Literature DB >> 21790196

Metal-catalyzed rearrangement of cyclopropenes to allenes.

Jingwei Li1, Chunrui Sun, Silviya Demerzhan, Daesung Lee.   

Abstract

A novel transition-metal-catalyzed rearrangement of silylated cyclopropenes to the corresponding allenes is described. The presence of both the trimethylsilyl group on the cyclopropene and the platinum catalyst are crucial for this rearrangement.

Entities:  

Year:  2011        PMID： 21790196     DOI： 10.1021/ja204979r

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Off-Cycle Processes in Pd-Catalyzed Cross-Coupling of Carboranes.

Authors:  Rafal M Dziedzic; Jonathan C Axtell; Arnold L Rheingold; Alexander M Spokoyny
Journal:  Org Process Res Dev       Date:  2019-08-05       Impact factor: 3.317

2.  Gold-Catalyzed Reaction of Propargyl Esters and Alkynylsilanes: Synthesis of Vinylallene Derivatives through a Twofold 1,2-Rearrangement.

Authors:  Olaya Bernardo; Silvia González-Pelayo; Israel Fernández; Luis A López
Journal:  Angew Chem Int Ed Engl       Date:  2021-10-21       Impact factor: 16.823
  2 in total

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