Literature DB >> 21800855

Intramolecular N→Sn coordination in tin(II) and tin(IV) compounds based on enantiopure ephedrine derivatives.

Thomas Zöller1, Ljuba Iovkova-Berends, Thorsten Berends, Christina Dietz, Gerrit Bradtmöller, Klaus Jurkschat.   

Abstract

The syntheses and molecular structures of the intramolecularly coordinated tin(II) compounds {CH(2)N(Me)CH(Me)CH(Ph)O}(2)SnL (2, L = lone pair; 4, L = W(CO)(5); 5, L = Cr(CO)(5)) and of the related hydroxido-substituted tin(IV) compound [{CH(2)N(Me)CH(Me)CH(Ph)O}(2)Sn(OH)](2)O, 6a, are reported. Also reported are the molecular structures of the enantiopure N,N'-ethylenebis-(1R,2S)-ephedrine, {CH(2)N(Me)CH(Me)CH(Ph)OH}(2) (1), and its hydrobromide {CH(2)N(Me)CH(Me)CH(Ph)OH}(2)·HBr (1a).

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Year:  2011        PMID: 21800855     DOI: 10.1021/ic201203u

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  Synthesis, Spectroscopic, Molecular Structure, and Antibacterial Studies of Dibutyltin(IV) Schiff Base Complexes Derived from Phenylalanine, Isoleucine, and Glycine.

Authors:  Har Lal Singh; Jangbhadur Singh
Journal:  Bioinorg Chem Appl       Date:  2014-11-27       Impact factor: 7.778

  1 in total

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