Literature DB >> 21776618

Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex.

Yong Yang1, Robert M Rioux.   

Abstract

Highly regio- and stereoselective hydrothiolation of a wide range of alkynes with various thiols was demonstrated in the presence of a well-defined Rh complex supported on mesoporous SBA-15 silica. The catalyst was easily recovered and reused several times without significant loss of activity or selectivity. This journal is © The Royal Society of Chemistry 2011

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Year:  2011        PMID： 21776618     DOI： 10.1039/c1cc11605c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Mechanism of the palladium-catalyzed hydrothiolation of alkynes to thioethers: a DFT study.

Authors:  Xing-hui Zhang; Zhi-yuan Geng; Ke-tai Wang; Shan-shan Li
Journal:  J Mol Model       Date:  2014-08-20       Impact factor: 1.810

2.  Hydrothiolation of benzyl mercaptan to arylacetylene: application to the synthesis of (E) and (Z)-isomers of ON 01910·Na (Rigosertib®), a phase III clinical stage anti-cancer agent.

Authors:  Venkat R Pallela; Muralidhar R Mallireddigari; Stephen C Cosenza; Balaiah Akula; D R C Venkata Subbaiah; E Premkumar Reddy; M V Ramana Reddy
Journal:  Org Biomol Chem       Date:  2013-02-06       Impact factor: 3.876

Review 3.  Metal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and Dienes.

Authors:  Nikolai V Orlov
Journal:  ChemistryOpen       Date:  2015-09-09       Impact factor: 2.911

4.  Thiol-yne click reaction: an interesting way to derive thiol-provided catechols.

Authors:  Fabiana Nador; Juan Mancebo-Aracil; Duham Zanotto; Daniel Ruiz-Molina; Gabriel Radivoy
Journal:  RSC Adv       Date:  2021-01-07       Impact factor: 3.361

Review 5.  Applications of SBA-15 supported Pd metal catalysts as nanoreactors in C-C coupling reactions.

Authors:  Ghodsi Mohammadi Ziarani; Sahar Rohani; Abolfazl Ziarati; Alireza Badiei
Journal:  RSC Adv       Date:  2018-12-07       Impact factor: 4.036
  5 in total

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