Literature DB >> 21770424

Palladium-catalyzed alkynylation of secondary α-bromo carbonyl compounds via Stille coupling.

Jun Yong Kang1, Brian T Connell.   

Abstract

A catalytic intermolecular cross-coupling reaction that couples secondary α-bromo carbonyl compounds with alkynylstannanes to form secondary alkynyl carbonyl compounds via palladium catalysis employing the XPhos ligand is described.

Entities:  

Year:  2011        PMID: 21770424     DOI: 10.1021/jo200939u

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

Review 1.  The Fascinating Chemistry of α-Haloamides.

Authors:  Anna Fantinati; Vinicio Zanirato; Paolo Marchetti; Claudio Trapella
Journal:  ChemistryOpen       Date:  2020-01-13       Impact factor: 2.911

2.  Pd-catalyzed alkynylation of 2-chloroacetates and 2-chloroacetamides with potassium alkynyltrifluoroborates.

Authors:  Gary A Molander; Kaitlin M Traister
Journal:  Org Lett       Date:  2013-09-16       Impact factor: 6.005

  2 in total

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