Literature DB >> 21786789

An unexpected oxidation of unactivated methylene C-H using DIB/TBHP protocol.

Yi Zhao1, Wai-Leung Yim, Chong Kiat Tan, Ying-Yeung Yeung.   

Abstract

An in situ generated hypervalent iodine species, bis(tert-butylperoxy)iodobenzene, was used as a peroxy radical source for the oxidation of unreactive, remote, and isolated alkyl (cyclic or aliphatic) esters and amides to the corresponding keto compounds under very mild conditions.
© 2011 American Chemical Society

Entities:  

Year:  2011        PMID： 21786789     DOI： 10.1021/ol2016466

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  A Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation.

Authors:  Ji-Bao Xia; Kevin W Cormier; Chuo Chen
Journal:  Chem Sci       Date:  2012-04-13       Impact factor: 9.825

2.  Wacker-type oxidation of internal alkenes using Pd(Quinox) and TBHP.

Authors:  Ryan J DeLuca; Jennifer L Edwards; Laura D Steffens; Brian W Michel; Xiaoxiao Qiao; Chunyin Zhu; Silas P Cook; Matthew S Sigman
Journal:  J Org Chem       Date:  2013-02-06       Impact factor: 4.354

3.  Iodine(III) Reagents in Radical Chemistry.

Authors:  Xi Wang; Armido Studer
Journal:  Acc Chem Res       Date:  2017-06-21       Impact factor: 22.384

4.  A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C-H bonds.

Authors:  Yaxin Wang; Guo-Xing Li; Guohui Yang; Gang He; Gong Chen
Journal:  Chem Sci       Date:  2016-01-11       Impact factor: 9.825

5.  Chemo- and regioselective oxygenation of C(sp3)-H bonds in aliphatic alcohols using a covalently bound directing activator and atmospheric oxygen.

Authors:  Jun Ozawa; Masayuki Tashiro; Jizhi Ni; Kounosuke Oisaki; Motomu Kanai
Journal:  Chem Sci       Date:  2015-11-27       Impact factor: 9.825
  5 in total

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