Literature DB >> 21818481

Synthesis and optical resolution of a Cu(I) double-stranded helicate with ketimine-bridged tris(bipyridine) ligands.

Yoshio Furusho1, Hidetoshi Goto, Ken Itomi, Hiroshi Katagiri, Toyoharu Miyagawa, Eiji Yashima.   

Abstract

A tetranuclear Cu(I) double-stranded helicate was synthesized from ketimine-bridged tris(bipyridine) ligands and Cu(I) ions, and the racemate was successfully resolved by diastereomeric salt formation using an optically pure phosphate anion followed by anion exchange with NaPF(6) without racemization.

Entities:  

Year:  2011        PMID： 21818481     DOI： 10.1039/c1cc13333k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Dynamic control of chirality and self-assembly of double-stranded helicates with light.

Authors:  Depeng Zhao; Thomas van Leeuwen; Jinling Cheng; Ben L Feringa
Journal:  Nat Chem       Date:  2016-11-07       Impact factor: 24.427

2.  Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests.

Authors:  Naoki Ousaka; Shinya Yamamoto; Hiroki Iida; Takuya Iwata; Shingo Ito; Yuh Hijikata; Stephan Irle; Eiji Yashima
Journal:  Nat Commun       Date:  2019-03-29       Impact factor: 14.919

3.  Beauty in Chemistry: Making Artistic Molecules with Schiff Bases.

Authors:  Luigi Fabbrizzi
Journal:  J Org Chem       Date:  2020-09-14       Impact factor: 4.354
  3 in total

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