Mesosynthesis of ZnO-SiO(2) porous nanocomposites with low-defect ZnO nanometric domains.

Silica-based ZnO-MCM-41 mesoporous nanocomposites with high Zn content (5≤Si/Zn≤50) have been synthesized by a one-pot surfactant-assisted procedure from aqueous solution using a cationic surfactant (CTMABr = cetyltrimethylammonium bromide) as structure-directing agent, and starting from molecular atrane complexes as inorganic hydrolytic precursors. This preparative technique allows optimization of the dispersion of the ZnO nanodomains in the silica walls. The mesoporous nature of the final materials is confirmed by x-ray diffraction (XRD), transmission electron microscopy (TEM) and N(2) adsorption-desorption isotherms. The ZnO-MCM-41 materials show unimodal pore size distributions without blocking of the pore system even for high Zn content. A careful optical spectroscopic study (using x-ray photoelectron spectroscopy (XPS), photoluminescence (PL) and UV-visible spectroscopy) of these materials shows that, irrespective of the Si/Zn ratio, the Zn atoms are organized in well-dispersed, uniform low-defect ZnO nanodomains (radius about 1 nm) and are partially embedded within the silica walls.