Bis(μ-2-{[2-(1,3-benzothia-zol-2-yl)hydrazinyl-idene]meth-yl}-6-meth-oxy-phenolato)bis-[dinitratodysprosium(III)] methanol disolvate.

In the centrosymmetric dinuclear title compound, [Dy(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(4)]·2CH(3)OH, the two Dy(III) atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothia-zol-2-yl)hydrazinyl-idene]meth-yl}-6-meth-oxy-phenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by inter-molecular N-H⋯O hydrogen bonds and weak O-H⋯O inter-actions, forming a two-dimensional network parallel to (010).

Related literature

For applications of dysprosium complexes in data storage and processing, see: Lin et al. (2010 ▶). For the preparation of the 2-{[2-(1,3-benzothia­zol-2-yl)hydrazinyl­idene]meth­yl}-6-meth­oxy­phenol ligand, see: Patil et al. (2009 ▶). For related structures, see: Lin & Hong (2009 ▶); Lin et al. (2008 ▶); Xu et al. (2010 ▶).

Experimental

Crystal data

[Dy2(C15H12N3O2S)2(NO3)4]·2CH4O

M = 1233.82

Triclinic,

a = 9.6191 (6) Å

b = 10.1002 (7) Å

c = 11.6151 (8) Å

α = 112.045 (1)°

β = 105.065 (1)°

γ = 93.154 (1)°

V = 995.23 (12) Å3

Z = 1

Mo Kα radiation

μ = 3.92 mm−1

T = 159 K

0.20 × 0.10 × 0.10 mm

Data collection

Rigaku Saturn CCD area-detector diffractometer

Absorption correction: multi-scan (CrystalClear; Rigaku, 2002 ▶) T min = 0.631, T max = 0.676

5083 measured reflections

3502 independent reflections

3162 reflections with I > 2σ(I)

R int = 0.016

Refinement

R[F 2 > 2σ(F 2)] = 0.025

wR(F 2) = 0.057

S = 1.07

3502 reflections

292 parameters

H-atom parameters constrained

Δρmax = 0.83 e Å−3

Δρmin = −0.51 e Å−3

Data collection: CrystalClear (Rigaku, 2002 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg & Putz, 2006 ▶) and XP (Siemens, 1994 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536811019118/jj2083sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811019118/jj2083Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Dy2(C15H12N3O2S)2(NO3)4]·2CH4O	Z = 1
Mr = 1233.82	F(000) = 602
Triclinic, P1	Dx = 2.059 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.6191 (6) Å	Cell parameters from 3776 reflections
b = 10.1002 (7) Å	θ = 2.3–25.1°
c = 11.6151 (8) Å	µ = 3.92 mm−1
α = 112.045 (1)°	T = 159 K
β = 105.065 (1)°	Block, yellow
γ = 93.154 (1)°	0.20 × 0.10 × 0.10 mm
V = 995.23 (12) Å3

Rigaku Saturn CCD area-detector diffractometer	3502 independent reflections
Radiation source: rotating anode	3162 reflections with I > 2σ(I)
confocal	Rint = 0.016
Detector resolution: 7.31 pixels mm-1	θmax = 25.1°, θmin = 2.0°
ω and φ scans	h = −11→11
Absorption correction: multi-scan (CrystalClear; Rigaku, 2002)	k = −12→7
Tmin = 0.631, Tmax = 0.676	l = −13→13
5083 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.025	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.057	H-atom parameters constrained
S = 1.07	w = 1/[σ2(Fo2) + (0.0289P)2 + 0.127P] where P = (Fo2 + 2Fc2)/3
3502 reflections	(Δ/σ)max = 0.001
292 parameters	Δρmax = 0.83 e Å−3
0 restraints	Δρmin = −0.51 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.5488 (5)	−0.1481 (6)	1.3423 (4)	0.0419 (12)
H1A	0.4829	−0.0989	1.3895	0.063*
H1B	0.6488	−0.0946	1.3876	0.063*
H1C	0.5453	−0.2468	1.3387	0.063*
C2	0.3550 (4)	−0.2085 (4)	1.1420 (4)	0.0262 (9)
C3	0.2744 (5)	−0.3007 (5)	1.1704 (4)	0.0328 (10)
H3	0.3194	−0.3323	1.2363	0.039*
C4	0.1277 (5)	−0.3481 (5)	1.1034 (4)	0.0349 (10)
H4	0.0711	−0.4143	1.1208	0.042*
C5	0.0654 (4)	−0.2974 (5)	1.0113 (4)	0.0314 (10)
H5	−0.0365	−0.3263	0.9677	0.038*
C6	0.1455 (4)	−0.2054 (4)	0.9789 (4)	0.0259 (9)
C7	0.2972 (4)	−0.1615 (4)	1.0421 (4)	0.0237 (8)
C8	0.0613 (4)	−0.1613 (5)	0.8805 (4)	0.0308 (10)
H8	−0.0395	−0.2025	0.8423	0.037*
C9	0.0364 (4)	0.0701 (5)	0.7244 (4)	0.0285 (9)
C10	0.1564 (4)	0.2767 (4)	0.7467 (4)	0.0265 (9)
C11	0.2636 (4)	0.3998 (5)	0.7988 (4)	0.0309 (10)
H11	0.3530	0.4075	0.8617	0.037*
C12	0.2378 (5)	0.5099 (5)	0.7573 (4)	0.0335 (10)
H12	0.3112	0.5930	0.7904	0.040*
C13	0.1059 (5)	0.5011 (5)	0.6680 (4)	0.0354 (10)
H13	0.0902	0.5791	0.6421	0.042*
C14	−0.0026 (5)	0.3818 (5)	0.6163 (4)	0.0335 (10)
H14	−0.0930	0.3764	0.5557	0.040*
C15	0.0251 (4)	0.2701 (5)	0.6558 (4)	0.0284 (9)
C16	0.2951 (6)	0.3287 (6)	0.4354 (5)	0.0540 (14)
H16A	0.2585	0.3862	0.3858	0.081*
H16C	0.3978	0.3682	0.4862	0.081*
H16B	0.2374	0.3326	0.4945	0.081*
Dy1	0.358298 (18)	0.05304 (2)	0.890365 (17)	0.02346 (8)
N4	0.1097 (3)	−0.0726 (4)	0.8405 (3)	0.0283 (8)
N5	0.1632 (3)	0.1587 (4)	0.7829 (3)	0.0274 (8)
N6	0.3542 (4)	0.3093 (4)	1.1063 (3)	0.0345 (9)
N7	0.3601 (4)	−0.1898 (4)	0.6517 (3)	0.0327 (8)
N9	0.0038 (3)	−0.0478 (4)	0.7456 (3)	0.0327 (8)
H9	−0.0802	−0.1070	0.7020	0.039*
O1	0.5034 (3)	−0.1543 (3)	1.2102 (3)	0.0291 (6)
O2	0.3863 (3)	−0.0823 (3)	1.0113 (2)	0.0249 (6)
O3	0.2717 (3)	0.1897 (3)	1.0724 (3)	0.0340 (7)
O4	0.4335 (3)	0.3079 (3)	1.0330 (3)	0.0337 (7)
O5	0.3585 (4)	0.4152 (4)	1.2012 (3)	0.0574 (10)
O6	0.2613 (3)	−0.1127 (3)	0.6575 (3)	0.0371 (7)
O7	0.3620 (4)	−0.2850 (4)	0.5512 (3)	0.0580 (10)
O8	0.4579 (3)	−0.1600 (3)	0.7589 (3)	0.0416 (8)
O9	0.2828 (3)	0.1836 (4)	0.3486 (3)	0.0452 (8)
H9A	0.3398	0.1790	0.3038	0.068*
S1	−0.09430 (11)	0.11034 (12)	0.61321 (10)	0.0315 (2)

	U11	U22	U33	U12	U13	U23
C1	0.033 (2)	0.062 (3)	0.028 (2)	0.002 (2)	0.0030 (19)	0.020 (2)
C2	0.021 (2)	0.029 (2)	0.027 (2)	0.0045 (17)	0.0058 (17)	0.0110 (18)
C3	0.036 (2)	0.029 (2)	0.033 (2)	0.006 (2)	0.0075 (19)	0.014 (2)
C4	0.033 (2)	0.033 (2)	0.041 (3)	0.002 (2)	0.011 (2)	0.017 (2)
C5	0.022 (2)	0.035 (2)	0.034 (2)	0.0027 (18)	0.0075 (18)	0.011 (2)
C6	0.0188 (19)	0.028 (2)	0.030 (2)	0.0037 (17)	0.0051 (17)	0.0118 (18)
C7	0.0183 (19)	0.022 (2)	0.028 (2)	0.0031 (16)	0.0038 (16)	0.0095 (18)
C8	0.016 (2)	0.037 (3)	0.033 (2)	0.0030 (18)	0.0006 (17)	0.013 (2)
C9	0.019 (2)	0.037 (2)	0.028 (2)	0.0086 (18)	0.0036 (17)	0.013 (2)
C10	0.023 (2)	0.032 (2)	0.024 (2)	0.0070 (18)	0.0049 (17)	0.0117 (18)
C11	0.022 (2)	0.039 (3)	0.030 (2)	0.0060 (19)	0.0039 (17)	0.014 (2)
C12	0.029 (2)	0.035 (2)	0.032 (2)	0.003 (2)	0.0046 (19)	0.012 (2)
C13	0.039 (2)	0.039 (3)	0.031 (2)	0.011 (2)	0.006 (2)	0.019 (2)
C14	0.031 (2)	0.042 (3)	0.028 (2)	0.012 (2)	0.0021 (19)	0.019 (2)
C15	0.020 (2)	0.038 (2)	0.022 (2)	0.0059 (18)	0.0028 (16)	0.0086 (19)
C16	0.043 (3)	0.069 (4)	0.044 (3)	0.009 (3)	0.011 (2)	0.018 (3)
Dy1	0.01390 (10)	0.03118 (12)	0.02375 (11)	0.00321 (8)	0.00021 (7)	0.01318 (9)
N4	0.0175 (16)	0.033 (2)	0.0301 (18)	−0.0005 (15)	−0.0019 (14)	0.0156 (16)
N5	0.0207 (17)	0.0310 (19)	0.0281 (18)	0.0054 (15)	0.0046 (14)	0.0110 (16)
N6	0.033 (2)	0.039 (2)	0.029 (2)	0.0144 (18)	0.0035 (17)	0.0152 (19)
N7	0.0199 (18)	0.036 (2)	0.031 (2)	0.0019 (16)	−0.0010 (15)	0.0067 (18)
N9	0.0144 (16)	0.045 (2)	0.0347 (19)	−0.0018 (16)	−0.0072 (14)	0.0229 (18)
O1	0.0195 (13)	0.0415 (17)	0.0277 (15)	0.0034 (13)	0.0010 (11)	0.0199 (14)
O2	0.0146 (13)	0.0316 (16)	0.0279 (14)	0.0016 (12)	0.0007 (11)	0.0156 (13)
O3	0.0291 (16)	0.0430 (19)	0.0312 (16)	0.0091 (15)	0.0063 (13)	0.0177 (15)
O4	0.0285 (15)	0.0393 (18)	0.0298 (15)	0.0044 (14)	0.0036 (13)	0.0138 (14)
O5	0.086 (3)	0.041 (2)	0.041 (2)	0.021 (2)	0.0250 (19)	0.0073 (18)
O6	0.0229 (15)	0.0449 (19)	0.0318 (16)	0.0119 (14)	−0.0016 (13)	0.0087 (15)
O7	0.0373 (19)	0.066 (3)	0.037 (2)	0.0132 (18)	−0.0008 (16)	−0.0066 (19)
O8	0.0351 (17)	0.0463 (19)	0.0321 (16)	0.0152 (15)	−0.0033 (14)	0.0117 (15)
O9	0.0258 (17)	0.057 (2)	0.046 (2)	−0.0010 (16)	0.0079 (14)	0.0163 (18)
S1	0.0212 (5)	0.0388 (6)	0.0302 (5)	0.0037 (5)	−0.0020 (4)	0.0161 (5)

C1—O1	1.459 (5)	C13—H13	0.9500
C1—H1A	0.9800	C14—C15	1.384 (6)
C1—H1B	0.9800	C14—H14	0.9500
C1—H1C	0.9800	C15—S1	1.752 (4)
C2—C3	1.364 (6)	C16—O9	1.410 (6)
C2—O1	1.402 (4)	C16—H16A	0.9800
C2—C7	1.410 (5)	C16—H16C	0.9800
C3—C4	1.379 (6)	C16—H16B	0.9800
C3—H3	0.9500	Dy1—O2	2.280 (3)
C4—C5	1.370 (6)	Dy1—O2i	2.374 (2)
C4—H4	0.9500	Dy1—O1i	2.394 (3)
C5—C6	1.390 (5)	Dy1—O4	2.422 (3)
C5—H5	0.9500	Dy1—O3	2.433 (3)
C6—C7	1.412 (5)	Dy1—N4	2.461 (3)
C6—C8	1.451 (5)	Dy1—O6	2.471 (3)
C7—O2	1.342 (4)	Dy1—N5	2.494 (3)
C8—N4	1.270 (5)	Dy1—O8	2.530 (3)
C8—H8	0.9500	Dy1—Dy1i	3.7184 (4)
C9—N5	1.320 (5)	N4—N9	1.402 (4)
C9—N9	1.340 (5)	N6—O5	1.203 (5)
C9—S1	1.738 (4)	N6—O3	1.273 (5)
C10—C11	1.395 (6)	N6—O4	1.279 (4)
C10—C15	1.399 (5)	N7—O7	1.208 (5)
C10—N5	1.405 (5)	N7—O6	1.261 (4)
C11—C12	1.379 (6)	N7—O8	1.266 (4)
C11—H11	0.9500	N9—H9	0.8800
C12—C13	1.388 (6)	O1—Dy1i	2.394 (3)
C12—H12	0.9500	O2—Dy1i	2.374 (2)
C13—C14	1.376 (6)	O9—H9A	0.8400
O1—C1—H1A	109.5	O4—Dy1—O3	52.63 (10)
O1—C1—H1B	109.5	O2—Dy1—N4	75.53 (10)
H1A—C1—H1B	109.5	O2i—Dy1—N4	149.07 (10)
O1—C1—H1C	109.5	O1i—Dy1—N4	138.80 (10)
H1A—C1—H1C	109.5	O4—Dy1—N4	121.11 (11)
H1B—C1—H1C	109.5	O3—Dy1—N4	74.17 (11)
C3—C2—O1	122.0 (4)	O2—Dy1—O6	108.45 (10)
C3—C2—C7	123.2 (4)	O2i—Dy1—O6	116.45 (9)
O1—C2—C7	114.8 (3)	O1i—Dy1—O6	76.95 (10)
C2—C3—C4	120.1 (4)	O4—Dy1—O6	141.79 (10)
C2—C3—H3	120.0	O3—Dy1—O6	139.92 (10)
C4—C3—H3	120.0	N4—Dy1—O6	69.16 (10)
C5—C4—C3	118.5 (4)	O2—Dy1—N5	139.17 (10)
C5—C4—H4	120.8	O2i—Dy1—N5	144.17 (10)
C3—C4—H4	120.8	O1i—Dy1—N5	81.46 (10)
C4—C5—C6	122.6 (4)	O4—Dy1—N5	79.22 (10)
C4—C5—H5	118.7	O3—Dy1—N5	79.08 (10)
C6—C5—H5	118.7	N4—Dy1—N5	66.52 (11)
C5—C6—C7	119.6 (4)	O6—Dy1—N5	72.05 (10)
C5—C6—C8	115.0 (4)	O2—Dy1—O8	77.32 (10)
C7—C6—C8	125.3 (4)	O2i—Dy1—O8	70.22 (9)
O2—C7—C2	119.8 (3)	O1i—Dy1—O8	76.42 (10)
O2—C7—C6	124.3 (3)	O4—Dy1—O8	140.65 (10)
C2—C7—C6	115.8 (3)	O3—Dy1—O8	153.86 (10)
N4—C8—C6	126.1 (4)	N4—Dy1—O8	98.23 (11)
N4—C8—H8	117.0	O6—Dy1—O8	50.52 (9)
C6—C8—H8	117.0	N5—Dy1—O8	121.51 (10)
N5—C9—N9	123.9 (4)	O2—Dy1—Dy1i	37.86 (6)
N5—C9—S1	117.3 (3)	O2i—Dy1—Dy1i	36.10 (6)
N9—C9—S1	118.8 (3)	O1i—Dy1—Dy1i	103.10 (6)
C11—C10—C15	119.0 (4)	O4—Dy1—Dy1i	92.27 (7)
C11—C10—N5	125.8 (3)	O3—Dy1—Dy1i	90.23 (7)
C15—C10—N5	115.2 (4)	N4—Dy1—Dy1i	113.24 (8)
C12—C11—C10	118.9 (4)	O6—Dy1—Dy1i	118.59 (7)
C12—C11—H11	120.6	N5—Dy1—Dy1i	169.00 (8)
C10—C11—H11	120.6	O8—Dy1—Dy1i	69.47 (6)
C11—C12—C13	120.9 (4)	C8—N4—N9	114.2 (3)
C11—C12—H12	119.5	C8—N4—Dy1	131.6 (3)
C13—C12—H12	119.5	N9—N4—Dy1	114.1 (2)
C14—C13—C12	121.5 (4)	C9—N5—C10	109.1 (3)
C14—C13—H13	119.3	C9—N5—Dy1	113.1 (3)
C12—C13—H13	119.3	C10—N5—Dy1	136.6 (2)
C13—C14—C15	117.4 (4)	O5—N6—O3	122.4 (4)
C13—C14—H14	121.3	O5—N6—O4	122.6 (4)
C15—C14—H14	121.3	O3—N6—O4	115.0 (3)
C14—C15—C10	122.3 (4)	O7—N7—O6	122.5 (4)
C14—C15—S1	127.6 (3)	O7—N7—O8	122.2 (4)
C10—C15—S1	109.9 (3)	O6—N7—O8	115.2 (3)
O9—C16—H16A	109.5	C9—N9—N4	117.0 (3)
O9—C16—H16C	109.5	C9—N9—H9	121.5
H16A—C16—H16C	109.5	N4—N9—H9	121.5
O9—C16—H16B	109.5	C2—O1—C1	114.9 (3)
H16A—C16—H16B	109.5	C2—O1—Dy1i	116.7 (2)
H16C—C16—H16B	109.5	C1—O1—Dy1i	127.7 (2)
O2—Dy1—O2i	73.96 (10)	C7—O2—Dy1	136.2 (2)
O2—Dy1—O1i	139.27 (9)	C7—O2—Dy1i	117.7 (2)
O2i—Dy1—O1i	68.12 (9)	Dy1—O2—Dy1i	106.04 (10)
O2—Dy1—O4	109.76 (9)	N6—O3—Dy1	95.9 (2)
O2i—Dy1—O4	74.78 (9)	N6—O4—Dy1	96.3 (2)
O1i—Dy1—O4	74.29 (10)	N7—O6—Dy1	98.6 (2)
O2—Dy1—O3	76.56 (10)	N7—O8—Dy1	95.6 (2)
O2i—Dy1—O3	103.27 (9)	C16—O9—H9A	109.5
O1i—Dy1—O3	125.83 (10)	C9—S1—C15	88.36 (19)
O1—C2—C3—C4	178.1 (4)	C8—N4—N9—C9	162.8 (4)
C7—C2—C3—C4	−2.5 (7)	Dy1—N4—N9—C9	−20.4 (4)
C2—C3—C4—C5	−1.7 (6)	C3—C2—O1—C1	−25.7 (5)
C3—C4—C5—C6	2.8 (7)	C7—C2—O1—C1	154.9 (4)
C4—C5—C6—C7	0.2 (6)	C3—C2—O1—Dy1i	162.7 (3)
C4—C5—C6—C8	−179.3 (4)	C7—C2—O1—Dy1i	−16.7 (4)
C3—C2—C7—O2	−173.5 (4)	C2—C7—O2—Dy1	−167.5 (3)
O1—C2—C7—O2	6.0 (5)	C6—C7—O2—Dy1	13.8 (6)
C3—C2—C7—C6	5.3 (6)	C2—C7—O2—Dy1i	7.9 (5)
O1—C2—C7—C6	−175.2 (3)	C6—C7—O2—Dy1i	−170.8 (3)
C5—C6—C7—O2	174.7 (4)	O2i—Dy1—O2—C7	175.7 (4)
C8—C6—C7—O2	−6.0 (6)	O1i—Dy1—O2—C7	−162.4 (3)
C5—C6—C7—C2	−4.1 (6)	O4—Dy1—O2—C7	108.9 (3)
C8—C6—C7—C2	175.3 (4)	O3—Dy1—O2—C7	67.4 (3)
C5—C6—C8—N4	176.4 (4)	N4—Dy1—O2—C7	−9.4 (3)
C7—C6—C8—N4	−3.0 (7)	O6—Dy1—O2—C7	−71.2 (3)
C15—C10—C11—C12	−1.1 (6)	N5—Dy1—O2—C7	12.5 (4)
N5—C10—C11—C12	−176.9 (4)	O8—Dy1—O2—C7	−111.5 (3)
C10—C11—C12—C13	1.8 (6)	Dy1i—Dy1—O2—C7	175.7 (4)
C11—C12—C13—C14	−1.0 (7)	O2i—Dy1—O2—Dy1i	0.0
C12—C13—C14—C15	−0.5 (6)	O1i—Dy1—O2—Dy1i	21.83 (19)
C13—C14—C15—C10	1.2 (6)	O4—Dy1—O2—Dy1i	−66.82 (12)
C13—C14—C15—S1	176.6 (3)	O3—Dy1—O2—Dy1i	−108.32 (12)
C11—C10—C15—C14	−0.5 (6)	N4—Dy1—O2—Dy1i	174.87 (13)
N5—C10—C15—C14	175.8 (4)	O6—Dy1—O2—Dy1i	113.12 (11)
C11—C10—C15—S1	−176.5 (3)	N5—Dy1—O2—Dy1i	−163.24 (12)
N5—C10—C15—S1	−0.2 (4)	O8—Dy1—O2—Dy1i	72.77 (11)
C6—C8—N4—N9	−179.2 (4)	O5—N6—O3—Dy1	−175.9 (4)
C6—C8—N4—Dy1	4.8 (7)	O4—N6—O3—Dy1	3.2 (3)
O2—Dy1—N4—C8	0.1 (4)	O2—Dy1—O3—N6	126.4 (2)
O2i—Dy1—N4—C8	9.7 (5)	O2i—Dy1—O3—N6	56.8 (2)
O1i—Dy1—N4—C8	153.4 (3)	O1i—Dy1—O3—N6	−15.6 (2)
O4—Dy1—N4—C8	−104.5 (4)	O4—Dy1—O3—N6	−1.92 (19)
O3—Dy1—N4—C8	−79.8 (4)	N4—Dy1—O3—N6	−155.1 (2)
O6—Dy1—N4—C8	116.7 (4)	O6—Dy1—O3—N6	−130.8 (2)
N5—Dy1—N4—C8	−164.5 (4)	N5—Dy1—O3—N6	−86.6 (2)
O8—Dy1—N4—C8	74.6 (4)	O8—Dy1—O3—N6	128.8 (3)
Dy1i—Dy1—N4—C8	3.5 (4)	Dy1i—Dy1—O3—N6	90.8 (2)
O2—Dy1—N4—N9	−176.0 (3)	O5—N6—O4—Dy1	175.9 (4)
O2i—Dy1—N4—N9	−166.4 (2)	O3—N6—O4—Dy1	−3.2 (3)
O1i—Dy1—N4—N9	−22.7 (3)	O2—Dy1—O4—N6	−52.3 (2)
O4—Dy1—N4—N9	79.4 (3)	O2i—Dy1—O4—N6	−118.6 (2)
O3—Dy1—N4—N9	104.2 (3)	O1i—Dy1—O4—N6	170.4 (2)
O6—Dy1—N4—N9	−59.4 (3)	O3—Dy1—O4—N6	1.91 (19)
N5—Dy1—N4—N9	19.4 (2)	N4—Dy1—O4—N6	32.4 (2)
O8—Dy1—N4—N9	−101.4 (3)	O6—Dy1—O4—N6	127.8 (2)
Dy1i—Dy1—N4—N9	−172.6 (2)	N5—Dy1—O4—N6	86.3 (2)
N9—C9—N5—C10	−175.2 (4)	O8—Dy1—O4—N6	−146.3 (2)
S1—C9—N5—C10	5.1 (4)	Dy1i—Dy1—O4—N6	−86.6 (2)
N9—C9—N5—Dy1	15.4 (5)	O7—N7—O6—Dy1	−176.6 (4)
S1—C9—N5—Dy1	−164.29 (19)	O8—N7—O6—Dy1	3.1 (4)
C11—C10—N5—C9	173.0 (4)	O2—Dy1—O6—N7	−56.8 (2)
C15—C10—N5—C9	−3.0 (5)	O2i—Dy1—O6—N7	24.1 (3)
C11—C10—N5—Dy1	−21.3 (6)	O1i—Dy1—O6—N7	81.2 (2)
C15—C10—N5—Dy1	162.7 (3)	O4—Dy1—O6—N7	123.1 (2)
O2—Dy1—N5—C9	−40.9 (3)	O3—Dy1—O6—N7	−147.7 (2)
O2i—Dy1—N5—C9	167.3 (2)	N4—Dy1—O6—N7	−122.6 (2)
O1i—Dy1—N5—C9	135.7 (3)	N5—Dy1—O6—N7	166.3 (3)
O4—Dy1—N5—C9	−148.7 (3)	O8—Dy1—O6—N7	−1.8 (2)
O3—Dy1—N5—C9	−95.1 (3)	Dy1i—Dy1—O6—N7	−16.8 (2)
N4—Dy1—N5—C9	−17.7 (3)	O7—N7—O8—Dy1	176.7 (4)
O6—Dy1—N5—C9	56.8 (3)	O6—N7—O8—Dy1	−3.0 (4)
O8—Dy1—N5—C9	67.5 (3)	O2—Dy1—O8—N7	129.1 (2)
Dy1i—Dy1—N5—C9	−108.9 (4)	O2i—Dy1—O8—N7	−153.6 (3)
O2—Dy1—N5—C10	153.8 (3)	O1i—Dy1—O8—N7	−82.3 (2)
O2i—Dy1—N5—C10	2.0 (5)	O4—Dy1—O8—N7	−125.1 (2)
O1i—Dy1—N5—C10	−29.6 (4)	O3—Dy1—O8—N7	126.7 (3)
O4—Dy1—N5—C10	46.0 (4)	N4—Dy1—O8—N7	56.0 (2)
O3—Dy1—N5—C10	99.6 (4)	O6—Dy1—O8—N7	1.8 (2)
N4—Dy1—N5—C10	177.0 (4)	N5—Dy1—O8—N7	−11.4 (3)
O6—Dy1—N5—C10	−108.5 (4)	Dy1i—Dy1—O8—N7	167.8 (3)
O8—Dy1—N5—C10	−97.8 (4)	N5—C9—S1—C15	−4.6 (3)
Dy1i—Dy1—N5—C10	85.8 (5)	N9—C9—S1—C15	175.7 (4)
N5—C9—N9—N4	3.2 (6)	C14—C15—S1—C9	−173.3 (4)
S1—C9—N9—N4	−177.1 (3)	C10—C15—S1—C9	2.4 (3)

D—H···A	D—H	H···A	D···A	D—H···A
O9—H9A···O3ii	0.84	2.64	3.206 (4)	126
O9—H9A···O8iii	0.84	2.24	3.049 (4)	161
N9—H9···O9iv	0.88	1.91	2.751 (4)	160

Table 1

Selected bond lengths (Å)

Dy1—O2	2.280 (3)
Dy1—O2i	2.374 (2)
Dy1—O1i	2.394 (3)
Dy1—O4	2.422 (3)
Dy1—O3	2.433 (3)
Dy1—N4	2.461 (3)
Dy1—O6	2.471 (3)
Dy1—N5	2.494 (3)
Dy1—O8	2.530 (3)

Symmetry code: (i) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O9—H9A⋯O3ii	0.84	2.64	3.206 (4)	126
O9—H9A⋯O8iii	0.84	2.24	3.049 (4)	161
N9—H9⋯O9iv	0.88	1.91	2.751 (4)	160

Symmetry codes: (ii) ; (iii) ; (iv) .