Diaqua-bis-(4-carb-oxy-2-ethyl-1H-imidazole-5-carboxyl-ato-κN,O)zinc N,N-dimethyl-formamide disolvate.

In the title compound, [Zn(C(7)H(7)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) ion, which lies on a center of inversion, is coordinated by two O atoms and two N atoms from two 4-carboxy-2-ethyl-1H-imid-azole-5-carboxyl-ato anions and two water O atoms in an octa-hedral environment, Each 4-carboxy-2-ethyl-1H-imid-azole-5-carboxyl-ato ligand adopts a bidentate chelating mode to the Zn(II) ion, forming two five-membered metalla rings. In the crystal, a two-dimensional framework parallel to (010) is formed by N-H⋯O and O-H⋯O hydrogen bonds.

Related literature

For the properties of complexes derived from imidazole-4,5-dicarboxylic acid, see: Maji et al. (2005 ▶); Yang & Zhang (2006 ▶). For our previous work based on 2-ethyl-4,5-imidazole­dicarboxyl­ate, see: Tian et al. (2010 ▶).

Experimental

Crystal data

[Zn(C7H7N2O4)2(H2O)2]·2C3H7NO

M = 613.89

Monoclinic,

a = 7.2817 (8) Å

b = 20.660 (2) Å

c = 9.3623 (9) Å

β = 111.846 (7)°

V = 1307.3 (2) Å3

Z = 2

Mo Kα radiation

μ = 1.01 mm−1

T = 296 K

0.53 × 0.41 × 0.31 mm

Data collection

Bruker APEXII area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.616, T max = 0.744

10742 measured reflections

2619 independent reflections

2083 reflections with I > 2σ(I)

R int = 0.037

Refinement

R[F 2 > 2σ(F 2)] = 0.034

wR(F 2) = 0.086

S = 1.02

2619 reflections

181 parameters

3 restraints

H-atom parameters constrained

Δρmax = 0.22 e Å−3

Δρmin = −0.36 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536811012992/nk2096sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811012992/nk2096Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Zn(C7H7N2O4)2(H2O)2]·2C3H7NO	F(000) = 640
Mr = 613.89	Dx = 1.560 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 5837 reflections
a = 7.2817 (8) Å	θ = 2.8–27.9°
b = 20.660 (2) Å	µ = 1.01 mm−1
c = 9.3623 (9) Å	T = 296 K
β = 111.846 (7)°	Block, colourless
V = 1307.3 (2) Å3	0.53 × 0.41 × 0.31 mm
Z = 2

Bruker APEXII area-detector diffractometer	2619 independent reflections
Radiation source: fine-focus sealed tube	2083 reflections with I > 2σ(I)
graphite	Rint = 0.037
φ and ω scan	θmax = 26.2°, θmin = 2.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −9→8
Tmin = 0.616, Tmax = 0.744	k = −25→25
10742 measured reflections	l = −11→11

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.034	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.086	H-atom parameters constrained
S = 1.02	w = 1/[σ2(Fo2) + (0.0387P)2 + 0.6624P] where P = (Fo2 + 2Fc2)/3
2619 reflections	(Δ/σ)max < 0.001
181 parameters	Δρmax = 0.22 e Å−3
3 restraints	Δρmin = −0.36 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Zn1	1.0000	0.0000	1.0000	0.02973 (13)
O1	0.6355 (3)	−0.00930 (9)	0.25342 (18)	0.0414 (4)
O1W	1.2808 (2)	0.03585 (9)	1.00911 (17)	0.0383 (4)
H1W	1.2982	0.0255	0.9272	0.057*
H2W	1.3729	0.0197	1.0863	0.057*
O2	0.7948 (3)	−0.09580 (9)	0.38356 (18)	0.0424 (4)
O3	0.9815 (3)	−0.12960 (8)	0.65214 (18)	0.0392 (4)
H3	0.9214	−0.1176	0.5595	0.047*
O4	1.0464 (2)	−0.08767 (8)	0.88405 (17)	0.0358 (4)
N1	0.8675 (3)	0.02603 (9)	0.77101 (19)	0.0263 (4)
N2	0.7049 (3)	0.05738 (9)	0.5331 (2)	0.0287 (4)
H2	0.6373	0.0814	0.4565	0.034*
C1	0.7687 (3)	0.07446 (11)	0.6824 (2)	0.0280 (5)
C2	0.8660 (3)	−0.02367 (11)	0.6730 (2)	0.0247 (4)
C3	0.7660 (3)	−0.00476 (11)	0.5237 (2)	0.0274 (5)
C4	0.9705 (3)	−0.08386 (11)	0.7418 (2)	0.0292 (5)
C5	0.7267 (3)	−0.03848 (12)	0.3751 (2)	0.0326 (5)
C6	0.7387 (4)	0.14021 (12)	0.7351 (3)	0.0407 (6)
H6A	0.7823	0.1403	0.8464	0.049*
H6B	0.5986	0.1504	0.6934	0.049*
C7	0.8514 (5)	0.19225 (14)	0.6854 (4)	0.0594 (8)
H7A	0.9895	0.1815	0.7230	0.089*
H7B	0.8342	0.2333	0.7269	0.089*
H7C	0.8013	0.1947	0.5751	0.089*
O5	0.4712 (3)	0.14244 (10)	0.32830 (19)	0.0504 (5)
N3	0.4143 (3)	0.18961 (10)	0.0978 (2)	0.0412 (5)
C8	0.5131 (4)	0.15203 (13)	0.2144 (3)	0.0428 (6)
H8A	0.6239	0.1309	0.2104	0.051*
C9	0.4683 (6)	0.1927 (2)	−0.0361 (4)	0.0754 (10)
H9A	0.5986	0.1751	−0.0109	0.113*
H9B	0.4665	0.2369	−0.0679	0.113*
H9C	0.3755	0.1680	−0.1182	0.113*
C10	0.2338 (5)	0.22132 (16)	0.0909 (4)	0.0654 (9)
H10A	0.2220	0.2184	0.1895	0.098*
H10B	0.1223	0.2005	0.0147	0.098*
H10C	0.2374	0.2660	0.0640	0.098*

	U11	U22	U33	U12	U13	U23
Zn1	0.0328 (2)	0.0381 (2)	0.01527 (18)	0.00315 (17)	0.00554 (15)	0.00143 (15)
O1	0.0407 (10)	0.0605 (12)	0.0179 (8)	0.0054 (8)	0.0051 (8)	0.0017 (8)
O1W	0.0322 (9)	0.0579 (12)	0.0227 (8)	−0.0008 (8)	0.0078 (7)	0.0013 (8)
O2	0.0510 (11)	0.0429 (11)	0.0271 (9)	0.0046 (9)	0.0075 (8)	−0.0077 (7)
O3	0.0489 (10)	0.0363 (9)	0.0271 (9)	0.0113 (8)	0.0079 (8)	−0.0007 (7)
O4	0.0433 (10)	0.0374 (9)	0.0211 (8)	0.0090 (8)	0.0055 (7)	0.0040 (7)
N1	0.0285 (10)	0.0322 (10)	0.0167 (9)	0.0036 (8)	0.0065 (8)	0.0015 (7)
N2	0.0295 (10)	0.0336 (11)	0.0196 (9)	0.0060 (8)	0.0053 (8)	0.0066 (8)
C1	0.0283 (12)	0.0331 (12)	0.0218 (11)	0.0025 (9)	0.0082 (10)	0.0026 (9)
C2	0.0250 (11)	0.0297 (11)	0.0183 (10)	0.0009 (9)	0.0068 (9)	0.0007 (8)
C3	0.0251 (11)	0.0359 (12)	0.0204 (10)	−0.0016 (10)	0.0075 (9)	0.0005 (9)
C4	0.0292 (12)	0.0323 (12)	0.0252 (12)	0.0008 (10)	0.0092 (10)	−0.0001 (9)
C5	0.0278 (12)	0.0450 (15)	0.0230 (12)	−0.0046 (11)	0.0072 (10)	−0.0024 (10)
C6	0.0472 (15)	0.0407 (15)	0.0313 (13)	0.0133 (12)	0.0114 (12)	−0.0014 (11)
C7	0.067 (2)	0.0383 (16)	0.064 (2)	−0.0033 (15)	0.0142 (17)	−0.0061 (14)
O5	0.0557 (12)	0.0593 (13)	0.0310 (10)	0.0156 (10)	0.0101 (9)	0.0128 (8)
N3	0.0462 (12)	0.0405 (12)	0.0304 (11)	0.0003 (10)	0.0069 (10)	0.0045 (9)
C8	0.0419 (15)	0.0422 (15)	0.0390 (15)	0.0083 (12)	0.0090 (12)	0.0028 (12)
C9	0.091 (3)	0.095 (3)	0.0440 (18)	−0.008 (2)	0.0296 (19)	0.0128 (17)
C10	0.066 (2)	0.062 (2)	0.0517 (18)	0.0231 (17)	0.0028 (16)	0.0102 (15)

Zn1—N1	2.0680 (17)	C2—C4	1.475 (3)
Zn1—N1i	2.0680 (17)	C3—C5	1.485 (3)
Zn1—O1Wi	2.1464 (16)	C6—C7	1.526 (4)
Zn1—O1W	2.1464 (16)	C6—H6A	0.9700
Zn1—O4	2.2013 (16)	C6—H6B	0.9700
Zn1—O4i	2.2013 (16)	C7—H7A	0.9600
O1—C5	1.241 (3)	C7—H7B	0.9600
O1W—H1W	0.8501	C7—H7C	0.9600
O1W—H2W	0.8500	O5—C8	1.230 (3)
O2—C5	1.275 (3)	N3—C8	1.314 (3)
O3—C4	1.286 (3)	N3—C10	1.448 (4)
O3—H3	0.8500	N3—C9	1.448 (3)
O4—C4	1.240 (3)	C8—H8A	0.9300
N1—C1	1.328 (3)	C9—H9A	0.9600
N1—C2	1.375 (3)	C9—H9B	0.9600
N2—C1	1.346 (3)	C9—H9C	0.9600
N2—C3	1.372 (3)	C10—H10A	0.9600
N2—H2	0.8600	C10—H10B	0.9600
C1—C6	1.489 (3)	C10—H10C	0.9600
C2—C3	1.371 (3)
N1—Zn1—N1i	180.0	O4—C4—C2	118.3 (2)
N1—Zn1—O1Wi	88.77 (7)	O3—C4—C2	118.78 (19)
N1i—Zn1—O1Wi	91.23 (6)	O1—C5—O2	124.8 (2)
N1—Zn1—O1W	91.23 (6)	O1—C5—C3	118.9 (2)
N1i—Zn1—O1W	88.77 (7)	O2—C5—C3	116.3 (2)
O1Wi—Zn1—O1W	180.0	C1—C6—C7	112.3 (2)
N1—Zn1—O4	78.50 (6)	C1—C6—H6A	109.1
N1i—Zn1—O4	101.50 (6)	C7—C6—H6A	109.1
O1Wi—Zn1—O4	90.87 (6)	C1—C6—H6B	109.1
O1W—Zn1—O4	89.13 (6)	C7—C6—H6B	109.1
N1—Zn1—O4i	101.50 (6)	H6A—C6—H6B	107.9
N1i—Zn1—O4i	78.50 (6)	C6—C7—H7A	109.5
O1Wi—Zn1—O4i	89.13 (6)	C6—C7—H7B	109.5
O1W—Zn1—O4i	90.87 (6)	H7A—C7—H7B	109.5
O4—Zn1—O4i	180.000 (1)	C6—C7—H7C	109.5
Zn1—O1W—H1W	109.7	H7A—C7—H7C	109.5
Zn1—O1W—H2W	109.7	H7B—C7—H7C	109.5
H1W—O1W—H2W	109.5	C8—N3—C10	120.8 (2)
C4—O3—H3	108.6	C8—N3—C9	120.2 (3)
C4—O4—Zn1	112.88 (14)	C10—N3—C9	118.4 (2)
C1—N1—C2	106.13 (17)	O5—C8—N3	125.4 (2)
C1—N1—Zn1	141.17 (15)	O5—C8—H8A	117.3
C2—N1—Zn1	112.51 (14)	N3—C8—H8A	117.3
C1—N2—C3	108.49 (18)	N3—C9—H9A	109.5
C1—N2—H2	125.8	N3—C9—H9B	109.5
C3—N2—H2	125.8	H9A—C9—H9B	109.5
N1—C1—N2	110.41 (19)	N3—C9—H9C	109.5
N1—C1—C6	126.4 (2)	H9A—C9—H9C	109.5
N2—C1—C6	123.2 (2)	H9B—C9—H9C	109.5
C3—C2—N1	109.71 (19)	N3—C10—H10A	109.5
C3—C2—C4	132.7 (2)	N3—C10—H10B	109.5
N1—C2—C4	117.60 (18)	H10A—C10—H10B	109.5
C2—C3—N2	105.25 (18)	N3—C10—H10C	109.5
C2—C3—C5	131.7 (2)	H10A—C10—H10C	109.5
N2—C3—C5	123.0 (2)	H10B—C10—H10C	109.5
O4—C4—O3	122.9 (2)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1W···O1ii	0.85	1.95	2.798 (2)	173
O1W—H2W···O1iii	0.85	2.06	2.894 (2)	168
O3—H3···O2	0.85	1.62	2.473 (2)	177
N2—H2···O5	0.86	1.85	2.689 (2)	166

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1W⋯O1i	0.85	1.95	2.798 (2)	173
O1W—H2W⋯O1ii	0.85	2.06	2.894 (2)	168
O3—H3⋯O2	0.85	1.62	2.473 (2)	177
N2—H2⋯O5	0.86	1.85	2.689 (2)	166

Symmetry codes: (i) ; (ii) .