Literature DB >> 21819063

Additive-free clicking for polymer functionalization and coupling by tetrazine-norbornene chemistry.

Claire F Hansell1, Pieter Espeel, Milan M Stamenović, Ian A Barker, Andrew P Dove, Filip E Du Prez, Rachel K O'Reilly.   

Abstract

Herein we report the use of a tetrazine-norbornene inverse electron demand Diels-Alder conjugation applied to polymer end-functionalization and polymer-polymer coupling. The reaction was found to be applicable to polymer-polymer coupling, as judged by SEC, DOSY NMR, and LCxSEC analyses, giving diblock copolymers by merely mixing the constituent homopolymers together under ambient conditions, using no catalyst, additive, or external stimulus.

Entities:  

Year:  2011        PMID： 21819063     DOI： 10.1021/ja203957h

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  30 in total

1.  Torsional Control of Stereoselectivities in Electrophilic Additions and Cycloadditions to Alkenes.

Authors:  Hao Wang; K N Houk
Journal:  Chem Sci       Date:  2014-02       Impact factor: 9.825

2.  Counting primary loops in polymer gels.

Authors:  Huaxing Zhou; Jiyeon Woo; Alexandra M Cok; Muzhou Wang; Bradley D Olsen; Jeremiah A Johnson
Journal:  Proc Natl Acad Sci U S A       Date:  2012-11-06       Impact factor: 11.205

3.  Polymer chemistry: Rooftop reactions.

Authors:  David M Haddleton
Journal:  Nat Chem       Date:  2013-05       Impact factor: 24.427

4.  Exploring strain-promoted 1,3-dipolar cycloadditions of end functionalized polymers.

Authors:  Petr A Ledin; Nagesh Kolishetti; Manish S Hudlikar; Geert-Jan Boons
Journal:  Chemistry       Date:  2014-06-06       Impact factor: 5.236

5.  Meter-long multiblock copolymer microfibers via interfacial bioorthogonal polymerization.

Authors:  Shuang Liu; Han Zhang; Roddel A Remy; Fei Deng; Michael E Mackay; Joseph M Fox; Xinqiao Jia
Journal:  Adv Mater       Date:  2015-03-30       Impact factor: 30.849

6.  Triazolinediones enable ultrafast and reversible click chemistry for the design of dynamic polymer systems.

Authors:  Stijn Billiet; Kevin De Bruycker; Frank Driessen; Hannelore Goossens; Veronique Van Speybroeck; Johan M Winne; Filip E Du Prez
Journal:  Nat Chem       Date:  2014-08-11       Impact factor: 24.427

7.  Synthesis and reactivity comparisons of 1-methyl-3-substituted cyclopropene mini-tags for tetrazine bioorthogonal reactions.

Authors:  Jun Yang; Yong Liang; Jolita Šečkutė; K N Houk; Neal K Devaraj
Journal:  Chemistry       Date:  2014-02-24       Impact factor: 5.236

8.  Stealth polymeric vesicles via metal-free click coupling.

Authors:  Michael J Isaacman; Eleonora M Corigliano; Luke S Theogarajan
Journal:  Biomacromolecules       Date:  2013-08-21       Impact factor: 6.988

9.  3,6-Substituted-1,2,4,5-tetrazines: tuning reaction rates for staged labeling applications.

Authors:  Danzhu Wang; Weixuan Chen; Yueqin Zheng; Chaofeng Dai; Ke Wang; Bowen Ke; Binghe Wang
Journal:  Org Biomol Chem       Date:  2014-06-21       Impact factor: 3.876

10.  Norbornadiene Chain-End Functional Polymers as Stable, Readily Available Precursors to Cyclopentadiene Derivatives.

Authors:  Sophia J Bailey; Emre H Discekici; Stephanie M Barbon; Shay N Nguyen; Craig J Hawker; Javier Read de Alaniz
Journal:  Macromolecules       Date:  2020-06-11       Impact factor: 5.985
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