C12—H12A	0.9500
C5—H5A	0.9500	C13—H13A	0.9500
C6—C7	1.390 (2)	C14—H14A	0.9800
C6—H6A	0.9500	C14—H14B	0.9800
C7—C8	1.486 (2)	C14—H14C	0.9800
C8—C13	1.391 (2)
N1—C1—C2	177.67 (19)	C10—C9—C8	120.81 (17)
C3—C2—C7	121.07 (17)	C10—C9—H9A	119.6
C3—C2—C1	117.04 (16)	C8—C9—H9A	119.6
C7—C2—C1	121.87 (15)	C11—C10—C9	121.45 (18)
C4—C3—C2	120.14 (18)	C11—C10—H10A	119.3
C4—C3—H3A	119.9	C9—C10—H10A	119.3
C2—C3—H3A	119.9	C10—C11—C12	118.03 (17)
C3—C4—C5	119.46 (17)	C10—C11—C14	121.3 (2)
C3—C4—H4A	120.3	C12—C11—C14	120.6 (2)
C5—C4—H4A	120.3	C13—C12—C11	120.95 (18)
C4—C5—C6	120.7 (2)	C13—C12—H12A	119.5
C4—C5—H5A	119.6	C11—C12—H12A	119.5
C6—C5—H5A	119.6	C12—C13—C8	121.25 (17)
C5—C6—C7	121.45 (19)	C12—C13—H13A	119.4
C5—C6—H6A	119.3	C8—C13—H13A	119.4
C7—C6—H6A	119.3	C11—C14—H14A	109.5
C6—C7—C2	117.15 (15)	C11—C14—H14B	109.5
C6—C7—C8	120.14 (16)	H14A—C14—H14B	109.5
C2—C7—C8	122.70 (15)	C11—C14—H14C	109.5
C13—C8—C9	117.51 (16)	H14A—C14—H14C	109.5
C13—C8—C7	122.45 (16)	H14B—C14—H14C	109.5
C9—C8—C7	120.03 (16)
C7—C2—C3—C4	−1.0 (3)	C6—C7—C8—C9	−43.5 (2)
C1—C2—C3—C4	−179.36 (18)	C2—C7—C8—C9	135.8 (2)
C2—C3—C4—C5	0.8 (3)	C13—C8—C9—C10	0.4 (3)
C3—C4—C5—C6	0.1 (3)	C7—C8—C9—C10	179.27 (18)
C4—C5—C6—C7	−0.8 (3)	C8—C9—C10—C11	−0.1 (3)
C5—C6—C7—C2	0.6 (3)	C9—C10—C11—C12	−0.3 (3)
C5—C6—C7—C8	179.9 (2)	C9—C10—C11—C14	−179.5 (2)
C3—C2—C7—C6	0.3 (3)	C10—C11—C12—C13	0.3 (3)
C1—C2—C7—C6	178.58 (18)	C14—C11—C12—C13	179.5 (2)
C3—C2—C7—C8	−179.05 (18)	C11—C12—C13—C8	0.1 (3)
C1—C2—C7—C8	−0.7 (3)	C9—C8—C13—C12	−0.5 (3)
C6—C7—C8—C13	135.2 (2)	C7—C8—C13—C12	−179.24 (17)
C2—C7—C8—C13	−45.5 (3)

CgI···CgJ	Cg···Cg (Å)	CgI Perp (Å)	Cgj Perp (Å)
Cg1···Cg2i	3.8172 (12)	3.5763 (8)	-3.5789 (8)
Cg2···Cg1ii	3.9349 (12)	-3.5230 (8)	3.5154 (8)