Literature DB >> 21761822

Kinetic profiling of prolinate-catalyzed α-amination of aldehydes.

Jason E Hein1, Alan Armstrong, Donna G Blackmond.   

Abstract

Deconvolution of the role of off-cycle species from the desired catalytic cycle leads to an optimized protocol for the prolinate-catalyzed amination of aldehydes. The scope of complex reaction networks will be greatly broadened by understanding ancillary rate processes that influence the productive catalytic pathway.
© 2011 American Chemical Society

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Year:  2011        PMID: 21761822     DOI: 10.1021/ol201639z

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Mechanistically Guided Design of an Efficient and Enantioselective Aminocatalytic α-Chlorination of Aldehydes.

Authors:  George Hutchinson; Carla Alamillo-Ferrer; Jordi Burés
Journal:  J Am Chem Soc       Date:  2021-04-30       Impact factor: 15.419

2.  Differential scanning calorimetry (DSC) as a tool for probing the reactivity of polyynes relevant to hexadehydro-Diels-Alder (HDDA) cascades.

Authors:  Brian P Woods; Thomas R Hoye
Journal:  Org Lett       Date:  2014-12-03       Impact factor: 6.005

  2 in total

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