| Literature DB >> 21800844 |
Xi-Bo Chen1, Qian-Jia Yuan, Jing Wang, Si-Kai Hua, Jiangmeng Ren, Bu-Bing Zeng.
Abstract
The marine natural product 16-deacetoxy-12-epi-scalarafuranacetate, isolated from Spongua officinalis , was synthesized in 18 linear steps, starting from (-)-sclareol, with high stereoselectivity and an overall yield of 6.1%. The intermediate 16-deacetoxy-12-epi-scalarafuran could be easily transformed into a series of natural scalarane sesterterpenoids in a few steps.Entities:
Mesh：
Substances：
Year: 2011 PMID： 21800844 DOI： 10.1021/jo2008127
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354