| Literature DB >> 21793524 |
Florent Poulhès1, Nicolas Vanthuyne, Michèle P Bertrand, Stéphane Gastaldi, Gérard Gil.
Abstract
The (R)-selective chemoenzymatic dynamic kinetic resolution of primary amines was performed at 38-40 °C in MTBE, in good to high yields and with high enantiomeric excesses. These reactions associating CAL-B to octanethiol as radical racemizing agent were carried out in the presence of methyl β-methoxy propanoate as acyl donor, under photochemical irradiation at 350 nm in glassware.Entities:
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Year: 2011 PMID： 21793524 DOI： 10.1021/jo201256w
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354