A trinuclear Fe-Fe-Ni complex formed by ligand reshuffling.

The title complex, dicarbonyl-3κ(2)C-(μ(3)-3,6-dimethyl-3,6-diaza-octane-1,8-dithiol-ato-1:2:3κ(7)S:S,N,N',S':S,S')(μ(2)-3,6-di-methyl-3,6-diaza-octane-1,8-dithiol-ato-1:2κ(5)S,N,N',S':S)-1,2-diiron(II)-3-nickel(0) [Fe(2)Ni(C(8)H(18)N(2)S(2))(2)(CO)(2)], is the second example showing M(μ-SR)(2)Ni(0)(CO)(2) coordination (M = any metal atom). Both Fe(II) ions are five-coordinated in distorted trigonal-bipyramidal geometries by two N atoms and three S atoms. The Ni atom is four-coordinated in a distorted tetra-hedral geometry by two S atoms and two carbonyl ligands. One of the 3,6-dimethyl-3,6-diaza-octane-1,8-dithiol-ate ligands is disordered, the major component having a refined occupancy of 0.873 (2). The Fe⋯Fe distance is 3.0945 (3)Å and the Ni⋯Fe distance is 2.8505 (3) Å.

Related literature

For the structure of [FeII(dsdm)Ni0(CO)3]2 (dsdm = 3,6-dimethyl-3,6-diazaoctane-1,8-dithiolato), see: Bouwman et al. (1999 ▶). For the structure of [NiII(N2S2′)Ni0(CO)2] (N2S2′ = 4,7-diazadecane-3,8-dione-1,10-dithiolato), see: Linck et al. (2003 ▶). For the structure of [FeII(dsdm)]2, see: Hu & Lippard (1974 ▶). The synthesis of the starting materials [Et4N][FeII(CN)2(CO)3I] and [NiII(dsdm)] has been described by Jiang et al. (2009 ▶) and Turner et al. (1990 ▶). For structures of Ni–Fe hydrogenase active sites, see: Fontecilla-Camps et al. (2007 ▶). Structure checking was performed using PLATON (Spek, 2009 ▶).

Experimental

Crystal data

[Fe2Ni(C8H18N2S2)2(CO)2]

M = 639.16

Triclinic,

a = 8.4051 (3) Å

b = 12.7146 (5) Å

c = 13.3451 (5) Å

α = 70.475 (1)°

β = 83.208 (1)°

γ = 79.309 (1)°

V = 1318.38 (9) Å3

Z = 2

Mo Kα radiation

μ = 2.13 mm−1

T = 173 K

0.35 × 0.10 × 0.10 mm

Data collection

Bruker SMART CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 2004 ▶) T min = 0.774, T max = 0.808

41649 measured reflections

6596 independent reflections

5863 reflections with I > 2σ(I)

R int = 0.026

Refinement

R[F 2 > 2σ(F 2)] = 0.022

wR(F 2) = 0.056

S = 1.07

6596 reflections

301 parameters

2 restraints

H-atom parameters constrained

Δρmax = 0.84 e Å−3

Δρmin = −0.31 e Å−3

Data collection: SMART (Bruker, 2003 ▶); cell refinement: SAINT (Bruker, 2003 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536811017892/pk2319sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811017892/pk2319Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Fe2Ni(C8H18N2S2)2(CO)2]	Z = 2
Mr = 639.16	F(000) = 664
Triclinic, P1	Dx = 1.610 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.4051 (3) Å	Cell parameters from 300 reflections
b = 12.7146 (5) Å	θ = 2.5–28.4°
c = 13.3451 (5) Å	µ = 2.13 mm−1
α = 70.475 (1)°	T = 173 K
β = 83.208 (1)°	Needle, black
γ = 79.309 (1)°	0.35 × 0.10 × 0.10 mm
V = 1318.38 (9) Å3

Bruker SMART CCD area-detector diffractometer	6596 independent reflections
Radiation source: fine-focus sealed tube	5863 reflections with I > 2σ(I)
graphite	Rint = 0.026
φ and ω scans	θmax = 28.4°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Sheldrick, 2004)	h = −11→11
Tmin = 0.774, Tmax = 0.808	k = −16→16
41649 measured reflections	l = −17→17

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.022	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.056	H-atom parameters constrained
S = 1.07	w = 1/[σ2(Fo2) + (0.0257P)2 + 0.7211P] where P = (Fo2 + 2Fc2)/3
6596 reflections	(Δ/σ)max = 0.001
301 parameters	Δρmax = 0.84 e Å−3
2 restraints	Δρmin = −0.31 e Å−3

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Fe1	0.16309 (2)	0.133392 (18)	0.257975 (16)	0.01240 (5)
Fe2	0.09584 (2)	0.348721 (18)	0.325379 (16)	0.01218 (5)
Ni3	0.28724 (2)	0.242434 (17)	0.047760 (16)	0.01672 (5)
S1	0.43299 (4)	0.11355 (3)	0.18653 (3)	0.01652 (8)
S2	0.10001 (4)	0.33301 (3)	0.15138 (3)	0.01364 (7)
S3	−0.16068 (4)	0.39578 (3)	0.39741 (3)	0.01589 (8)
S4	0.14979 (5)	0.14843 (3)	0.43141 (3)	0.01533 (8)
C1	0.4545 (2)	−0.02863 (14)	0.17643 (14)	0.0227 (3)
H1A	0.5104	−0.0291	0.1087	0.027*
H1B	0.5207	−0.0810	0.2325	0.027*
C2	0.29216 (19)	−0.06906 (14)	0.18532 (13)	0.0200 (3)
H2A	0.2377	−0.0295	0.1199	0.024*
H2B	0.3114	−0.1490	0.1936	0.024*
C3	0.02134 (19)	−0.07559 (13)	0.27173 (13)	0.0176 (3)
H3A	−0.0332	−0.0923	0.3422	0.021*
H3B	0.0314	−0.1417	0.2492	0.021*
C4	−0.07916 (19)	0.02363 (13)	0.19473 (13)	0.0170 (3)
H4A	−0.0334	0.0330	0.1226	0.020*
H4B	−0.1889	0.0082	0.1987	0.020*
C5	−0.14768 (18)	0.22706 (13)	0.12884 (12)	0.0158 (3)
H5A	−0.2637	0.2297	0.1283	0.019*
H5B	−0.0978	0.2168	0.0627	0.019*
C6	−0.11543 (18)	0.33834 (13)	0.13483 (12)	0.0158 (3)
H6A	−0.1801	0.3552	0.1944	0.019*
H6B	−0.1478	0.3985	0.0702	0.019*
C7	0.2542 (2)	−0.12185 (14)	0.37795 (14)	0.0229 (3)
H7A	0.1806	−0.1121	0.4360	0.034*
H7B	0.3559	−0.1004	0.3830	0.034*
H7C	0.2713	−0.1996	0.3810	0.034*
C8	−0.18756 (18)	0.12685 (14)	0.31805 (12)	0.0168 (3)
H8A	−0.2950	0.1178	0.3084	0.025*
H8B	−0.1918	0.1964	0.3326	0.025*
H8C	−0.1433	0.0648	0.3767	0.025*
C9	−0.1930 (2)	0.54613 (14)	0.32196 (14)	0.0213 (3)
H9A	−0.2153	0.5564	0.2493	0.026*
H9B	−0.2860	0.5840	0.3536	0.026*
C10	−0.04347 (19)	0.59781 (13)	0.32169 (13)	0.0193 (3)
H10A	−0.0647	0.6784	0.2848	0.023*
H10B	−0.0214	0.5869	0.3945	0.023*
C15	0.0975 (2)	0.59951 (14)	0.15256 (13)	0.0237 (3)
H15A	0.1044	0.6783	0.1340	0.036*
H15B	−0.0019	0.5911	0.1293	0.036*
H15C	0.1878	0.5634	0.1185	0.036*
C17	0.2083 (2)	0.18224 (14)	−0.03214 (13)	0.0216 (3)
C18	0.4093 (2)	0.34856 (16)	−0.02072 (14)	0.0274 (4)
C11A	0.2515 (4)	0.5652 (2)	0.3033 (3)	0.0152 (6)	0.873 (2)
H11A	0.2306	0.6334	0.3232	0.018*	0.873 (2)
H11B	0.3338	0.5747	0.2449	0.018*	0.873 (2)
C12A	0.3122 (2)	0.46365 (15)	0.39850 (14)	0.0166 (3)	0.873 (2)
H12A	0.4172	0.4723	0.4153	0.020*	0.873 (2)
H12B	0.2376	0.4622	0.4601	0.020*	0.873 (2)
C13A	0.3720 (2)	0.26051 (15)	0.47315 (14)	0.0187 (4)	0.873 (2)
H13A	0.3039	0.2722	0.5336	0.022*	0.873 (2)
H13B	0.4835	0.2593	0.4864	0.022*	0.873 (2)
C14A	0.3555 (3)	0.1464 (4)	0.4646 (2)	0.0190 (7)	0.873 (2)
H14A	0.3792	0.0876	0.5318	0.023*	0.873 (2)
H14B	0.4329	0.1296	0.4100	0.023*	0.873 (2)
C16A	0.4504 (2)	0.35148 (16)	0.28764 (14)	0.0179 (4)	0.873 (2)
H16A	0.4154	0.4095	0.2234	0.027*	0.873 (2)
H16B	0.4629	0.2790	0.2776	0.027*	0.873 (2)
H16C	0.5523	0.3632	0.3045	0.027*	0.873 (2)
C11B	0.258 (3)	0.544 (2)	0.317 (3)	0.0152 (6)	0.127 (2)
H11C	0.2967	0.6154	0.2801	0.018*	0.127 (2)
H11D	0.2327	0.5404	0.3907	0.018*	0.127 (2)
C12B	0.3875 (15)	0.4560 (10)	0.3141 (10)	0.0166 (3)	0.127 (2)
H12C	0.4824	0.4642	0.3440	0.020*	0.127 (2)
H12D	0.4161	0.4556	0.2416	0.020*	0.127 (2)
C13B	0.4403 (15)	0.2509 (10)	0.3774 (10)	0.0187 (4)	0.127 (2)
H13C	0.5410	0.2506	0.4064	0.022*	0.127 (2)
H13D	0.4649	0.2498	0.3049	0.022*	0.127 (2)
C14B	0.368 (2)	0.145 (4)	0.444 (3)	0.0190 (7)	0.127 (2)
H14C	0.3846	0.1305	0.5184	0.023*	0.127 (2)
H14D	0.4285	0.0809	0.4243	0.023*	0.127 (2)
C16B	0.3161 (15)	0.3535 (11)	0.4984 (10)	0.0179 (4)	0.127 (2)
H16D	0.4235	0.3431	0.5213	0.027*	0.127 (2)
H16E	0.2618	0.2923	0.5425	0.027*	0.127 (2)
H16F	0.2565	0.4236	0.5040	0.027*	0.127 (2)
N1	0.18488 (15)	−0.05031 (11)	0.27614 (10)	0.0160 (3)
N2	−0.08327 (15)	0.12932 (11)	0.21968 (10)	0.0137 (2)
N3	0.10106 (16)	0.54665 (11)	0.26911 (10)	0.0163 (3)
N4	0.32667 (15)	0.35576 (11)	0.37691 (10)	0.0146 (2)
O1	0.16438 (17)	0.14540 (12)	−0.08973 (11)	0.0326 (3)
O2	0.4842 (2)	0.41629 (15)	−0.06992 (14)	0.0542 (5)

	U11	U22	U33	U12	U13	U23
Fe1	0.01141 (10)	0.01167 (10)	0.01369 (10)	−0.00240 (7)	−0.00188 (7)	−0.00282 (8)
Fe2	0.01255 (10)	0.01202 (10)	0.01194 (10)	−0.00203 (8)	−0.00163 (7)	−0.00344 (8)
Ni3	0.01734 (10)	0.01883 (11)	0.01431 (10)	−0.00452 (8)	0.00068 (7)	−0.00536 (8)
S1	0.01209 (16)	0.01827 (18)	0.01966 (18)	−0.00310 (13)	−0.00083 (13)	−0.00635 (15)
S2	0.01514 (17)	0.01348 (17)	0.01239 (16)	−0.00337 (13)	−0.00058 (12)	−0.00372 (13)
S3	0.01420 (17)	0.01595 (18)	0.01823 (18)	−0.00223 (13)	−0.00011 (13)	−0.00679 (14)
S4	0.01799 (17)	0.01352 (17)	0.01314 (16)	−0.00435 (13)	−0.00200 (13)	−0.00111 (13)
C1	0.0172 (8)	0.0192 (8)	0.0312 (9)	0.0001 (6)	0.0009 (6)	−0.0099 (7)
C2	0.0194 (8)	0.0162 (8)	0.0255 (8)	−0.0008 (6)	−0.0006 (6)	−0.0096 (6)
C3	0.0189 (7)	0.0141 (7)	0.0211 (8)	−0.0060 (6)	−0.0020 (6)	−0.0051 (6)
C4	0.0160 (7)	0.0164 (7)	0.0216 (8)	−0.0046 (6)	−0.0034 (6)	−0.0081 (6)
C5	0.0149 (7)	0.0174 (7)	0.0146 (7)	−0.0013 (6)	−0.0042 (5)	−0.0040 (6)
C6	0.0153 (7)	0.0160 (7)	0.0146 (7)	0.0002 (5)	−0.0035 (5)	−0.0034 (6)
C7	0.0265 (8)	0.0152 (8)	0.0243 (8)	−0.0022 (6)	−0.0092 (7)	−0.0009 (6)
C8	0.0144 (7)	0.0192 (8)	0.0160 (7)	−0.0037 (6)	0.0007 (5)	−0.0045 (6)
C9	0.0194 (8)	0.0171 (8)	0.0268 (8)	0.0013 (6)	−0.0065 (6)	−0.0069 (7)
C10	0.0220 (8)	0.0128 (7)	0.0230 (8)	0.0001 (6)	−0.0041 (6)	−0.0059 (6)
C15	0.0357 (10)	0.0173 (8)	0.0159 (7)	−0.0050 (7)	−0.0054 (7)	−0.0006 (6)
C17	0.0215 (8)	0.0216 (8)	0.0208 (8)	0.0032 (6)	−0.0030 (6)	−0.0085 (7)
C18	0.0265 (9)	0.0300 (10)	0.0227 (8)	−0.0067 (7)	0.0054 (7)	−0.0054 (7)
C11A	0.0210 (8)	0.0065 (16)	0.0164 (14)	−0.0054 (9)	−0.0018 (7)	0.0006 (12)
C12A	0.0185 (8)	0.0157 (8)	0.0174 (8)	−0.0044 (6)	−0.0033 (6)	−0.0060 (7)
C13A	0.0210 (9)	0.0168 (9)	0.0174 (8)	−0.0032 (7)	−0.0093 (7)	−0.0012 (7)
C14A	0.0208 (9)	0.0154 (8)	0.0191 (18)	−0.0020 (8)	−0.0099 (9)	−0.0008 (13)
C16A	0.0153 (8)	0.0186 (9)	0.0210 (9)	−0.0038 (7)	0.0010 (6)	−0.0080 (7)
C11B	0.0210 (8)	0.0065 (16)	0.0164 (14)	−0.0054 (9)	−0.0018 (7)	0.0006 (12)
C12B	0.0185 (8)	0.0157 (8)	0.0174 (8)	−0.0044 (6)	−0.0033 (6)	−0.0060 (7)
C13B	0.0210 (9)	0.0168 (9)	0.0174 (8)	−0.0032 (7)	−0.0093 (7)	−0.0012 (7)
C14B	0.0208 (9)	0.0154 (8)	0.0191 (18)	−0.0020 (8)	−0.0099 (9)	−0.0008 (13)
C16B	0.0153 (8)	0.0186 (9)	0.0210 (9)	−0.0038 (7)	0.0010 (6)	−0.0080 (7)
N1	0.0151 (6)	0.0137 (6)	0.0184 (6)	−0.0022 (5)	−0.0025 (5)	−0.0038 (5)
N2	0.0141 (6)	0.0132 (6)	0.0141 (6)	−0.0027 (5)	−0.0017 (5)	−0.0040 (5)
N3	0.0210 (6)	0.0133 (6)	0.0145 (6)	−0.0033 (5)	−0.0028 (5)	−0.0033 (5)
N4	0.0150 (6)	0.0131 (6)	0.0153 (6)	−0.0029 (5)	−0.0017 (5)	−0.0035 (5)
O1	0.0367 (7)	0.0340 (7)	0.0341 (7)	0.0055 (6)	−0.0133 (6)	−0.0223 (6)
O2	0.0591 (11)	0.0505 (10)	0.0465 (10)	−0.0323 (9)	0.0199 (8)	−0.0022 (8)

Fe1—N2	2.2044 (12)	C8—H8C	0.9600
Fe1—N1	2.2408 (13)	C9—C10	1.521 (2)
Fe1—S1	2.3570 (4)	C9—H9A	0.9700
Fe1—S4	2.3734 (4)	C9—H9B	0.9700
Fe1—S2	2.4519 (4)	C10—N3	1.484 (2)
Fe1—Ni3	2.8505 (3)	C10—H10A	0.9700
Fe1—Fe2	3.0945 (3)	C10—H10B	0.9700
Fe2—N4	2.1601 (13)	C15—N3	1.475 (2)
Fe2—S3	2.3122 (4)	C15—H15A	0.9600
Fe2—N3	2.3809 (13)	C15—H15B	0.9600
Fe2—S2	2.3919 (4)	C15—H15C	0.9600
Fe2—S4	2.4511 (4)	C17—O1	1.148 (2)
Ni3—C17	1.7506 (17)	C18—O2	1.138 (2)
Ni3—C18	1.7821 (18)	C11A—N3	1.477 (3)
Ni3—S1	2.3193 (4)	C11A—C12A	1.535 (3)
Ni3—S2	2.3648 (4)	C11A—H11A	0.9700
S1—C1	1.8316 (17)	C11A—H11B	0.9700
S2—C6	1.8361 (15)	C12A—N4	1.474 (2)
S3—C9	1.8240 (17)	C12A—H12A	0.9700
S4—C14A	1.829 (3)	C12A—H12B	0.9700
S4—C14B	1.851 (19)	C13A—N4	1.472 (2)
C1—C2	1.523 (2)	C13A—C14A	1.525 (5)
C1—H1A	0.9700	C13A—H13A	0.9700
C1—H1B	0.9700	C13A—H13B	0.9700
C2—N1	1.481 (2)	C14A—H14A	0.9700
C2—H2A	0.9700	C14A—H14B	0.9700
C2—H2B	0.9700	C16A—N4	1.494 (2)
C3—N1	1.481 (2)	C16A—H16A	0.9600
C3—C4	1.518 (2)	C16A—H16B	0.9600
C3—H3A	0.9700	C16A—H16C	0.9600
C3—H3B	0.9700	C11B—C12B	1.42 (3)
C4—N2	1.4823 (19)	C11B—N3	1.523 (18)
C4—H4A	0.9700	C11B—H11C	0.9700
C4—H4B	0.9700	C11B—H11D	0.9700
C5—N2	1.4851 (19)	C12B—N4	1.420 (12)
C5—C6	1.518 (2)	C12B—H12C	0.9700
C5—H5A	0.9700	C12B—H12D	0.9700
C5—H5B	0.9700	C13B—N4	1.488 (13)
C6—H6A	0.9700	C13B—C14B	1.54 (4)
C6—H6B	0.9700	C13B—H13C	0.9700
C7—N1	1.476 (2)	C13B—H13D	0.9700
C7—H7A	0.9600	C14B—H14C	0.9700
C7—H7B	0.9600	C14B—H14D	0.9700
C7—H7C	0.9600	C16B—N4	1.604 (12)
C8—N2	1.4843 (19)	C16B—H16D	0.9600
C8—H8A	0.9600	C16B—H16E	0.9600
C8—H8B	0.9600	C16B—H16F	0.9600
N2—Fe1—N1	80.24 (5)	H9A—C9—H9B	108.1
N2—Fe1—S1	139.76 (3)	N3—C10—C9	111.84 (13)
N1—Fe1—S1	84.02 (3)	N3—C10—H10A	109.2
N2—Fe1—S4	108.57 (3)	C9—C10—H10A	109.2
N1—Fe1—S4	107.46 (4)	N3—C10—H10B	109.2
S1—Fe1—S4	111.447 (15)	C9—C10—H10B	109.2
N2—Fe1—S2	82.61 (3)	H10A—C10—H10B	107.9
N1—Fe1—S2	150.54 (4)	N3—C15—H15A	109.5
S1—Fe1—S2	94.015 (15)	N3—C15—H15B	109.5
S4—Fe1—S2	100.626 (14)	H15A—C15—H15B	109.5
N2—Fe1—Ni3	98.29 (3)	N3—C15—H15C	109.5
N1—Fe1—Ni3	106.94 (3)	H15A—C15—H15C	109.5
S1—Fe1—Ni3	51.843 (11)	H15B—C15—H15C	109.5
S4—Fe1—Ni3	139.189 (13)	O1—C17—Ni3	175.39 (16)
S2—Fe1—Ni3	52.316 (10)	O2—C18—Ni3	175.96 (19)
N2—Fe1—Fe2	99.68 (3)	N3—C11A—C12A	109.62 (19)
N1—Fe1—Fe2	157.78 (3)	N3—C11A—H11A	109.7
S1—Fe1—Fe2	108.341 (13)	C12A—C11A—H11A	109.7
S4—Fe1—Fe2	51.214 (11)	N3—C11A—H11B	109.7
S2—Fe1—Fe2	49.442 (10)	C12A—C11A—H11B	109.7
Ni3—Fe1—Fe2	95.102 (8)	H11A—C11A—H11B	108.2
N4—Fe2—S3	128.04 (4)	N4—C12A—C11A	112.07 (19)
N4—Fe2—N3	77.79 (5)	N4—C12A—H12A	109.2
S3—Fe2—N3	84.35 (3)	C11A—C12A—H12A	109.2
N4—Fe2—S2	115.98 (4)	N4—C12A—H12B	109.2
S3—Fe2—S2	114.298 (15)	C11A—C12A—H12B	109.2
N3—Fe2—S2	96.66 (3)	H12A—C12A—H12B	107.9
N4—Fe2—S4	84.21 (4)	N4—C13A—C14A	113.18 (18)
S3—Fe2—S4	99.308 (15)	N4—C13A—H13A	108.9
N3—Fe2—S4	159.44 (3)	C14A—C13A—H13A	108.9
S2—Fe2—S4	100.131 (14)	N4—C13A—H13B	108.9
N4—Fe2—Fe1	103.49 (3)	C14A—C13A—H13B	108.9
S3—Fe2—Fe1	117.732 (13)	H13A—C13A—H13B	107.8
N3—Fe2—Fe1	145.50 (3)	C13A—C14A—S4	110.2 (3)
S2—Fe2—Fe1	51.154 (10)	C13A—C14A—H14A	109.6
S4—Fe2—Fe1	49.007 (10)	S4—C14A—H14A	109.6
C17—Ni3—C18	115.76 (8)	C13A—C14A—H14B	109.6
C17—Ni3—S1	114.68 (6)	S4—C14A—H14B	109.6
C18—Ni3—S1	107.23 (6)	H14A—C14A—H14B	108.1
C17—Ni3—S2	117.38 (5)	N4—C16A—H16A	109.5
C18—Ni3—S2	102.18 (6)	N4—C16A—H16B	109.5
S1—Ni3—S2	97.362 (15)	N4—C16A—H16C	109.5
C17—Ni3—Fe1	104.28 (6)	C12B—C11B—N3	118 (2)
C18—Ni3—Fe1	139.94 (6)	C12B—C11B—H11C	107.9
S1—Ni3—Fe1	53.046 (11)	N3—C11B—H11C	107.9
S2—Ni3—Fe1	55.140 (11)	C12B—C11B—H11D	107.9
C1—S1—Ni3	109.86 (6)	N3—C11B—H11D	107.9
C1—S1—Fe1	100.08 (5)	H11C—C11B—H11D	107.2
Ni3—S1—Fe1	75.111 (13)	C11B—C12B—N4	104.5 (15)
C6—S2—Ni3	116.05 (5)	C11B—C12B—H12C	110.9
C6—S2—Fe2	102.65 (5)	N4—C12B—H12C	110.9
Ni3—S2—Fe2	134.701 (17)	C11B—C12B—H12D	110.9
C6—S2—Fe1	98.77 (5)	N4—C12B—H12D	110.9
Ni3—S2—Fe1	72.544 (12)	H12C—C12B—H12D	108.9
Fe2—S2—Fe1	79.404 (13)	N4—C13B—C14B	111.5 (14)
C9—S3—Fe2	98.25 (6)	N4—C13B—H13C	109.3
C14A—S4—C14B	9.0 (10)	C14B—C13B—H13C	109.3
C14A—S4—Fe1	108.34 (8)	N4—C13B—H13D	109.3
C14B—S4—Fe1	99.3 (10)	C14B—C13B—H13D	109.3
C14A—S4—Fe2	97.46 (16)	H13C—C13B—H13D	108.0
C14B—S4—Fe2	96.0 (13)	C13B—C14B—S4	116 (2)
Fe1—S4—Fe2	79.779 (13)	C13B—C14B—H14C	108.2
C2—C1—S1	112.85 (11)	S4—C14B—H14C	108.2
C2—C1—H1A	109.0	C13B—C14B—H14D	108.2
S1—C1—H1A	109.0	S4—C14B—H14D	108.2
C2—C1—H1B	109.0	H14C—C14B—H14D	107.3
S1—C1—H1B	109.0	N4—C16B—H16D	109.5
H1A—C1—H1B	107.8	N4—C16B—H16E	109.5
N1—C2—C1	112.68 (13)	H16D—C16B—H16E	109.5
N1—C2—H2A	109.1	N4—C16B—H16F	109.5
C1—C2—H2A	109.1	H16D—C16B—H16F	109.5
N1—C2—H2B	109.1	H16E—C16B—H16F	109.5
C1—C2—H2B	109.1	C7—N1—C3	109.93 (13)
H2A—C2—H2B	107.8	C7—N1—C2	110.37 (13)
N1—C3—C4	110.94 (12)	C3—N1—C2	110.25 (12)
N1—C3—H3A	109.5	C7—N1—Fe1	111.07 (10)
C4—C3—H3A	109.5	C3—N1—Fe1	108.42 (9)
N1—C3—H3B	109.5	C2—N1—Fe1	106.74 (9)
C4—C3—H3B	109.5	C4—N2—C8	110.02 (12)
H3A—C3—H3B	108.0	C4—N2—C5	109.08 (12)
N2—C4—C3	111.19 (12)	C8—N2—C5	110.03 (12)
N2—C4—H4A	109.4	C4—N2—Fe1	107.80 (9)
C3—C4—H4A	109.4	C8—N2—Fe1	105.61 (9)
N2—C4—H4B	109.4	C5—N2—Fe1	114.21 (9)
C3—C4—H4B	109.4	C15—N3—C11A	108.35 (18)
H4A—C4—H4B	108.0	C15—N3—C10	109.56 (13)
N2—C5—C6	112.18 (12)	C11A—N3—C10	110.6 (2)
N2—C5—H5A	109.2	C15—N3—C11B	115.6 (14)
C6—C5—H5A	109.2	C11A—N3—C11B	10.1 (12)
N2—C5—H5B	109.2	C10—N3—C11B	112.4 (14)
C6—C5—H5B	109.2	C15—N3—Fe2	112.91 (10)
H5A—C5—H5B	107.9	C11A—N3—Fe2	108.45 (12)
C5—C6—S2	111.27 (10)	C10—N3—Fe2	107.01 (9)
C5—C6—H6A	109.4	C11B—N3—Fe2	98.7 (11)
S2—C6—H6A	109.4	C12B—N4—C13A	136.8 (5)
C5—C6—H6B	109.4	C12B—N4—C12A	51.1 (5)
S2—C6—H6B	109.4	C13A—N4—C12A	110.12 (13)
H6A—C6—H6B	108.0	C12B—N4—C13B	113.3 (7)
N1—C7—H7A	109.5	C13A—N4—C13B	55.2 (5)
N1—C7—H7B	109.5	C12A—N4—C13B	143.5 (5)
H7A—C7—H7B	109.5	C12B—N4—C16A	60.8 (5)
N1—C7—H7C	109.5	C13A—N4—C16A	109.72 (13)
H7A—C7—H7C	109.5	C12A—N4—C16A	110.66 (13)
H7B—C7—H7C	109.5	C13B—N4—C16A	57.7 (5)
N2—C8—H8A	109.5	C12B—N4—C16B	106.9 (7)
N2—C8—H8B	109.5	C13A—N4—C16B	50.8 (5)
H8A—C8—H8B	109.5	C12A—N4—C16B	61.5 (5)
N2—C8—H8C	109.5	C13B—N4—C16B	103.5 (7)
H8A—C8—H8C	109.5	C16A—N4—C16B	139.9 (4)
H8B—C8—H8C	109.5	C12B—N4—Fe2	111.3 (5)
C10—C9—S3	110.20 (11)	C13A—N4—Fe2	111.61 (10)
C10—C9—H9A	109.6	C12A—N4—Fe2	107.49 (10)
S3—C9—H9A	109.6	C13B—N4—Fe2	109.0 (5)
C10—C9—H9B	109.6	C16A—N4—Fe2	107.19 (10)
S3—C9—H9B	109.6	C16B—N4—Fe2	112.6 (4)