Literature DB >> 21780782

Noncovalent trapping and stabilization of dinuclear ruthenium complexes within a coordination cage.

Shinnosuke Horiuchi1, Takashi Murase, Makoto Fujita.   

Abstract

A dinuclear ruthenium complex, [(η(5)-indenyl)Ru(CO)(2)](2), was noncovalently enclathrated within a self-assembled coordination cage. In the cavity, rapid cis-trans isomerization and ligand exchange between the terminal and bridging carbonyls were suppressed, and only the carbonyl-bridged cis configuration was observed by X-ray crystallographic analysis.

Entities:  

Year:  2011        PMID： 21780782     DOI： 10.1021/ja205450a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Design and Applications of Water-Soluble Coordination Cages.

Authors:  Edmundo G Percástegui; Tanya K Ronson; Jonathan R Nitschke
Journal:  Chem Rev       Date:  2020-11-25       Impact factor: 60.622

2.  Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics.

Authors:  Trandon A Bender; Mariko Morimoto; Robert G Bergman; Kenneth N Raymond; F Dean Toste
Journal:  J Am Chem Soc       Date:  2019-01-22       Impact factor: 15.419

3.  Incorporation of a Phosphino(pyridine) Subcomponent Enables the Formation of Cages with Homobimetallic and Heterobimetallic Vertices.

Authors:  John P Carpenter; Tanya K Ronson; Felix J Rizzuto; Théophile Héliot; Peter Grice; Jonathan R Nitschke
Journal:  J Am Chem Soc       Date:  2022-05-05       Impact factor: 16.383

4.  Selective Co-Encapsulation Inside an M6 L4 Cage.

Authors:  Stefan H A M Leenders; René Becker; Tatu Kumpulainen; Bas de Bruin; Tomohisa Sawada; Taito Kato; Makoto Fujita; Joost N H Reek
Journal:  Chemistry       Date:  2016-09-14       Impact factor: 5.236

5.  Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix.

Authors:  Sho Matsuno; Masahiro Yamashina; Yoshihisa Sei; Munetaka Akita; Akiyoshi Kuzume; Kimihisa Yamamoto; Michito Yoshizawa
Journal:  Nat Commun       Date:  2017-09-29       Impact factor: 14.919
  5 in total

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