Literature DB >> 21836845

A new Mo Schiff base complex: methanol[N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]dioxido-molybdenum(VI).

Iran Sheikhshoaie, Vratislav Langer, Seyed Ali Yasrebi.   

Abstract

In the title benzil-idene Schiff base molybdenum(VI) complex, [Mo(C(15)H(12)N(2)O(3))O(2)(CH(3)OH)], the Mo(VI) ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N'-(3-meth-oxy-2-oxidobenzyl-idene)benzo-hydrazidate (L) Schiff base ligand. The methanol O atom completes the distorted octa-hedral configuration of the Mo(VI) atom. Strong O-H⋯N hydrogen bonds form a C(5) chain around a 2(1) screw axis. Weak C-H-O hydrogen bonds are also present.

Entities:  

Year:  2011        PMID： 21836845      PMCID： PMC3152014          DOI： 10.1107/S1600536811020101

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For general background, see: Alizadeh et al. (1999 ▶); Ambroziak et al. (2004 ▶); Archer & Wang (1990 ▶); Bagherzadeh & Amini (2009 ▶); Bagherzadeh et al. (2008 ▶); Bhatia et al. (1981 ▶); Bindlish et al. (1978 ▶); Blake et al. (1995 ▶); Chang et al. (1998 ▶); Costamagna et al. (1992 ▶); Dhar & Taploo (1982 ▶); Hatefi et al. (2009 ▶); Holm (1990 ▶); Jalali-Heravi et al. (1999 ▶); Johnson et al. (1996 ▶); Maurya et al. (1997 ▶); Sheikhshoaie & Fabian (2009 ▶); Yamada (1999 ▶). For details of the synthesis, see: Perrin et al. (1990 ▶). For related structures, see: Dinda et al. (2006 ▶); Glowiak et al. (2003 ▶); Liimatainen et al. (2000 ▶); Monadi et al. (2009 ▶); Niaz et al. (2010 ▶); Pramaniky et al. (2007 ▶); Rao et al. (1999 ▶); Rezaeifard et al. (2010 ▶); Saeednia et al. (2009 ▶); Sheikhshoaie et al. (2009 ▶); Vrdoljak et al. (2010 ▶).

Experimental

Crystal data

[Mo(C15H12N2O3)O2(CH4O)] M = 428.25 Monoclinic, a = 29.400 (13) Å b = 8.553 (4) Å c = 14.391 (6) Å β = 112.993 (8)° V = 3331 (2) Å3 Z = 8 Mo Kα radiation μ = 0.82 mm−1 T = 173 K 0.58 × 0.54 × 0.46 mm

Data collection

Bruker SMART CCD diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 2003 ▶) T min = 0.368, T max = 0.703 27788 measured reflections 5867 independent reflections 4401 reflections with I > 2σ(I) R int = 0.065

Refinement

R[F 2 > 2σ(F 2)] = 0.038 wR(F 2) = 0.104 S = 1.01 5867 reflections 229 parameters H-atom parameters constrained Δρmax = 1.38 e Å−3 Δρmin = −1.80 e Å−3 Data collection: SMART (Bruker, 2003 ▶); cell refinement: SAINT (Bruker, 2003 ▶); data reduction: SAINT and SADABS (Sheldrick, 2003 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg, 2010 ▶); software used to prepare material for publication: SHELXTL (Sheldrick, 2008 ▶) and PLATON (Spek, 2009 ▶). Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536811020101/dn2692sup1.cif Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811020101/dn2692Isup2.hkl Additional supplementary materials: crystallographic information; 3D view; checkCIF report
[Mo(C15H12N2O3)O2(CH4O)]F(000) = 1728
Mr = 428.25Dx = 1.708 Mg m−3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2ycCell parameters from 5066 reflections
a = 29.400 (13) Åθ = 2.5–32.3°
b = 8.553 (4) ŵ = 0.82 mm−1
c = 14.391 (6) ÅT = 173 K
β = 112.993 (8)°Block, orange
V = 3331 (2) Å30.58 × 0.54 × 0.46 mm
Z = 8
Bruker SMART CCD diffractometer5867 independent reflections
Radiation source: fine-focus sealed tube4401 reflections with I > 2σ(I)
graphiteRint = 0.065
ω scansθmax = 32.8°, θmin = 2.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 2003)h = −43→43
Tmin = 0.368, Tmax = 0.703k = −12→12
27788 measured reflectionsl = −21→21
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.038Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.104H-atom parameters constrained
S = 1.01w = 1/[σ2(Fo2) + (0.0566P)2 + 2.343P] where P = (Fo2 + 2Fc2)/3
5867 reflections(Δ/σ)max = 0.001
229 parametersΔρmax = 1.38 e Å−3
0 restraintsΔρmin = −1.80 e Å−3
Experimental. Data were collected at 173 K using a Siemens SMART CCD diffractometer equipped with LT-2 A cooling device. A full sphere of reciprocal space was scanned by 0.3° steps in ω with a crystal–to–detector distance of 3.97 cm, 1 second per frame. Preliminary orientation matrix was obtained from the first 100 frames using SMART (Bruker, 2003). The collected frames were integrated using the preliminary orientation matrix which was updated every 100 frames. Final cell parameters were obtained by refinement on the position of 5066 reflections with I>10σ(I) after integration of all the frames data using SAINT (Bruker, 2003).
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
xyzUiso*/Ueq
Mo10.169567 (7)0.55438 (2)0.093970 (13)0.01640 (7)
O10.23804 (6)0.54087 (18)0.09191 (12)0.0191 (3)
O20.11949 (6)0.47242 (19)0.13716 (13)0.0209 (3)
O30.02944 (7)0.4772 (2)0.13247 (15)0.0299 (4)
O40.17354 (6)0.74754 (19)0.12674 (13)0.0244 (4)
O50.13736 (7)0.5485 (2)−0.03385 (13)0.0254 (4)
N10.19324 (7)0.3025 (2)0.11307 (13)0.0163 (3)
N20.24201 (7)0.2753 (2)0.12187 (14)0.0176 (4)
C10.11885 (8)0.1902 (3)0.12040 (16)0.0185 (4)
C20.09645 (8)0.3331 (3)0.12693 (16)0.0187 (4)
C30.04804 (9)0.3332 (3)0.12641 (17)0.0226 (4)
C40.02337 (9)0.1919 (3)0.11911 (19)0.0285 (5)
H4−0.00930.19180.11700.034*
C50.04618 (10)0.0501 (3)0.1148 (2)0.0282 (5)
H50.0291−0.04560.11110.034*
C60.09347 (9)0.0485 (3)0.11585 (19)0.0236 (5)
H60.1089−0.04820.11350.028*
C70.16837 (8)0.1801 (3)0.12059 (16)0.0189 (4)
H70.18320.07990.12640.023*
C8−0.02257 (10)0.4859 (4)0.1098 (2)0.0357 (6)
H8A−0.04090.43390.04520.054*
H8B−0.03270.59580.10530.054*
H8C−0.02970.43400.16330.054*
C90.26226 (8)0.4068 (3)0.11017 (16)0.0171 (4)
C100.31418 (8)0.4117 (3)0.11898 (17)0.0186 (4)
C110.33256 (9)0.5503 (3)0.09429 (18)0.0212 (4)
H110.31150.63830.07060.025*
C120.38163 (10)0.5592 (3)0.1044 (2)0.0265 (5)
H120.39380.65320.08740.032*
C130.41308 (10)0.4306 (3)0.1396 (2)0.0279 (5)
H130.44660.43700.14700.033*
C140.39471 (9)0.2927 (3)0.1637 (2)0.0277 (5)
H140.41580.20480.18730.033*
C150.34575 (9)0.2829 (3)0.15337 (18)0.0228 (5)
H150.33360.18830.16970.027*
O1M0.21855 (6)0.51974 (19)0.26524 (12)0.0200 (3)
H1M0.22880.60390.29640.030*
C1M0.21418 (10)0.4038 (3)0.33394 (17)0.0240 (5)
H1AM0.23380.43590.40350.036*
H1BM0.22630.30300.32060.036*
H1CM0.17940.39350.32440.036*
U11U22U33U12U13U23
Mo10.01570 (10)0.01803 (10)0.01522 (9)0.00265 (7)0.00577 (7)0.00205 (7)
O10.0194 (8)0.0192 (8)0.0205 (7)0.0034 (6)0.0098 (6)0.0041 (6)
O20.0171 (8)0.0222 (8)0.0249 (8)0.0010 (6)0.0099 (7)−0.0004 (6)
O30.0191 (9)0.0358 (10)0.0363 (10)0.0057 (7)0.0126 (8)0.0020 (8)
O40.0271 (9)0.0205 (8)0.0273 (9)0.0058 (7)0.0126 (7)0.0045 (7)
O50.0224 (9)0.0332 (10)0.0186 (8)0.0054 (7)0.0058 (7)0.0033 (7)
N10.0156 (9)0.0190 (8)0.0143 (8)0.0003 (7)0.0058 (7)−0.0004 (6)
N20.0152 (8)0.0213 (9)0.0167 (8)0.0019 (7)0.0066 (7)−0.0006 (7)
C10.0159 (10)0.0238 (11)0.0145 (9)−0.0014 (8)0.0046 (8)−0.0003 (8)
C20.0159 (10)0.0254 (11)0.0138 (9)0.0005 (8)0.0047 (8)0.0019 (8)
C30.0163 (10)0.0308 (12)0.0197 (10)0.0008 (9)0.0060 (8)0.0007 (9)
C40.0172 (11)0.0400 (14)0.0291 (12)−0.0050 (10)0.0099 (10)0.0022 (11)
C50.0220 (12)0.0321 (13)0.0308 (13)−0.0080 (10)0.0107 (10)−0.0001 (10)
C60.0212 (11)0.0248 (11)0.0234 (11)−0.0041 (9)0.0074 (9)−0.0007 (9)
C70.0177 (10)0.0217 (10)0.0163 (9)0.0008 (8)0.0055 (8)0.0000 (8)
C80.0194 (12)0.0552 (18)0.0344 (14)0.0113 (12)0.0125 (11)0.0076 (13)
C90.0184 (10)0.0207 (10)0.0115 (8)0.0011 (8)0.0050 (8)−0.0002 (7)
C100.0181 (10)0.0236 (11)0.0154 (9)−0.0003 (8)0.0079 (8)−0.0022 (8)
C110.0208 (11)0.0233 (11)0.0209 (10)0.0015 (9)0.0095 (9)0.0031 (9)
C120.0248 (12)0.0288 (12)0.0285 (12)−0.0037 (10)0.0133 (10)0.0024 (10)
C130.0198 (11)0.0356 (14)0.0304 (13)−0.0017 (10)0.0120 (10)−0.0005 (10)
C140.0214 (12)0.0304 (13)0.0335 (13)0.0034 (10)0.0130 (10)0.0012 (10)
C150.0205 (11)0.0228 (11)0.0280 (12)0.0021 (9)0.0128 (9)0.0023 (9)
O1M0.0241 (8)0.0205 (8)0.0152 (7)−0.0036 (6)0.0076 (6)−0.0017 (6)
C1M0.0307 (13)0.0247 (11)0.0149 (10)0.0001 (9)0.0071 (9)0.0027 (8)
Mo1—O12.0281 (19)C6—H60.9500
Mo1—O21.9391 (17)C7—H70.9500
Mo1—O41.7096 (18)C8—H8A0.9800
Mo1—O51.7093 (19)C8—H8B0.9800
Mo1—N12.248 (2)C8—H8C0.9800
Mo1—O1M2.3374 (18)C9—C101.482 (3)
O1—C91.321 (3)C10—C151.400 (3)
O2—C21.350 (3)C10—C111.404 (3)
O3—C31.364 (3)C11—C121.394 (4)
O3—C81.435 (3)C11—H110.9500
N1—C71.306 (3)C12—C131.399 (4)
N1—N21.409 (3)C12—H120.9500
N2—C91.313 (3)C13—C141.396 (4)
C1—C21.409 (3)C13—H130.9500
C1—C61.411 (3)C14—C151.391 (3)
C1—C71.457 (3)C14—H140.9500
C2—C31.420 (3)C15—H150.9500
C3—C41.392 (4)O1M—C1M1.441 (3)
C4—C51.399 (4)O1M—H1M0.8400
C4—H40.9500C1M—H1AM0.9800
C5—C61.384 (4)C1M—H1BM0.9800
C5—H50.9500C1M—H1CM0.9800
O4—Mo1—O5105.93 (8)N1—C7—H7118.5
O4—Mo1—O2103.86 (8)C1—C7—H7118.5
O5—Mo1—O299.42 (9)O3—C8—H8A109.5
O4—Mo1—O195.61 (7)O3—C8—H8B109.5
O5—Mo1—O196.80 (8)H8A—C8—H8B109.5
O2—Mo1—O1150.03 (7)O3—C8—H8C109.5
O4—Mo1—N1155.24 (8)H8A—C8—H8C109.5
O5—Mo1—N196.81 (7)H8B—C8—H8C109.5
O2—Mo1—N181.49 (7)N2—C9—O1122.2 (2)
O1—Mo1—N171.67 (6)N2—C9—C10121.1 (2)
C9—O1—Mo1120.49 (14)O1—C9—C10116.7 (2)
C2—O2—Mo1134.07 (14)C15—C10—C11119.1 (2)
C3—O3—C8116.8 (2)C15—C10—C9121.7 (2)
C7—N1—N2116.36 (18)C11—C10—C9119.2 (2)
C7—N1—Mo1128.46 (15)C12—C11—C10120.3 (2)
N2—N1—Mo1115.13 (13)C12—C11—H11119.9
C9—N2—N1110.11 (18)C10—C11—H11119.9
C2—C1—C6119.7 (2)C11—C12—C13120.4 (2)
C2—C1—C7122.9 (2)C11—C12—H12119.8
C6—C1—C7117.3 (2)C13—C12—H12119.8
O2—C2—C1123.0 (2)C14—C13—C12119.3 (2)
O2—C2—C3117.3 (2)C14—C13—H13120.4
C1—C2—C3119.6 (2)C12—C13—H13120.4
O3—C3—C4125.4 (2)C15—C14—C13120.6 (2)
O3—C3—C2115.2 (2)C15—C14—H14119.7
C4—C3—C2119.4 (2)C13—C14—H14119.7
C3—C4—C5120.8 (2)C14—C15—C10120.4 (2)
C3—C4—H4119.6C14—C15—H15119.8
C5—C4—H4119.6C10—C15—H15119.8
C6—C5—C4120.3 (2)C1M—O1M—H1M109.5
C6—C5—H5119.9O1M—C1M—H1AM109.5
C4—C5—H5119.9O1M—C1M—H1BM109.5
C5—C6—C1120.2 (2)H1AM—C1M—H1BM109.5
C5—C6—H6119.9O1M—C1M—H1CM109.5
C1—C6—H6119.9H1AM—C1M—H1CM109.5
N1—C7—C1123.0 (2)H1BM—C1M—H1CM109.5
O4—Mo1—O1—C9152.56 (16)O2—C2—C3—C4−178.1 (2)
O5—Mo1—O1—C9−100.61 (16)C1—C2—C3—C4−0.2 (3)
O2—Mo1—O1—C921.8 (2)O3—C3—C4—C5−179.1 (2)
N1—Mo1—O1—C9−5.67 (15)C2—C3—C4—C51.6 (4)
O4—Mo1—O2—C2174.04 (19)C3—C4—C5—C6−1.2 (4)
O5—Mo1—O2—C264.9 (2)C4—C5—C6—C1−0.6 (4)
O1—Mo1—O2—C2−56.9 (3)C2—C1—C6—C51.9 (3)
N1—Mo1—O2—C2−30.6 (2)C7—C1—C6—C5−179.6 (2)
O4—Mo1—N1—C7120.7 (2)N2—N1—C7—C1175.46 (18)
O5—Mo1—N1—C7−82.56 (19)Mo1—N1—C7—C1−1.8 (3)
O2—Mo1—N1—C715.99 (19)C2—C1—C7—N1−9.5 (3)
O1—Mo1—N1—C7−177.5 (2)C6—C1—C7—N1172.0 (2)
O4—Mo1—N1—N2−56.6 (2)N1—N2—C9—O1−0.6 (3)
O5—Mo1—N1—N2100.14 (14)N1—N2—C9—C10178.14 (18)
O2—Mo1—N1—N2−161.31 (14)Mo1—O1—C9—N25.8 (3)
O1—Mo1—N1—N25.20 (13)Mo1—O1—C9—C10−173.01 (14)
C7—N1—N2—C9178.27 (19)N2—C9—C10—C15−8.8 (3)
Mo1—N1—N2—C9−4.1 (2)O1—C9—C10—C15170.0 (2)
Mo1—O2—C2—C130.2 (3)N2—C9—C10—C11172.5 (2)
Mo1—O2—C2—C3−151.97 (17)O1—C9—C10—C11−8.6 (3)
C6—C1—C2—O2176.2 (2)C15—C10—C11—C12−0.3 (3)
C7—C1—C2—O2−2.2 (3)C9—C10—C11—C12178.3 (2)
C6—C1—C2—C3−1.5 (3)C10—C11—C12—C13−0.2 (4)
C7—C1—C2—C3−179.9 (2)C11—C12—C13—C140.5 (4)
C8—O3—C3—C4−12.9 (4)C12—C13—C14—C15−0.3 (4)
C8—O3—C3—C2166.5 (2)C13—C14—C15—C10−0.3 (4)
O2—C2—C3—O32.5 (3)C11—C10—C15—C140.5 (3)
C1—C2—C3—O3−179.6 (2)C9—C10—C15—C14−178.1 (2)
D—H···AD—HH···AD···AD—H···A
O1M—H1M···N2i0.841.872.700 (3)173
C1M—H1BM···O1ii0.982.583.402 (3)141
C6—H6···O4iii0.952.533.450 (3)162
C11—H11···O10.952.442.767 (3)100
C15—H15···O1Mii0.952.543.427 (3)156
Cis-dioxo molybdenum complexMo=OMo-NMo–O(solv)1N—Mo=OO=Mo=O
[MoO2(bnms)(MeOH)I1.7092.2482.337155.24105.93
1.70996.81
[MoO2(sae)(MeOH)]a1.6972.2522.339158.9106.1
1.70494.2
[MoO2(cysS-OR)(MeOH)]b1.6992.2912.385160.8105.9
1.70992.5
[MoO2(hbhy)(EtOH)]c1.6962.2342.356158.44106.03
1.69993.84
[MoO2(doin)(MeOH)]d1.7002.2502.331159.54106.65
1.71493.16
[MoO2(hpmp)(MeOH)]e1.7032.2742.355159.38107.05
1.70993.07
[MoO2(hpemp)(MeOH)]f1.7072.2682.387159.81106.36
1.69993.53
[MoO2(moip)(MeOH)]g1.7002.2512.349158.82105.61
1.70295.01
[MoO2(ssh)(MeOH)]h1.6922.2342.349157.6106.4
1.70593.7
[MoO2(hmt)(MeOH)]i1.7272.2732.351156.41105.26
1.70495.29
MoO2(bhpd)(MeOH)j1.9882.2842.301160.49105.9
1.71790.93
Complexνs(Mo═O)1νs(Mo═O)2ν(C═N)
[MoO2(bnms)(MeOH)I9399151627
[MoO2(sae)(MeOH)]a9289061641
[MoO2(cysS-OR)(MeOH)]b9959801626
[MoO2(hbhy)(EtOH)]c---
[MoO2(doin)(MeOH)]d---
[MoO2(hpmp)(MeOH)]e9249001638
[MoO2(hpemp)(MeOH)]f9209091638
[MoO2(moip)(MeOH)]g---
[MoO2(ssh)(MeOH)]h9399111637
[MoO2(hmt)(MeOH)]i9329011626
MoO2(bhpd)(MeOH)j9399141579
Table 1

Selected geometric parameters (Å, °)

Mo1—O12.0281 (19)
Mo1—O21.9391 (17)
Mo1—O41.7096 (18)
Mo1—O51.7093 (19)
Mo1—N12.248 (2)
Mo1—O1M2.3374 (18)
Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯AD—HH⋯AD⋯AD—H⋯A
O1M—H1M⋯N2i0.841.872.700 (3)173
C1M—H1BM⋯O1ii0.982.583.402 (3)141
C6—H6⋯O4iii0.952.533.450 (3)162
C11—H11⋯O10.952.442.767 (3)100
C15—H15⋯O1Mii0.952.543.427 (3)156

Symmetry codes: (i) ; (ii) ; (iii) .

  7 in total

1.  Transition Metal Complexes of p-Sulfonatocalix[5]arene.

Authors:  Carl P. Johnson; Jerry L. Atwood; Jonathan W. Steed; Cary B. Bauer; Robin D. Rogers
Journal:  Inorg Chem       Date:  1996-04-24       Impact factor: 5.165

2.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

3.  Methano-ldioxido{1-[(2RS)-(2-oxidoprop-yl)iminometh-yl]-2-naphtholato}molybdenium(VI).

Authors:  Monadi Niaz; Sheikhshoaie Iran; Rezaeifard Abdolreza
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-01-27

4.  Methanol{2-meth-oxy-6-[(2-oxidoprop-yl)imino-meth-yl]phenolato}dioxidomolyb-denum(VI).

Authors:  Samira Saeednia; Iran Sheikhshoaie; Helen Stoeckli-Evans
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-11-18

5.  Synthesis and characterisation of thiosemicarbazonato molybdenum(VI) complexes and their in vitro antitumor activity.

Authors:  Visnja Vrdoljak; Ivica Dilović; Mirta Rubcić; Sandra Kraljević Pavelić; Marijeta Kralj; Dubravka Matković-Calogović; Ivo Piantanida; Predrag Novak; Andrea Rozman; Marina Cindrić
Journal:  Eur J Med Chem       Date:  2009-09-16       Impact factor: 6.514

6.  {1,1'-[(2,2-Dimethyl-propane-1,3-di-yl)bis-(nitrilo-methyl-idyne)]di-2-naphthol-ato}dioxidomolybdenum(VI) dichloro-methane 1.75-solvate.

Authors:  Niaz Monadi; Iran Sheikhshoaie; Abdoreza Rezaeifard; Helen Stoeckli-Evans
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-08-22

7.  Structure validation in chemical crystallography.

Authors:  Anthony L Spek
Journal:  Acta Crystallogr D Biol Crystallogr       Date:  2009-01-20
  7 in total
  1 in total

1.  [N'-(3-Eth-oxy-2-oxidobenzyl-idene)-4-hy-droxy-3-meth-oxy-benzohydrazidato](methanol)dioxidomolybdenum(VI).

Authors:  Shou-Xing Wang
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-03-03
  1 in total

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