Literature DB >> 21823624

Oxidative intramolecular bromo-amination of N-alkenyl sulfonamides via umpolung of alkali metal bromides.

Katsuhiko Moriyama1, Yuta Izumisawa, Hideo Togo.   

Abstract

The oxidative intramolecular bromo-amination of various N-alkenyl sulfonamides and N-alkenoxyl sulfonamides via umpolung of alkali metal bromides occurred exo-selectively to generate cyclic bromoamides in high yields with good diastereoselectivities. This method provided the desired products without elaborating the stoichiometric amount of corresponding organic waste.

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Year:  2011        PMID: 21823624     DOI: 10.1021/jo201113r

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  6 in total

1.  Stereoselective isoxazolidine synthesis via copper-catalyzed alkene aminooxygenation.

Authors:  Shuklendu D Karyakarte; Thomas P Smith; Sherry R Chemler
Journal:  J Org Chem       Date:  2012-08-15       Impact factor: 4.354

2.  Catalytic enantioselective alkene aminohalogenation/cyclization involving atom transfer.

Authors:  Michael T Bovino; Sherry R Chemler
Journal:  Angew Chem Int Ed Engl       Date:  2012-03-05       Impact factor: 15.336

3.  Gold redox catalysis for cyclization/arylation of allylic oximes: synthesis of isoxazoline derivatives.

Authors:  Abiola Azeez Jimoh; Seyedmorteza Hosseyni; Xiaohan Ye; Lukasz Wojtas; Yong Hu; Xiaodong Shi
Journal:  Chem Commun (Camb)       Date:  2019-07-09       Impact factor: 6.222

4.  Aza-Heterocycles via Copper-Catalyzed, Remote C-H Desaturation of Amines.

Authors:  Leah M Stateman; Ross M Dare; Alyson N Paneque; David A Nagib
Journal:  Chem       Date:  2021-11-16       Impact factor: 22.804

5.  Stereoselective Synthesis of Isoxazolidines via Copper-Catalyzed Alkene Diamination.

Authors:  Zainab M Khoder; Christina E Wong; Sherry R Chemler
Journal:  ACS Catal       Date:  2017-06-15       Impact factor: 13.084

Review 6.  A Review of the Pharmacological Activities and Recent Synthetic Advances of γ-Butyrolactones.

Authors:  Joonseong Hur; Jaebong Jang; Jaehoon Sim
Journal:  Int J Mol Sci       Date:  2021-03-09       Impact factor: 5.923

  6 in total

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