2-(4-Acetamido-benzene-sulfonamido)-benzoic acid.

In the title compound, C(15)H(14)N(2)O(5)S, two similar mol-ecules comprise the asymmetric unit, which are linked by strong inter-molecular C-H⋯π inter-actions. Both mol-ecules are bent, with dihedral angles of 71.94 (16) and 74.62 (15)° between the benzene rings. An intra-molecular N-H⋯O hydrogen bond occurs in each mol-ecule. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

Related literature

For our previous studies on sulfonamide derivatives, see: Khan et al. (2011 ▶); Sharif et al. (2010 ▶). For background to the pharmacological use of sulfonamides, see: Korolkovas (1988 ▶); Mandell & Sande (1992 ▶).

Experimental

Crystal data

C15H14N2O5S

M = 334.34

Monoclinic,

a = 9.3721 (19) Å

b = 13.036 (3) Å

c = 13.132 (3) Å

β = 109.47 (3)°

V = 1512.7 (5) Å3

Z = 4

Mo Kα radiation

μ = 0.24 mm−1

T = 296 K

0.25 × 0.12 × 0.09 mm

Data collection

Bruker APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2007 ▶) T min = 0.92, T max = 0.931

2926 measured reflections

2926 independent reflections

1470 reflections with I > 2σ(I)

Refinement

R[F 2 > 2σ(F 2)] = 0.045

wR(F 2) = 0.092

S = 0.82

2926 reflections

415 parameters

1 restraint

H-atom parameters constrained

Δρmax = 0.26 e Å−3

Δρmin = −0.24 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX publication routines (Farrugia, 1999 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536811020307/tk2747sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811020307/tk2747Isup2.hkl

Supplementary material file. DOI: 10.1107/S1600536811020307/tk2747Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C15H14N2O5S	F(000) = 696
Mr = 334.34	Dx = 1.468 Mg m−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2yb	Cell parameters from 1295 reflections
a = 9.3721 (19) Å	θ = 2.8–18.7°
b = 13.036 (3) Å	µ = 0.24 mm−1
c = 13.132 (3) Å	T = 296 K
β = 109.47 (3)°	Block, violet
V = 1512.7 (5) Å3	0.25 × 0.12 × 0.09 mm
Z = 4

Bruker APEXII CCD diffractometer	2926 independent reflections
graphite	1470 reflections with I > 2σ(I)
φ and ω scans	θmax = 25.5°, θmin = 2.8°
Absorption correction: multi-scan (SADABS; Bruker, 2007)	h = −11→10
Tmin = 0.92, Tmax = 0.931	k = 0→15
2926 measured reflections	l = 0→15

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.045	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.092	H-atom parameters constrained
S = 0.82	w = 1/[σ2(Fo2) + (0.0338P)2] where P = (Fo2 + 2Fc2)/3
2926 reflections	(Δ/σ)max < 0.001
415 parameters	Δρmax = 0.26 e Å−3
1 restraint	Δρmin = −0.24 e Å−3

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.9116 (7)	0.1951 (5)	0.4462 (5)	0.0489 (17)
C2	0.8856 (6)	0.1876 (4)	0.3361 (5)	0.0378 (15)
C3	0.9664 (8)	0.2491 (5)	0.2895 (6)	0.069 (2)
H3	0.9489	0.2433	0.2157	0.082*
C4	1.0705 (8)	0.3179 (6)	0.3474 (7)	0.068 (2)
H4	1.124	0.3585	0.3143	0.081*
C5	1.0948 (8)	0.3260 (6)	0.4565 (7)	0.078 (2)
H5	1.1645	0.3736	0.4972	0.094*
C6	1.0181 (8)	0.2652 (6)	0.5064 (6)	0.0547 (18)
H6	1.0374	0.271	0.5804	0.066*
C7	0.8274 (7)	0.1297 (5)	0.4990 (5)	0.0444 (16)
O8	0.7297 (6)	0.0692 (4)	0.4533 (4)	0.0761 (16)
O9	0.8716 (5)	0.1415 (4)	0.6050 (4)	0.0753 (14)
H9	0.8211	0.1043	0.63	0.113*
N10	0.7746 (6)	0.1191 (4)	0.2728 (4)	0.0556 (15)
H10	0.7657	0.0613	0.3017	0.067*
S11	0.6629 (2)	0.13965 (13)	0.15141 (13)	0.0496 (5)
O12	0.5537 (5)	0.0600 (3)	0.1345 (3)	0.0650 (13)
O13	0.7415 (4)	0.1479 (3)	0.0766 (3)	0.0601 (12)
C14	0.5771 (6)	0.2586 (5)	0.1545 (5)	0.0409 (16)
C15	0.5660 (7)	0.3302 (5)	0.0747 (5)	0.0505 (18)
H15	0.6111	0.3183	0.0225	0.061*
C16	0.4882 (7)	0.4181 (5)	0.0734 (5)	0.0523 (19)
H16	0.48	0.4663	0.0196	0.063*
C17	0.4204 (6)	0.4379 (5)	0.1504 (5)	0.0374 (15)
C18	0.4315 (7)	0.3678 (5)	0.2282 (5)	0.0485 (18)
H18	0.3873	0.3809	0.2806	0.058*
C19	0.5082 (7)	0.2768 (5)	0.2307 (5)	0.0479 (17)
H19	0.5134	0.228	0.2834	0.057*
N20	0.3395 (5)	0.5312 (4)	0.1386 (4)	0.0434 (13)
H20	0.3362	0.5668	0.0827	0.052*
C21	0.2673 (6)	0.5729 (5)	0.2010 (5)	0.0411 (16)
O22	0.2672 (5)	0.5316 (3)	0.2864 (3)	0.0580 (13)
C23	0.1884 (7)	0.6728 (4)	0.1635 (5)	0.059 (2)
H23A	0.2015	0.6925	0.0967	0.088*
H23B	0.2307	0.7246	0.217	0.088*
H23C	0.0825	0.6653	0.1527	0.088*
C24	−0.0124 (7)	0.9059 (5)	0.1004 (5)	0.0449 (16)
C25	0.0910 (7)	0.9800 (5)	0.1592 (5)	0.0437 (17)
C26	0.1722 (7)	1.0380 (5)	0.1075 (6)	0.061 (2)
H26	0.2361	1.09	0.1449	0.074*
C27	0.1581 (7)	1.0185 (6)	0.0021 (6)	0.064 (2)
H27	0.2137	1.0569	−0.0312	0.077*
C28	0.0617 (8)	0.9422 (6)	−0.0555 (6)	0.071 (2)
H28	0.0553	0.9272	−0.1261	0.085*
C29	−0.0240 (7)	0.8892 (5)	−0.0065 (6)	0.0510 (18)
H29	−0.0924	0.8405	−0.0463	0.061*
C30	−0.1013 (7)	0.8458 (5)	0.1504 (6)	0.0479 (17)
O31	−0.1843 (5)	0.7725 (4)	0.0872 (4)	0.0677 (14)
H31	−0.2313	0.7413	0.12	0.101*
O32	−0.1066 (5)	0.8583 (4)	0.2407 (4)	0.0691 (15)
N33	0.1094 (5)	0.9963 (4)	0.2685 (4)	0.0555 (15)
H33	0.0295	0.9965	0.2869	0.067*
S34	0.2731 (2)	1.01499 (13)	0.36347 (14)	0.0574 (5)
O35	0.3439 (5)	1.1036 (3)	0.3377 (4)	0.0690 (14)
O36	0.2365 (5)	1.0137 (4)	0.4614 (3)	0.0713 (13)
C37	0.3874 (7)	0.9084 (5)	0.3622 (5)	0.0471 (17)
C38	0.4644 (7)	0.9058 (5)	0.2911 (6)	0.059 (2)
H38	0.4576	0.9616	0.2457	0.07*
C39	0.5520 (7)	0.8235 (6)	0.2842 (6)	0.0584 (19)
H39	0.6053	0.8234	0.2358	0.07*
C40	0.5584 (7)	0.7408 (5)	0.3516 (5)	0.0498 (18)
C41	0.4833 (7)	0.7435 (5)	0.4263 (5)	0.0540 (19)
H41	0.4912	0.6889	0.4733	0.065*
C42	0.3979 (7)	0.8271 (5)	0.4301 (5)	0.0530 (18)
H42	0.3462	0.8289	0.4794	0.064*
N43	0.6463 (5)	0.6529 (4)	0.3513 (4)	0.0563 (15)
H43	0.6701	0.6161	0.4089	0.068*
C44	0.6993 (7)	0.6179 (6)	0.2710 (6)	0.0548 (19)
O45	0.6655 (5)	0.6604 (4)	0.1829 (4)	0.0682 (14)
C46	0.7926 (7)	0.5216 (6)	0.2971 (5)	0.071 (2)
H46A	0.8045	0.5004	0.3695	0.106*
H46B	0.8903	0.5345	0.291	0.106*
H46C	0.7426	0.4684	0.2475	0.106*

	U11	U22	U33	U12	U13	U23
C1	0.055 (4)	0.049 (5)	0.045 (4)	0.016 (4)	0.019 (4)	0.011 (4)
C2	0.038 (4)	0.027 (4)	0.051 (4)	0.014 (3)	0.019 (4)	0.012 (4)
C3	0.077 (6)	0.060 (5)	0.071 (6)	−0.005 (4)	0.027 (5)	0.003 (4)
C4	0.050 (5)	0.063 (6)	0.081 (6)	−0.001 (4)	0.009 (5)	0.017 (5)
C5	0.063 (6)	0.059 (6)	0.094 (7)	−0.003 (4)	0.002 (5)	0.006 (5)
C6	0.049 (4)	0.051 (5)	0.057 (5)	−0.004 (4)	0.007 (4)	0.004 (4)
C7	0.050 (4)	0.048 (4)	0.035 (4)	0.010 (4)	0.013 (3)	0.004 (4)
O8	0.091 (4)	0.081 (4)	0.056 (3)	−0.030 (3)	0.023 (3)	0.005 (3)
O9	0.083 (4)	0.088 (4)	0.054 (3)	−0.007 (3)	0.022 (3)	0.003 (3)
N10	0.081 (4)	0.034 (3)	0.046 (3)	0.006 (3)	0.014 (3)	0.008 (3)
S11	0.0681 (12)	0.0425 (11)	0.0387 (10)	−0.0015 (10)	0.0186 (9)	−0.0069 (9)
O12	0.101 (4)	0.038 (3)	0.063 (3)	−0.023 (3)	0.038 (3)	−0.013 (2)
O13	0.079 (3)	0.056 (3)	0.057 (3)	−0.001 (3)	0.038 (3)	−0.010 (3)
C14	0.044 (4)	0.036 (4)	0.041 (4)	0.002 (3)	0.011 (3)	0.001 (3)
C15	0.073 (5)	0.053 (5)	0.038 (4)	0.003 (4)	0.035 (4)	0.007 (4)
C16	0.065 (5)	0.054 (5)	0.040 (4)	0.011 (4)	0.020 (4)	0.015 (3)
C17	0.041 (4)	0.033 (4)	0.039 (4)	0.001 (3)	0.014 (3)	0.002 (3)
C18	0.055 (4)	0.052 (5)	0.051 (4)	0.010 (3)	0.033 (4)	0.018 (4)
C19	0.064 (4)	0.052 (5)	0.033 (4)	−0.004 (4)	0.023 (4)	0.013 (4)
N20	0.051 (3)	0.048 (4)	0.037 (3)	0.004 (3)	0.023 (3)	0.012 (3)
C21	0.043 (4)	0.042 (4)	0.034 (4)	−0.011 (3)	0.006 (3)	−0.005 (3)
O22	0.077 (3)	0.058 (3)	0.051 (3)	0.004 (3)	0.036 (3)	0.001 (3)
C23	0.069 (5)	0.052 (5)	0.052 (4)	0.014 (4)	0.017 (4)	−0.008 (4)
C24	0.043 (4)	0.048 (4)	0.045 (4)	0.004 (3)	0.016 (3)	0.011 (4)
C25	0.046 (4)	0.048 (5)	0.042 (4)	0.013 (3)	0.020 (4)	0.009 (3)
C26	0.065 (5)	0.061 (5)	0.058 (5)	−0.001 (4)	0.022 (4)	−0.004 (4)
C27	0.065 (5)	0.064 (6)	0.063 (5)	0.008 (4)	0.023 (4)	0.026 (5)
C28	0.068 (5)	0.089 (7)	0.053 (5)	−0.002 (5)	0.017 (4)	0.008 (5)
C29	0.055 (5)	0.056 (5)	0.043 (4)	0.007 (4)	0.017 (4)	0.004 (4)
C30	0.052 (5)	0.046 (5)	0.048 (5)	0.013 (4)	0.021 (4)	0.010 (4)
O31	0.071 (3)	0.070 (3)	0.064 (3)	−0.015 (3)	0.025 (3)	−0.010 (3)
O32	0.080 (4)	0.076 (4)	0.065 (3)	−0.010 (3)	0.041 (3)	0.000 (3)
N33	0.051 (3)	0.070 (4)	0.046 (3)	0.009 (3)	0.016 (3)	−0.011 (3)
S34	0.0712 (13)	0.0507 (13)	0.0499 (11)	−0.0118 (10)	0.0194 (10)	−0.0137 (10)
O35	0.088 (4)	0.042 (3)	0.079 (3)	−0.022 (3)	0.029 (3)	−0.008 (3)
O36	0.101 (4)	0.064 (3)	0.056 (3)	−0.014 (3)	0.037 (3)	−0.017 (3)
C37	0.055 (5)	0.047 (5)	0.038 (4)	−0.011 (3)	0.013 (4)	−0.002 (4)
C38	0.064 (5)	0.052 (5)	0.062 (5)	−0.010 (4)	0.024 (4)	0.024 (4)
C39	0.052 (5)	0.067 (5)	0.062 (5)	0.007 (4)	0.027 (4)	0.026 (4)
C40	0.041 (4)	0.065 (5)	0.045 (4)	−0.001 (4)	0.015 (4)	0.008 (4)
C41	0.058 (5)	0.065 (6)	0.038 (4)	−0.002 (4)	0.014 (4)	0.010 (4)
C42	0.063 (5)	0.059 (5)	0.042 (4)	−0.004 (4)	0.025 (4)	−0.012 (4)
N43	0.058 (4)	0.062 (4)	0.045 (3)	0.003 (3)	0.012 (3)	0.019 (3)
C44	0.047 (4)	0.066 (6)	0.048 (5)	−0.021 (4)	0.013 (4)	−0.005 (4)
O45	0.098 (4)	0.065 (4)	0.050 (3)	−0.020 (3)	0.036 (3)	−0.006 (3)
C46	0.057 (5)	0.084 (6)	0.066 (5)	0.004 (5)	0.014 (4)	−0.015 (5)

C1—C2	1.387 (8)	C24—C29	1.389 (8)
C1—C6	1.389 (9)	C24—C25	1.403 (8)
C1—C7	1.482 (8)	C24—C30	1.450 (8)
C2—C3	1.379 (8)	C25—C26	1.399 (8)
C2—N10	1.412 (7)	C25—N33	1.402 (7)
C3—C4	1.356 (9)	C26—C27	1.370 (8)
C3—H3	0.93	C26—H26	0.93
C4—C5	1.378 (9)	C27—C28	1.386 (9)
C4—H4	0.93	C27—H27	0.93
C5—C6	1.374 (9)	C28—C29	1.372 (9)
C5—H5	0.93	C28—H28	0.93
C6—H6	0.93	C29—H29	0.93
C7—O8	1.206 (7)	C30—O32	1.215 (7)
C7—O9	1.322 (7)	C30—O31	1.332 (8)
O9—H9	0.82	O31—H31	0.82
N10—S11	1.611 (5)	N33—S34	1.641 (5)
N10—H10	0.86	N33—H33	0.86
S11—O13	1.415 (4)	S34—O35	1.429 (4)
S11—O12	1.423 (4)	S34—O36	1.438 (4)
S11—C14	1.754 (6)	S34—C37	1.758 (7)
C14—C19	1.380 (7)	C37—C38	1.358 (8)
C14—C15	1.382 (8)	C37—C42	1.366 (8)
C15—C16	1.355 (8)	C38—C39	1.371 (9)
C15—H15	0.93	C38—H38	0.93
C16—C17	1.386 (7)	C39—C40	1.383 (8)
C16—H16	0.93	C39—H39	0.93
C17—C18	1.348 (8)	C40—C41	1.385 (8)
C17—N20	1.414 (7)	C40—N43	1.412 (7)
C18—C19	1.382 (8)	C41—C42	1.363 (8)
C18—H18	0.93	C41—H41	0.93
C19—H19	0.93	C42—H42	0.93
N20—C21	1.340 (7)	N43—C44	1.385 (8)
N20—H20	0.86	N43—H43	0.86
C21—O22	1.244 (6)	C44—O45	1.224 (7)
C21—C23	1.497 (8)	C44—C46	1.503 (9)
C23—H23A	0.96	C46—H46A	0.96
C23—H23B	0.96	C46—H46B	0.96
C23—H23C	0.96	C46—H46C	0.96
C2—C1—C6	118.9 (7)	C29—C24—C25	118.1 (6)
C2—C1—C7	120.8 (6)	C29—C24—C30	120.7 (7)
C6—C1—C7	120.3 (7)	C25—C24—C30	121.2 (6)
C3—C2—C1	119.3 (6)	C26—C25—N33	120.9 (6)
C3—C2—N10	120.8 (6)	C26—C25—C24	119.5 (6)
C1—C2—N10	119.8 (6)	N33—C25—C24	119.6 (6)
C4—C3—C2	122.3 (7)	C27—C26—C25	120.4 (6)
C4—C3—H3	118.9	C27—C26—H26	119.8
C2—C3—H3	118.9	C25—C26—H26	119.8
C3—C4—C5	118.2 (8)	C26—C27—C28	120.7 (7)
C3—C4—H4	120.9	C26—C27—H27	119.7
C5—C4—H4	120.9	C28—C27—H27	119.7
C6—C5—C4	121.3 (7)	C29—C28—C27	118.8 (7)
C6—C5—H5	119.3	C29—C28—H28	120.6
C4—C5—H5	119.3	C27—C28—H28	120.6
C5—C6—C1	119.9 (7)	C28—C29—C24	122.4 (7)
C5—C6—H6	120.1	C28—C29—H29	118.8
C1—C6—H6	120.1	C24—C29—H29	118.8
O8—C7—O9	121.3 (6)	O32—C30—O31	120.0 (6)
O8—C7—C1	125.3 (6)	O32—C30—C24	125.8 (7)
O9—C7—C1	113.4 (6)	O31—C30—C24	114.2 (6)
C7—O9—H9	109.5	C30—O31—H31	109.5
C2—N10—S11	125.8 (4)	C25—N33—S34	124.4 (4)
C2—N10—H10	117.1	C25—N33—H33	117.8
S11—N10—H10	117.1	S34—N33—H33	117.8
O13—S11—O12	117.5 (3)	O35—S34—O36	119.3 (3)
O13—S11—N10	112.5 (3)	O35—S34—N33	109.3 (3)
O12—S11—N10	103.2 (3)	O36—S34—N33	103.7 (3)
O13—S11—C14	107.3 (3)	O35—S34—C37	107.7 (3)
O12—S11—C14	109.7 (3)	O36—S34—C37	109.1 (3)
N10—S11—C14	106.0 (3)	N33—S34—C37	107.1 (3)
C19—C14—C15	119.9 (6)	C38—C37—C42	119.3 (6)
C19—C14—S11	119.9 (5)	C38—C37—S34	119.4 (6)
C15—C14—S11	119.9 (5)	C42—C37—S34	121.2 (5)
C16—C15—C14	119.0 (6)	C37—C38—C39	122.1 (6)
C16—C15—H15	120.5	C37—C38—H38	118.9
C14—C15—H15	120.5	C39—C38—H38	118.9
C15—C16—C17	121.7 (6)	C38—C39—C40	117.8 (6)
C15—C16—H16	119.2	C38—C39—H39	121.1
C17—C16—H16	119.2	C40—C39—H39	121.1
C18—C17—C16	119.2 (6)	C39—C40—C41	120.6 (7)
C18—C17—N20	124.7 (5)	C39—C40—N43	122.2 (6)
C16—C17—N20	116.1 (5)	C41—C40—N43	117.2 (6)
C17—C18—C19	120.5 (6)	C42—C41—C40	119.3 (6)
C17—C18—H18	119.7	C42—C41—H41	120.3
C19—C18—H18	119.7	C40—C41—H41	120.3
C14—C19—C18	119.7 (6)	C41—C42—C37	120.8 (6)
C14—C19—H19	120.1	C41—C42—H42	119.6
C18—C19—H19	120.1	C37—C42—H42	119.6
C21—N20—C17	130.0 (5)	C44—N43—C40	128.8 (6)
C21—N20—H20	115	C44—N43—H43	115.6
C17—N20—H20	115	C40—N43—H43	115.6
O22—C21—N20	121.9 (6)	O45—C44—N43	121.7 (7)
O22—C21—C23	121.6 (6)	O45—C44—C46	122.7 (7)
N20—C21—C23	116.5 (6)	N43—C44—C46	115.5 (6)
C21—C23—H23A	109.5	C44—C46—H46A	109.5
C21—C23—H23B	109.5	C44—C46—H46B	109.5
H23A—C23—H23B	109.5	H46A—C46—H46B	109.5
C21—C23—H23C	109.5	C44—C46—H46C	109.5
H23A—C23—H23C	109.5	H46A—C46—H46C	109.5
H23B—C23—H23C	109.5	H46B—C46—H46C	109.5

D—H···A	D—H	H···A	D···A	D—H···A
O9—H9···O22i	0.82	1.84	2.649 (6)	168
N10—H10···O8	0.86	2.13	2.624 (7)	116
N20—H20···O13ii	0.86	2.24	3.073 (6)	164
O31—H31···O45iii	0.82	1.81	2.623 (6)	174
N33—H33···O32	0.86	2.17	2.641 (7)	114
N43—H43···O36i	0.86	2.11	2.958 (7)	168
C23—H23B···Cg1	0.96	2.74	3.6110 (15)	151
C46—H46C···Cg2	0.96	2.71	3.5821 (13)	151

Table 1

Hydrogen-bond geometry (Å, °)

Cg1 and Cg2 are the centroids of the C37–C42 and C14–C19 rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O9—H9⋯O22i	0.82	1.84	2.649 (6)	168
N10—H10⋯O8	0.86	2.13	2.624 (7)	116
N20—H20⋯O13ii	0.86	2.24	3.073 (6)	164
O31—H31⋯O45iii	0.82	1.81	2.623 (6)	174
N33—H33⋯O32	0.86	2.17	2.641 (7)	114
N43—H43⋯O36i	0.86	2.11	2.958 (7)	168
C23—H23B⋯Cg1	0.96	2.74	3.6110 (15)	151
C46—H46C⋯Cg2	0.96	2.71	3.5821 (13)	151

Symmetry codes: (i) ; (ii) ; (iii) .