| Literature DB >> 21814703 |
Hiromichi Fujioka1, Akihiro Goto, Kazuki Otake, Ozora Kubo, Yoshinari Sawama, Tomohiro Maegawa.
Abstract
An unusual and novel reaction of α-alkoxyphosphonium salts, generated from O,O-acetals and Ph(3)P, with Grignard reagents under an O(2) atmosphere afforded alcohols in moderate to high yields. It was clarified by isotopic labelling experiments that the reaction proceeded via a novel radical pathway.Entities:
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Year: 2011 PMID： 21814703 DOI： 10.1039/c1cc13919c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222