Acrinathrin: (S)-cyano-(3-phen-oxy-phenyl)methyl (Z)-(1R,3S)-2,2-dimethyl-3-{2-[2,2,2-trifluoro-1-(trifluoro-methyl)eth-oxy-carbon-yl]vin-yl}cyclo-propane-1-carboxyl-ate.

In the title compound, C(26)H(21)F(6)NO(5), the dihedral angle between the cyclo-propane ring plane and the vinyl group plane is 79.3 (3)°. The dihedral angle between the benzene and phenyl ring planes in the phen-oxy-benzyl group is 82.7 (1)°. In the crystal structure, weak inter-molecular C-H⋯π inter-actions and C-H⋯F hydrogen bonds contribute to the stabilization of the packing.

Related literature

For information on the insecticidal activity of the title compound, see: Vilchez et al. (1997 ▶). For related crystal structures, see: Owen (1976 ▶); Babin et al. (1992 ▶); Lei et al. (2001 ▶).

Experimental

Crystal data

C26H21F6NO5

M = 541.44

Orthorhombic,

a = 7.4932 (2) Å

b = 9.2679 (2) Å

c = 36.9165 (8) Å

V = 2563.71 (10) Å3

Z = 4

Mo Kα radiation

μ = 0.13 mm−1

T = 173 K

0.17 × 0.14 × 0.13 mm

Data collection

Bruker APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.979, T max = 0.984

24962 measured reflections

3634 independent reflections

2868 reflections with I > 2σ(I)

R int = 0.042

Refinement

R[F 2 > 2σ(F 2)] = 0.043

wR(F 2) = 0.099

S = 1.06

3634 reflections

345 parameters

H-atom parameters constrained

Δρmax = 0.29 e Å−3

Δρmin = −0.20 e Å−3

Data collection: APEX2 (Bruker, 2006 ▶); cell refinement: SAINT (Bruker, 2006 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL and DIAMOND (Brandenburg, 1998 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536811014760/wn2431sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811014760/wn2431Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C26H21F6NO5	F(000) = 1112
Mr = 541.44	Dx = 1.403 Mg m−3
Orthorhombic, P212121	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2ab	Cell parameters from 6226 reflections
a = 7.4932 (2) Å	θ = 2.3–23.1°
b = 9.2679 (2) Å	µ = 0.13 mm−1
c = 36.9165 (8) Å	T = 173 K
V = 2563.71 (10) Å3	Plate, colourless
Z = 4	0.17 × 0.14 × 0.13 mm

Bruker APEXII CCD diffractometer	3634 independent reflections
Radiation source: fine-focus sealed tube	2868 reflections with I > 2σ(I)
graphite	Rint = 0.042
φ and ω scans	θmax = 28.3°, θmin = 2.2°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −7→9
Tmin = 0.979, Tmax = 0.984	k = −12→12
24962 measured reflections	l = −49→42

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.043	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.099	H-atom parameters constrained
S = 1.06	w = 1/[σ2(Fo2) + (0.0327P)2 + 0.8807P] where P = (Fo2 + 2Fc2)/3
3634 reflections	(Δ/σ)max = 0.001
345 parameters	Δρmax = 0.29 e Å−3
0 restraints	Δρmin = −0.20 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
F1	0.9406 (3)	0.7188 (4)	0.39798 (7)	0.1086 (9)
F2	0.8936 (3)	0.6123 (3)	0.44823 (6)	0.0915 (7)
F3	0.9197 (3)	0.8418 (3)	0.44673 (7)	0.0964 (8)
F4	0.5707 (4)	0.6522 (2)	0.47933 (5)	0.0852 (7)
F5	0.5953 (4)	0.8812 (2)	0.47448 (6)	0.1013 (9)
F6	0.3792 (3)	0.7694 (3)	0.44896 (7)	0.0873 (7)
O1	0.6010 (3)	0.61863 (19)	0.40474 (5)	0.0423 (5)
O2	0.4704 (3)	0.7556 (2)	0.36230 (5)	0.0566 (6)
O3	0.3658 (3)	0.3918 (2)	0.25488 (5)	0.0545 (6)
O4	0.3278 (2)	0.57874 (18)	0.21721 (4)	0.0337 (4)
O5	−0.0634 (2)	0.6201 (3)	0.10760 (5)	0.0673 (8)
N1	0.7583 (4)	0.5008 (3)	0.20012 (6)	0.0564 (7)
C1	0.8548 (5)	0.7284 (4)	0.42894 (10)	0.0629 (9)
C2	0.5516 (5)	0.7623 (4)	0.45687 (9)	0.0610 (9)
C3	0.6580 (4)	0.7456 (3)	0.42269 (7)	0.0431 (7)
H3	0.6367	0.8309	0.4067	0.052*
C4	0.5049 (4)	0.6380 (3)	0.37320 (7)	0.0375 (6)
C5	0.4624 (4)	0.4984 (3)	0.35754 (6)	0.0412 (7)
H5	0.5242	0.4163	0.3665	0.049*
C6	0.3425 (4)	0.4784 (3)	0.33150 (6)	0.0412 (7)
H6	0.3310	0.3832	0.3223	0.049*
C7	0.2268 (4)	0.5881 (3)	0.31574 (6)	0.0366 (6)
H7	0.2238	0.6811	0.3295	0.044*
C8	0.0544 (4)	0.5510 (3)	0.29675 (7)	0.0437 (7)
C9	0.2095 (4)	0.6050 (3)	0.27442 (6)	0.0384 (6)
H9	0.1973	0.7070	0.2659	0.046*
C10	−0.0072 (5)	0.3963 (4)	0.29394 (9)	0.0660 (10)
H10B	0.0954	0.3340	0.2888	0.099*
H10A	−0.0947	0.3877	0.2743	0.099*
H10C	−0.0622	0.3670	0.3169	0.099*
C11	−0.0958 (4)	0.6583 (4)	0.30134 (9)	0.0614 (9)
H11A	−0.1767	0.6520	0.2805	0.092*
H11B	−0.0465	0.7560	0.3029	0.092*
H11C	−0.1617	0.6364	0.3236	0.092*
C12	0.3083 (4)	0.5105 (3)	0.24965 (6)	0.0378 (6)
C13	0.4145 (3)	0.4969 (3)	0.18922 (6)	0.0304 (5)
H13	0.3725	0.3946	0.1905	0.036*
C14	0.6090 (4)	0.4999 (3)	0.19511 (6)	0.0394 (6)
C15	0.3567 (3)	0.5607 (3)	0.15333 (6)	0.0278 (5)
C16	0.4784 (3)	0.6086 (3)	0.12799 (6)	0.0314 (5)
H16	0.6028	0.6030	0.1328	0.038*
C17	0.4178 (3)	0.6650 (3)	0.09551 (6)	0.0344 (6)
H17	0.5014	0.6983	0.0781	0.041*
C18	0.2380 (3)	0.6735 (3)	0.08809 (6)	0.0339 (6)
H18	0.1972	0.7142	0.0660	0.041*
C19	0.1186 (3)	0.6220 (3)	0.11322 (7)	0.0369 (6)
C20	0.1758 (3)	0.5663 (3)	0.14596 (6)	0.0371 (6)
H20	0.0918	0.5321	0.1632	0.044*
C21	−0.1298 (3)	0.6912 (4)	0.07707 (7)	0.0426 (7)
C22	−0.1479 (4)	0.8371 (4)	0.07716 (8)	0.0487 (7)
H22	−0.1069	0.8922	0.0972	0.058*
C23	−0.2266 (4)	0.9048 (4)	0.04787 (9)	0.0542 (8)
H23	−0.2392	1.0068	0.0477	0.065*
C24	−0.2859 (4)	0.8259 (4)	0.01934 (8)	0.0506 (8)
H24	−0.3414	0.8728	−0.0006	0.061*
C25	−0.2664 (4)	0.6809 (4)	0.01912 (8)	0.0522 (8)
H25	−0.3072	0.6267	−0.0011	0.063*
C26	−0.1869 (4)	0.6104 (4)	0.04824 (8)	0.0501 (7)
H26	−0.1727	0.5086	0.0481	0.060*

	U11	U22	U33	U12	U13	U23
F1	0.0654 (14)	0.164 (3)	0.0968 (17)	−0.0054 (18)	0.0156 (14)	0.0000 (18)
F2	0.0805 (16)	0.0831 (15)	0.1108 (17)	0.0176 (14)	−0.0389 (14)	0.0186 (14)
F3	0.0823 (16)	0.0920 (17)	0.1148 (18)	−0.0321 (14)	−0.0483 (15)	0.0006 (15)
F4	0.128 (2)	0.0805 (14)	0.0467 (10)	−0.0099 (15)	0.0096 (13)	0.0122 (11)
F5	0.148 (2)	0.0745 (14)	0.0815 (14)	−0.0317 (17)	0.0167 (16)	−0.0427 (13)
F6	0.0680 (14)	0.0754 (15)	0.1185 (19)	0.0067 (13)	0.0178 (14)	−0.0171 (15)
O1	0.0582 (12)	0.0328 (9)	0.0358 (9)	0.0009 (10)	−0.0143 (9)	0.0010 (8)
O2	0.0780 (16)	0.0350 (10)	0.0567 (12)	−0.0099 (11)	−0.0328 (12)	0.0126 (10)
O3	0.0876 (16)	0.0437 (11)	0.0322 (9)	0.0203 (12)	0.0059 (10)	0.0060 (9)
O4	0.0429 (10)	0.0363 (9)	0.0220 (7)	0.0062 (8)	−0.0007 (7)	0.0018 (7)
O5	0.0226 (9)	0.124 (2)	0.0551 (12)	−0.0031 (13)	−0.0015 (9)	0.0512 (14)
N1	0.0415 (15)	0.081 (2)	0.0462 (14)	0.0060 (15)	−0.0110 (12)	0.0057 (14)
C1	0.059 (2)	0.066 (2)	0.063 (2)	−0.0061 (19)	−0.0203 (18)	0.0057 (19)
C2	0.079 (3)	0.0510 (19)	0.0535 (18)	−0.007 (2)	0.0002 (18)	−0.0089 (17)
C3	0.0546 (17)	0.0342 (13)	0.0406 (14)	−0.0057 (14)	−0.0144 (13)	0.0024 (13)
C4	0.0439 (16)	0.0384 (14)	0.0300 (12)	−0.0039 (13)	−0.0055 (12)	0.0061 (11)
C5	0.0659 (19)	0.0307 (12)	0.0270 (12)	−0.0002 (14)	−0.0048 (13)	0.0051 (11)
C6	0.0648 (19)	0.0347 (13)	0.0242 (12)	−0.0046 (14)	−0.0021 (13)	−0.0011 (11)
C7	0.0490 (16)	0.0368 (13)	0.0240 (11)	−0.0020 (12)	0.0003 (11)	−0.0044 (11)
C8	0.0476 (17)	0.0554 (17)	0.0281 (12)	−0.0031 (15)	−0.0002 (12)	−0.0086 (12)
C9	0.0511 (16)	0.0399 (13)	0.0241 (11)	0.0057 (14)	−0.0019 (11)	−0.0007 (11)
C10	0.067 (2)	0.073 (2)	0.0578 (19)	−0.024 (2)	−0.0022 (17)	−0.0117 (18)
C11	0.0468 (18)	0.086 (3)	0.0518 (17)	0.0070 (19)	0.0022 (15)	−0.0103 (18)
C12	0.0481 (16)	0.0427 (14)	0.0227 (11)	0.0023 (13)	−0.0032 (11)	0.0012 (11)
C13	0.0318 (13)	0.0351 (12)	0.0242 (11)	0.0028 (11)	−0.0003 (10)	0.0005 (10)
C14	0.0399 (16)	0.0500 (16)	0.0282 (12)	0.0063 (14)	−0.0058 (11)	0.0014 (12)
C15	0.0297 (13)	0.0301 (11)	0.0236 (10)	0.0003 (10)	0.0002 (9)	−0.0011 (9)
C16	0.0239 (12)	0.0368 (12)	0.0335 (12)	0.0000 (11)	−0.0007 (10)	−0.0002 (11)
C17	0.0269 (13)	0.0485 (15)	0.0278 (12)	−0.0017 (12)	0.0062 (10)	0.0069 (11)
C18	0.0309 (13)	0.0482 (15)	0.0225 (11)	0.0012 (12)	0.0000 (10)	0.0056 (11)
C19	0.0219 (12)	0.0547 (16)	0.0342 (12)	0.0003 (12)	0.0003 (10)	0.0084 (13)
C20	0.0265 (13)	0.0551 (16)	0.0295 (12)	−0.0005 (12)	0.0050 (10)	0.0114 (12)
C21	0.0184 (12)	0.073 (2)	0.0368 (14)	0.0001 (13)	0.0015 (11)	0.0218 (14)
C22	0.0356 (16)	0.067 (2)	0.0435 (15)	−0.0086 (15)	−0.0002 (13)	−0.0039 (15)
C23	0.0386 (16)	0.0540 (18)	0.070 (2)	0.0045 (15)	0.0009 (15)	0.0117 (17)
C24	0.0356 (16)	0.075 (2)	0.0418 (16)	0.0067 (16)	−0.0019 (13)	0.0170 (16)
C25	0.0433 (17)	0.079 (2)	0.0344 (15)	0.0005 (17)	0.0020 (14)	−0.0077 (15)
C26	0.0361 (15)	0.0515 (16)	0.0627 (19)	0.0066 (15)	0.0088 (14)	0.0013 (16)

F1—C1	1.315 (4)	C10—H10B	0.9800
F2—C1	1.322 (4)	C10—H10A	0.9800
F3—C1	1.332 (4)	C10—H10C	0.9800
F4—C2	1.322 (4)	C11—H11A	0.9800
F5—C2	1.321 (4)	C11—H11B	0.9800
F6—C2	1.326 (4)	C11—H11C	0.9800
O1—C4	1.381 (3)	C13—C14	1.474 (4)
O1—C3	1.416 (3)	C13—C15	1.514 (3)
O2—C4	1.190 (3)	C13—H13	1.0000
O3—C12	1.197 (3)	C15—C16	1.380 (3)
O4—C12	1.362 (3)	C15—C20	1.383 (4)
O4—C13	1.437 (3)	C16—C17	1.385 (3)
O5—C19	1.380 (3)	C16—H16	0.9500
O5—C21	1.397 (3)	C17—C18	1.377 (4)
N1—C14	1.134 (4)	C17—H17	0.9500
C1—C3	1.501 (5)	C18—C19	1.374 (3)
C2—C3	1.500 (4)	C18—H18	0.9500
C3—H3	1.0000	C19—C20	1.383 (3)
C4—C5	1.453 (4)	C20—H20	0.9500
C5—C6	1.329 (4)	C21—C22	1.359 (4)
C5—H5	0.9500	C21—C26	1.370 (4)
C6—C7	1.457 (4)	C22—C23	1.382 (4)
C6—H6	0.9500	C22—H22	0.9500
C7—C8	1.509 (4)	C23—C24	1.357 (4)
C7—C9	1.539 (3)	C23—H23	0.9500
C7—H7	1.0000	C24—C25	1.352 (4)
C8—C10	1.509 (4)	C24—H24	0.9500
C8—C9	1.510 (4)	C25—C26	1.392 (4)
C8—C11	1.512 (4)	C25—H25	0.9500
C9—C12	1.466 (4)	C26—H26	0.9500
C9—H9	1.0000
C4—O1—C3	116.3 (2)	H10A—C10—H10C	109.5
C12—O4—C13	115.84 (19)	C8—C11—H11A	109.5
C19—O5—C21	117.8 (2)	C8—C11—H11B	109.5
F1—C1—F2	107.8 (3)	H11A—C11—H11B	109.5
F1—C1—F3	107.7 (3)	C8—C11—H11C	109.5
F2—C1—F3	107.2 (3)	H11A—C11—H11C	109.5
F1—C1—C3	110.8 (3)	H11B—C11—H11C	109.5
F2—C1—C3	112.7 (3)	O3—C12—O4	122.0 (2)
F3—C1—C3	110.5 (3)	O3—C12—C9	129.0 (2)
F5—C2—F4	108.0 (3)	O4—C12—C9	109.0 (2)
F5—C2—F6	108.0 (3)	O4—C13—C14	109.3 (2)
F4—C2—F6	106.4 (3)	O4—C13—C15	107.07 (18)
F5—C2—C3	111.6 (3)	C14—C13—C15	113.9 (2)
F4—C2—C3	113.0 (3)	O4—C13—H13	108.8
F6—C2—C3	109.7 (3)	C14—C13—H13	108.8
O1—C3—C2	108.6 (2)	C15—C13—H13	108.8
O1—C3—C1	106.2 (3)	N1—C14—C13	178.9 (3)
C2—C3—C1	113.8 (3)	C16—C15—C20	120.2 (2)
O1—C3—H3	109.4	C16—C15—C13	122.0 (2)
C2—C3—H3	109.4	C20—C15—C13	117.8 (2)
C1—C3—H3	109.4	C15—C16—C17	119.4 (2)
O2—C4—O1	121.2 (2)	C15—C16—H16	120.3
O2—C4—C5	129.3 (2)	C17—C16—H16	120.3
O1—C4—C5	109.5 (2)	C18—C17—C16	121.0 (2)
C6—C5—C4	124.1 (3)	C18—C17—H17	119.5
C6—C5—H5	118.0	C16—C17—H17	119.5
C4—C5—H5	118.0	C19—C18—C17	118.9 (2)
C5—C6—C7	126.4 (2)	C19—C18—H18	120.6
C5—C6—H6	116.8	C17—C18—H18	120.6
C7—C6—H6	116.8	C18—C19—O5	123.1 (2)
C6—C7—C8	122.4 (2)	C18—C19—C20	121.2 (2)
C6—C7—C9	121.1 (2)	O5—C19—C20	115.7 (2)
C8—C7—C9	59.36 (17)	C19—C20—C15	119.3 (2)
C6—C7—H7	114.4	C19—C20—H20	120.3
C8—C7—H7	114.4	C15—C20—H20	120.3
C9—C7—H7	114.4	C22—C21—C26	121.0 (3)
C10—C8—C7	120.7 (3)	C22—C21—O5	120.2 (3)
C10—C8—C9	120.8 (3)	C26—C21—O5	118.7 (3)
C7—C8—C9	61.29 (18)	C21—C22—C23	119.5 (3)
C10—C8—C11	113.9 (3)	C21—C22—H22	120.2
C7—C8—C11	115.8 (2)	C23—C22—H22	120.2
C9—C8—C11	114.6 (3)	C24—C23—C22	120.1 (3)
C12—C9—C8	122.1 (2)	C24—C23—H23	119.9
C12—C9—C7	121.0 (2)	C22—C23—H23	119.9
C8—C9—C7	59.35 (17)	C25—C24—C23	120.3 (3)
C12—C9—H9	114.5	C25—C24—H24	119.8
C8—C9—H9	114.5	C23—C24—H24	119.8
C7—C9—H9	114.5	C24—C25—C26	120.5 (3)
C8—C10—H10B	109.5	C24—C25—H25	119.7
C8—C10—H10A	109.5	C26—C25—H25	119.7
H10B—C10—H10A	109.5	C21—C26—C25	118.5 (3)
C8—C10—H10C	109.5	C21—C26—H26	120.7
H10B—C10—H10C	109.5	C25—C26—H26	120.7
C4—O1—C3—C2	109.0 (3)	C13—O4—C12—C9	−176.9 (2)
C4—O1—C3—C1	−128.2 (3)	C8—C9—C12—O3	−46.8 (4)
F5—C2—C3—O1	−178.4 (3)	C7—C9—C12—O3	24.2 (5)
F4—C2—C3—O1	59.8 (4)	C8—C9—C12—O4	132.7 (2)
F6—C2—C3—O1	−58.8 (3)	C7—C9—C12—O4	−156.3 (2)
F5—C2—C3—C1	63.5 (4)	C12—O4—C13—C14	−79.2 (3)
F4—C2—C3—C1	−58.3 (4)	C12—O4—C13—C15	157.0 (2)
F6—C2—C3—C1	−176.8 (3)	O4—C13—C14—N1	73 (21)
F1—C1—C3—O1	62.5 (4)	C15—C13—C14—N1	−167 (92)
F2—C1—C3—O1	−58.3 (4)	O4—C13—C15—C16	124.6 (2)
F3—C1—C3—O1	−178.3 (2)	C14—C13—C15—C16	3.7 (3)
F1—C1—C3—C2	−178.1 (3)	O4—C13—C15—C20	−57.2 (3)
F2—C1—C3—C2	61.1 (4)	C14—C13—C15—C20	−178.1 (3)
F3—C1—C3—C2	−58.8 (4)	C20—C15—C16—C17	1.3 (4)
C3—O1—C4—O2	−1.1 (4)	C13—C15—C16—C17	179.5 (2)
C3—O1—C4—C5	178.0 (2)	C15—C16—C17—C18	−0.2 (4)
O2—C4—C5—C6	−15.1 (5)	C16—C17—C18—C19	−1.4 (4)
O1—C4—C5—C6	166.0 (3)	C17—C18—C19—O5	−177.1 (3)
C4—C5—C6—C7	−3.8 (5)	C17—C18—C19—C20	1.9 (4)
C5—C6—C7—C8	−157.7 (3)	C21—O5—C19—C18	−8.8 (5)
C5—C6—C7—C9	131.1 (3)	C21—O5—C19—C20	172.2 (3)
C6—C7—C8—C10	1.1 (4)	C18—C19—C20—C15	−0.8 (5)
C9—C7—C8—C10	110.8 (3)	O5—C19—C20—C15	178.3 (3)
C6—C7—C8—C9	−109.6 (3)	C16—C15—C20—C19	−0.9 (4)
C6—C7—C8—C11	145.2 (3)	C13—C15—C20—C19	−179.1 (2)
C9—C7—C8—C11	−105.2 (3)	C19—O5—C21—C22	−78.7 (4)
C10—C8—C9—C12	−1.0 (4)	C19—O5—C21—C26	105.6 (3)
C7—C8—C9—C12	109.6 (3)	C26—C21—C22—C23	0.5 (5)
C11—C8—C9—C12	−143.3 (3)	O5—C21—C22—C23	−175.0 (2)
C10—C8—C9—C7	−110.5 (3)	C21—C22—C23—C24	0.3 (5)
C11—C8—C9—C7	107.2 (3)	C22—C23—C24—C25	−0.9 (5)
C6—C7—C9—C12	0.3 (4)	C23—C24—C25—C26	0.6 (5)
C8—C7—C9—C12	−111.4 (3)	C22—C21—C26—C25	−0.8 (4)
C6—C7—C9—C8	111.7 (3)	O5—C21—C26—C25	174.8 (2)
C13—O4—C12—O3	2.7 (4)	C24—C25—C26—C21	0.2 (5)

Cg1 is the centroid of the C21–C26 phenyl ring.

D—H···A	D—H	H···A	D···A	D—H···A
C26—H26···F3i	0.95	2.45	3.200 (4)	135.
C17—H17···Cg1ii	0.95	2.51	3.421 (1)	161.

Table 1

Hydrogen-bond geometry (Å, °)

Cg1 is the centroid of the C21–C26 phenyl ring.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C26—H26⋯F3i	0.95	2.45	3.200 (4)	135
C17—H17⋯Cg1ii	0.95	2.51	3.421 (1)	161

Symmetry codes: (i) ; (ii) .