| Literature DB >> 21793492 |
Haralampos N Miras1, Daniel Stone, De-Liang Long, Eric J L McInnes, Paul Kögerler, Leroy Cronin.
Abstract
Vanadate(V)-templated Dawson-type capsules {V(IV)M(VI)(17)(VO(4))(2)} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been examined in the solid state by magnetic studies. The collision-induced dissociation (CID-MS) studies confirmed the solution structures as well as helped pinpoint the position of the vanadium ion on the {VM(17)}-type shell, which was corroborated by EPR and theoretical studies.Entities:
Year: 2011 PMID： 21793492 DOI： 10.1021/ic200943s
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165