Triphen-yl[2-(triphenyl-phosphanium-yl)eth-yl]phosphanium bis-(periodate).

In title salt, C(38)H(34)P(2) (2+)·2IO(4) (-), the P atoms of the dication and the I atoms of the periodate anions are each in a slightly distorted tetra-hedral environment. In the dication, the two -P(C(6)H(5))(3) groups adopt a gauche conformation with respect to each other. In the crystal, several C-H⋯O hydrogen bonds between the cations and anions lead to a two-dimensional arrangement along (101).

Related literature

For the synthesis and structures of related compounds, see: Barkell et al. (2008 ▶); Rizzoli et al. (2010 ▶).

Experimental

Crystal data

C38H34P2 2+·2IO4 −

M = 934.39

Monoclinic,

a = 9.2077 (18) Å

b = 18.387 (4) Å

c = 21.992 (4) Å

β = 94.37 (3)°

V = 3712.5 (13) Å3

Z = 4

Mo Kα radiation

μ = 1.83 mm−1

T = 298 K

0.5 × 0.2 × 0.2 mm

Data collection

Stoe IPDS II diffractometer

Absorption correction: numerical [shape of crystal determined optically (X-RED and X-SHAPE; Stoe & Cie, 2005 ▶)] T min = 0.649, T max = 0.692

26606 measured reflections

9970 independent reflections

7229 reflections with I > 2σ(I)

R int = 0.077

Refinement

R[F 2 > 2σ(F 2)] = 0.069

wR(F 2) = 0.190

S = 1.17

9970 reflections

451 parameters

H-atom parameters constrained

Δρmax = 1.18 e Å−3

Δρmin = −1.69 e Å−3

Data collection: X-AREA (Stoe & Cie, 2005 ▶); cell refinement: X-AREA ▶); data reduction: X-AREA; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536811008725/sj5109sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811008725/sj5109Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C38H34P22+·2IO4−	F(000) = 1848
Mr = 934.39	Dx = 1.672 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 9970 reflections
a = 9.2077 (18) Å	θ = 2.2–29.3°
b = 18.387 (4) Å	µ = 1.83 mm−1
c = 21.992 (4) Å	T = 298 K
β = 94.37 (3)°	Plate, colorless
V = 3712.5 (13) Å3	0.5 × 0.2 × 0.2 mm
Z = 4

Stoe IPDS II diffractometer	9970 independent reflections
Radiation source: fine-focus sealed tube	7229 reflections with I > 2σ(I)
graphite	Rint = 0.077
Detector resolution: 0.15 pixels mm-1	θmax = 29.3°, θmin = 2.2°
rotation method scans	h = −11→12
Absorption correction: numerical [shape of crystal determined optically (X-RED and X-SHAPE; Stoe & Cie, 2005)]	k = −24→25
Tmin = 0.649, Tmax = 0.692	l = −30→30
26606 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.069	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.190	H-atom parameters constrained
S = 1.17	w = 1/[σ2(Fo2) + (0.0878P)2 + 4.1315P] where P = (Fo2 + 2Fc2)/3
9970 reflections	(Δ/σ)max < 0.001
451 parameters	Δρmax = 1.18 e Å−3
0 restraints	Δρmin = −1.68 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C17	0.5169 (13)	0.5057 (5)	0.3529 (4)	0.080 (3)
H17	0.5649	0.4623	0.3626	0.096*
I1	0.78527 (5)	0.81354 (3)	0.04912 (2)	0.05251 (15)
I2	0.99789 (5)	0.50851 (2)	0.22398 (2)	0.04750 (13)
P2	0.79094 (14)	0.76230 (7)	0.37105 (5)	0.0281 (3)
P1	0.52902 (15)	0.66259 (7)	0.22621 (5)	0.0288 (3)
C13	0.4736 (7)	0.6095 (3)	0.2891 (2)	0.0387 (12)
C22	0.7211 (9)	0.6477 (4)	0.4439 (3)	0.0553 (18)
H22	0.6486	0.6780	0.4568	0.066*
C7	0.3896 (6)	0.7236 (3)	0.1975 (2)	0.0351 (11)
C27	0.7309 (7)	0.8181 (3)	0.4310 (2)	0.0382 (12)
C1	0.5723 (7)	0.6036 (3)	0.1652 (2)	0.0355 (11)
C28	0.8096 (9)	0.8135 (4)	0.4882 (3)	0.0519 (16)
H28	0.8910	0.7837	0.4941	0.062*
C19	0.6887 (6)	0.7135 (3)	0.2547 (2)	0.0332 (10)
H19A	0.7654	0.6800	0.2687	0.040*
H19B	0.7236	0.7425	0.2219	0.040*
C33	0.9613 (6)	0.7949 (3)	0.3475 (2)	0.0327 (10)
C20	0.6531 (6)	0.7637 (3)	0.3075 (2)	0.0336 (11)
H20A	0.5606	0.7491	0.3220	0.040*
H20B	0.6425	0.8131	0.2924	0.040*
C21	0.8146 (7)	0.6714 (3)	0.4001 (2)	0.0357 (11)
C12	0.2447 (7)	0.7006 (4)	0.1924 (3)	0.0479 (14)
H12	0.2183	0.6568	0.2096	0.058*
C6	0.4850 (8)	0.5428 (3)	0.1532 (3)	0.0479 (15)
H6	0.4116	0.5317	0.1786	0.057*
C26	0.9184 (8)	0.6259 (3)	0.3797 (3)	0.0459 (14)
H26	0.9783	0.6416	0.3502	0.055*
C32	0.6125 (7)	0.8641 (3)	0.4224 (3)	0.0434 (13)
H32	0.5630	0.8680	0.3841	0.052*
C8	0.4276 (8)	0.7889 (4)	0.1725 (3)	0.0482 (14)
H8	0.5239	0.8047	0.1759	0.058*
C30	0.6429 (12)	0.8995 (4)	0.5272 (3)	0.067 (2)
H30	0.6130	0.9265	0.5598	0.081*
C31	0.5667 (10)	0.9049 (4)	0.4710 (4)	0.063 (2)
H31	0.4860	0.9352	0.4655	0.075*
C9	0.3191 (10)	0.8310 (5)	0.1422 (4)	0.066 (2)
H9	0.3432	0.8755	0.1256	0.079*
C4	0.6197 (10)	0.5157 (4)	0.0671 (3)	0.064 (2)
H4	0.6365	0.4856	0.0344	0.077*
C29	0.7614 (11)	0.8552 (5)	0.5358 (3)	0.067 (2)
H29	0.8113	0.8527	0.5742	0.080*
C2	0.6809 (8)	0.6204 (4)	0.1274 (3)	0.0491 (15)
H2	0.7373	0.6619	0.1349	0.059*
C5	0.5067 (10)	0.4989 (4)	0.1040 (3)	0.061 (2)
H5	0.4473	0.4587	0.0953	0.073*
C11	0.1412 (8)	0.7438 (5)	0.1615 (4)	0.064 (2)
H11	0.0445	0.7289	0.1579	0.077*
C23	0.7404 (12)	0.5777 (5)	0.4673 (4)	0.075 (3)
H23	0.6809	0.5611	0.4967	0.091*
C10	0.1786 (9)	0.8080 (5)	0.1363 (4)	0.069 (2)
H10	0.1079	0.8362	0.1150	0.082*
C3	0.7065 (10)	0.5760 (5)	0.0784 (3)	0.069 (2)
H3	0.7810	0.5867	0.0536	0.083*
C25	0.9331 (10)	0.5565 (4)	0.4036 (4)	0.064 (2)
H25	1.0028	0.5252	0.3898	0.076*
C24	0.8452 (12)	0.5334 (5)	0.4477 (5)	0.079 (3)
H24	0.8577	0.4870	0.4642	0.094*
C34	1.0851 (7)	0.7827 (4)	0.3851 (3)	0.0451 (14)
H34	1.0800	0.7545	0.4200	0.054*
C38	0.9676 (8)	0.8376 (3)	0.2951 (3)	0.0428 (13)
H38	0.8840	0.8467	0.2698	0.051*
O4	0.7872 (7)	0.8035 (4)	0.1293 (3)	0.0770 (18)
C14	0.3675 (8)	0.6350 (5)	0.3252 (3)	0.0519 (16)
H14	0.3179	0.6780	0.3155	0.062*
O1	0.6096 (8)	0.8275 (6)	0.0168 (4)	0.117 (3)
O3	0.8942 (9)	0.8885 (4)	0.0339 (3)	0.092 (2)
C37	1.1017 (9)	0.8662 (4)	0.2815 (3)	0.0557 (18)
H37	1.1079	0.8947	0.2468	0.067*
C18	0.5491 (9)	0.5449 (4)	0.3023 (3)	0.0509 (16)
H18	0.6196	0.5286	0.2774	0.061*
C15	0.3371 (10)	0.5946 (7)	0.3765 (3)	0.077 (3)
H15	0.2665	0.6107	0.4014	0.092*
O7	0.9244 (10)	0.5937 (4)	0.2375 (4)	0.106 (3)
C35	1.2175 (8)	0.8120 (4)	0.3713 (4)	0.0588 (19)
H35	1.3007	0.8044	0.3973	0.071*
O2	0.8591 (11)	0.7359 (5)	0.0176 (4)	0.120 (3)
O5	1.0677 (11)	0.5069 (4)	0.1517 (4)	0.112 (3)
O6	1.1384 (11)	0.4915 (6)	0.2794 (5)	0.132 (4)
C16	0.4092 (12)	0.5326 (6)	0.3902 (4)	0.083 (3)
H16	0.3883	0.5066	0.4247	0.100*
C36	1.2246 (9)	0.8524 (4)	0.3193 (4)	0.067 (2)
H36	1.3139	0.8707	0.3093	0.080*
O8	0.8702 (12)	0.4403 (5)	0.2268 (4)	0.130 (4)

	U11	U22	U33	U12	U13	U23
C17	0.109 (8)	0.077 (6)	0.050 (4)	−0.039 (5)	−0.024 (5)	0.033 (4)
I1	0.0562 (3)	0.0506 (3)	0.0483 (2)	0.00431 (19)	−0.01228 (18)	−0.00348 (17)
I2	0.0502 (3)	0.0379 (2)	0.0542 (2)	0.00568 (17)	0.00268 (17)	−0.00459 (16)
P2	0.0279 (6)	0.0320 (6)	0.0239 (5)	−0.0021 (5)	−0.0013 (4)	0.0009 (4)
P1	0.0318 (7)	0.0309 (6)	0.0232 (5)	0.0021 (5)	−0.0005 (4)	−0.0021 (4)
C13	0.046 (3)	0.042 (3)	0.029 (2)	−0.007 (2)	0.003 (2)	0.003 (2)
C22	0.072 (5)	0.049 (4)	0.045 (3)	−0.017 (3)	0.002 (3)	0.010 (3)
C7	0.037 (3)	0.036 (3)	0.031 (2)	0.008 (2)	−0.004 (2)	−0.002 (2)
C27	0.044 (3)	0.045 (3)	0.027 (2)	−0.010 (2)	0.005 (2)	−0.005 (2)
C1	0.044 (3)	0.032 (3)	0.029 (2)	0.009 (2)	−0.004 (2)	−0.0062 (19)
C28	0.069 (5)	0.059 (4)	0.028 (3)	0.000 (3)	0.000 (3)	−0.005 (2)
C19	0.030 (3)	0.039 (3)	0.030 (2)	0.001 (2)	0.0000 (18)	−0.004 (2)
C33	0.033 (3)	0.031 (2)	0.034 (2)	−0.004 (2)	0.005 (2)	0.0018 (19)
C20	0.036 (3)	0.038 (3)	0.026 (2)	−0.001 (2)	−0.0031 (19)	−0.0090 (19)
C21	0.042 (3)	0.034 (3)	0.030 (2)	−0.005 (2)	−0.004 (2)	0.005 (2)
C12	0.037 (3)	0.054 (4)	0.052 (3)	0.003 (3)	−0.003 (3)	−0.005 (3)
C6	0.064 (4)	0.040 (3)	0.039 (3)	0.002 (3)	−0.002 (3)	−0.006 (2)
C26	0.052 (4)	0.033 (3)	0.053 (3)	0.001 (3)	−0.003 (3)	0.004 (2)
C32	0.045 (3)	0.045 (3)	0.041 (3)	0.001 (3)	0.008 (2)	−0.008 (2)
C8	0.044 (3)	0.042 (3)	0.057 (4)	0.001 (3)	−0.010 (3)	0.009 (3)
C30	0.108 (7)	0.054 (4)	0.044 (4)	−0.011 (5)	0.032 (4)	−0.014 (3)
C31	0.069 (5)	0.059 (4)	0.064 (4)	−0.002 (4)	0.029 (4)	−0.020 (4)
C9	0.064 (5)	0.056 (4)	0.074 (5)	0.015 (4)	−0.014 (4)	0.024 (4)
C4	0.083 (6)	0.059 (4)	0.049 (4)	0.026 (4)	−0.004 (4)	−0.020 (3)
C29	0.112 (7)	0.068 (5)	0.021 (3)	−0.025 (5)	0.006 (3)	−0.005 (3)
C2	0.051 (4)	0.057 (4)	0.040 (3)	−0.004 (3)	0.012 (3)	−0.011 (3)
C5	0.082 (6)	0.048 (4)	0.049 (4)	0.003 (4)	−0.014 (4)	−0.013 (3)
C11	0.038 (4)	0.074 (5)	0.078 (5)	0.015 (4)	−0.014 (3)	−0.018 (4)
C23	0.094 (7)	0.077 (6)	0.054 (4)	−0.038 (5)	−0.007 (4)	0.031 (4)
C10	0.055 (5)	0.073 (5)	0.073 (5)	0.028 (4)	−0.026 (4)	−0.004 (4)
C3	0.074 (6)	0.090 (6)	0.046 (4)	0.001 (5)	0.021 (4)	−0.025 (4)
C25	0.067 (5)	0.037 (3)	0.083 (5)	0.000 (3)	−0.016 (4)	0.008 (3)
C24	0.098 (7)	0.044 (4)	0.087 (6)	−0.024 (5)	−0.038 (5)	0.027 (4)
C34	0.031 (3)	0.052 (4)	0.051 (3)	−0.005 (3)	−0.004 (2)	0.008 (3)
C38	0.052 (4)	0.042 (3)	0.036 (3)	−0.006 (3)	0.009 (2)	0.008 (2)
O4	0.067 (4)	0.106 (5)	0.057 (3)	−0.007 (3)	−0.001 (3)	0.016 (3)
C14	0.047 (4)	0.074 (5)	0.034 (3)	−0.014 (3)	0.005 (2)	0.000 (3)
O1	0.068 (5)	0.158 (8)	0.117 (6)	0.024 (5)	−0.047 (4)	−0.020 (6)
O3	0.124 (6)	0.079 (4)	0.074 (4)	−0.027 (4)	0.012 (4)	0.006 (3)
C37	0.069 (5)	0.038 (3)	0.064 (4)	−0.005 (3)	0.029 (4)	0.010 (3)
C18	0.062 (4)	0.045 (3)	0.043 (3)	−0.005 (3)	−0.011 (3)	0.009 (3)
C15	0.068 (5)	0.128 (9)	0.037 (3)	−0.034 (6)	0.011 (3)	0.007 (4)
O7	0.136 (7)	0.074 (4)	0.107 (5)	0.062 (5)	0.003 (5)	−0.027 (4)
C35	0.033 (3)	0.056 (4)	0.087 (5)	−0.007 (3)	0.002 (3)	0.011 (4)
O2	0.138 (8)	0.085 (5)	0.135 (7)	0.039 (5)	−0.003 (6)	−0.040 (5)
O5	0.161 (9)	0.098 (6)	0.085 (5)	0.021 (5)	0.067 (6)	0.018 (4)
O6	0.121 (7)	0.136 (8)	0.128 (7)	0.052 (6)	−0.066 (6)	−0.025 (6)
C16	0.092 (7)	0.109 (8)	0.047 (4)	−0.044 (6)	−0.006 (4)	0.037 (5)
C36	0.050 (4)	0.055 (4)	0.099 (6)	−0.015 (4)	0.031 (4)	0.004 (4)
O8	0.155 (9)	0.120 (7)	0.118 (6)	−0.085 (7)	0.032 (6)	−0.020 (5)

C17—C18	1.376 (10)	C26—C25	1.383 (9)
C17—C16	1.423 (16)	C26—H26	0.9300
C17—H17	0.9300	C32—C31	1.396 (8)
I1—O1	1.736 (7)	C32—H32	0.9300
I1—O2	1.747 (7)	C8—C9	1.393 (9)
I1—O3	1.752 (7)	C8—H8	0.9300
I1—O4	1.772 (6)	C30—C29	1.363 (13)
I2—O8	1.723 (8)	C30—C31	1.378 (13)
I2—O6	1.737 (8)	C30—H30	0.9300
I2—O7	1.741 (6)	C31—H31	0.9300
I2—O5	1.760 (6)	C9—C10	1.357 (13)
P2—C27	1.791 (6)	C9—H9	0.9300
P2—C33	1.792 (5)	C4—C3	1.377 (13)
P2—C21	1.796 (6)	C4—C5	1.402 (13)
P2—C20	1.814 (5)	C4—H4	0.9300
P1—C7	1.784 (5)	C29—H29	0.9300
P1—C1	1.793 (5)	C2—C3	1.386 (9)
P1—C13	1.798 (6)	C2—H2	0.9300
P1—C19	1.814 (6)	C5—H5	0.9300
C13—C14	1.387 (9)	C11—C10	1.359 (13)
C13—C18	1.396 (9)	C11—H11	0.9300
C22—C23	1.393 (11)	C23—C24	1.358 (15)
C22—C21	1.408 (9)	C23—H23	0.9300
C22—H22	0.9300	C10—H10	0.9300
C7—C8	1.377 (9)	C3—H3	0.9300
C7—C12	1.396 (9)	C25—C24	1.376 (14)
C27—C32	1.381 (9)	C25—H25	0.9300
C27—C28	1.406 (8)	C24—H24	0.9300
C1—C2	1.384 (9)	C34—C35	1.388 (9)
C1—C6	1.391 (9)	C34—H34	0.9300
C28—C29	1.398 (10)	C38—C37	1.395 (10)
C28—H28	0.9300	C38—H38	0.9300
C19—C20	1.539 (7)	C14—C15	1.398 (10)
C19—H19A	0.9700	C14—H14	0.9300
C19—H19B	0.9700	C37—C36	1.376 (12)
C33—C34	1.375 (8)	C37—H37	0.9300
C33—C38	1.398 (7)	C18—H18	0.9300
C20—H20A	0.9700	C15—C16	1.341 (16)
C20—H20B	0.9700	C15—H15	0.9300
C21—C26	1.370 (9)	C35—C36	1.370 (11)
C12—C11	1.379 (10)	C35—H35	0.9300
C12—H12	0.9300	C16—H16	0.9300
C6—C5	1.378 (9)	C36—H36	0.9300
C6—H6	0.9300
C18—C17—C16	119.2 (9)	C27—C32—C31	120.4 (6)
C18—C17—H17	120.4	C27—C32—H32	119.8
C16—C17—H17	120.4	C31—C32—H32	119.8
O1—I1—O2	109.7 (4)	C7—C8—C9	118.7 (7)
O1—I1—O3	109.5 (5)	C7—C8—H8	120.7
O2—I1—O3	108.7 (5)	C9—C8—H8	120.7
O1—I1—O4	111.2 (4)	C29—C30—C31	121.0 (7)
O2—I1—O4	109.6 (4)	C29—C30—H30	119.5
O3—I1—O4	108.0 (3)	C31—C30—H30	119.5
O8—I2—O6	108.5 (6)	C30—C31—C32	119.0 (8)
O8—I2—O7	111.9 (5)	C30—C31—H31	120.5
O6—I2—O7	108.7 (4)	C32—C31—H31	120.5
O8—I2—O5	108.5 (4)	C10—C9—C8	121.1 (8)
O6—I2—O5	109.1 (5)	C10—C9—H9	119.5
O7—I2—O5	110.1 (4)	C8—C9—H9	119.5
C27—P2—C33	110.3 (3)	C3—C4—C5	121.3 (6)
C27—P2—C21	107.9 (3)	C3—C4—H4	119.4
C33—P2—C21	109.2 (3)	C5—C4—H4	119.4
C27—P2—C20	108.8 (3)	C30—C29—C28	121.3 (7)
C33—P2—C20	110.4 (3)	C30—C29—H29	119.3
C21—P2—C20	110.2 (3)	C28—C29—H29	119.3
C7—P1—C1	108.1 (2)	C1—C2—C3	120.6 (7)
C7—P1—C13	112.0 (3)	C1—C2—H2	119.7
C1—P1—C13	109.8 (3)	C3—C2—H2	119.7
C7—P1—C19	109.9 (3)	C6—C5—C4	119.0 (7)
C1—P1—C19	110.5 (3)	C6—C5—H5	120.5
C13—P1—C19	106.6 (3)	C4—C5—H5	120.5
C14—C13—C18	122.0 (6)	C10—C11—C12	121.0 (8)
C14—C13—P1	120.7 (5)	C10—C11—H11	119.5
C18—C13—P1	117.1 (5)	C12—C11—H11	119.5
C23—C22—C21	118.1 (8)	C24—C23—C22	120.7 (8)
C23—C22—H22	120.9	C24—C23—H23	119.7
C21—C22—H22	120.9	C22—C23—H23	119.7
C8—C7—C12	120.2 (6)	C9—C10—C11	120.0 (7)
C8—C7—P1	119.5 (5)	C9—C10—H10	120.0
C12—C7—P1	119.7 (5)	C11—C10—H10	120.0
C32—C27—C28	120.4 (6)	C4—C3—C2	118.9 (7)
C32—C27—P2	122.4 (4)	C4—C3—H3	120.5
C28—C27—P2	117.2 (5)	C2—C3—H3	120.5
C2—C1—C6	119.9 (5)	C24—C25—C26	120.4 (9)
C2—C1—P1	121.8 (5)	C24—C25—H25	119.8
C6—C1—P1	118.0 (5)	C26—C25—H25	119.8
C29—C28—C27	117.8 (7)	C23—C24—C25	120.6 (7)
C29—C28—H28	121.1	C23—C24—H24	119.7
C27—C28—H28	121.1	C25—C24—H24	119.7
C20—C19—P1	110.9 (4)	C33—C34—C35	120.5 (6)
C20—C19—H19A	109.5	C33—C34—H34	119.8
P1—C19—H19A	109.5	C35—C34—H34	119.8
C20—C19—H19B	109.5	C37—C38—C33	118.8 (6)
P1—C19—H19B	109.5	C37—C38—H38	120.6
H19A—C19—H19B	108.0	C33—C38—H38	120.6
C34—C33—C38	120.2 (6)	C13—C14—C15	118.4 (8)
C34—C33—P2	118.3 (4)	C13—C14—H14	120.8
C38—C33—P2	121.2 (5)	C15—C14—H14	120.8
C19—C20—P2	113.4 (4)	C36—C37—C38	120.1 (6)
C19—C20—H20A	108.9	C36—C37—H37	120.0
P2—C20—H20A	108.9	C38—C37—H37	120.0
C19—C20—H20B	108.9	C17—C18—C13	118.6 (8)
P2—C20—H20B	108.9	C17—C18—H18	120.7
H20A—C20—H20B	107.7	C13—C18—H18	120.7
C26—C21—C22	120.8 (6)	C16—C15—C14	120.5 (9)
C26—C21—P2	121.3 (5)	C16—C15—H15	119.8
C22—C21—P2	117.8 (5)	C14—C15—H15	119.8
C11—C12—C7	119.0 (7)	C36—C35—C34	119.4 (7)
C11—C12—H12	120.5	C36—C35—H35	120.3
C7—C12—H12	120.5	C34—C35—H35	120.3
C5—C6—C1	120.2 (7)	C15—C16—C17	121.4 (7)
C5—C6—H6	119.9	C15—C16—H16	119.3
C1—C6—H6	119.9	C17—C16—H16	119.3
C21—C26—C25	119.3 (7)	C35—C36—C37	121.0 (7)
C21—C26—H26	120.3	C35—C36—H36	119.5
C25—C26—H26	120.3	C37—C36—H36	119.5
C7—P1—C13—C14	−25.4 (6)	C20—P2—C21—C22	−86.0 (5)
C1—P1—C13—C14	−145.5 (5)	C8—C7—C12—C11	0.7 (9)
C19—P1—C13—C14	94.8 (6)	P1—C7—C12—C11	−170.0 (5)
C7—P1—C13—C18	159.2 (5)	C2—C1—C6—C5	0.4 (10)
C1—P1—C13—C18	39.1 (6)	P1—C1—C6—C5	175.0 (5)
C19—P1—C13—C18	−80.6 (5)	C22—C21—C26—C25	−1.4 (10)
C1—P1—C7—C8	−90.0 (5)	P2—C21—C26—C25	179.7 (5)
C13—P1—C7—C8	148.9 (5)	C28—C27—C32—C31	−2.0 (10)
C19—P1—C7—C8	30.7 (5)	P2—C27—C32—C31	177.8 (5)
C1—P1—C7—C12	80.8 (5)	C12—C7—C8—C9	−0.3 (10)
C13—P1—C7—C12	−40.3 (5)	P1—C7—C8—C9	170.5 (6)
C19—P1—C7—C12	−158.5 (5)	C29—C30—C31—C32	0.0 (12)
C33—P2—C27—C32	109.9 (5)	C27—C32—C31—C30	1.1 (11)
C21—P2—C27—C32	−130.9 (5)	C7—C8—C9—C10	−0.9 (12)
C20—P2—C27—C32	−11.3 (6)	C31—C30—C29—C28	−0.3 (13)
C33—P2—C27—C28	−70.3 (6)	C27—C28—C29—C30	−0.5 (12)
C21—P2—C27—C28	49.0 (6)	C6—C1—C2—C3	−1.8 (11)
C20—P2—C27—C28	168.5 (5)	P1—C1—C2—C3	−176.2 (6)
C7—P1—C1—C2	91.2 (6)	C1—C6—C5—C4	1.3 (11)
C13—P1—C1—C2	−146.4 (5)	C3—C4—C5—C6	−1.6 (12)
C19—P1—C1—C2	−29.1 (6)	C7—C12—C11—C10	0.0 (11)
C7—P1—C1—C6	−83.3 (5)	C21—C22—C23—C24	−0.9 (12)
C13—P1—C1—C6	39.2 (5)	C8—C9—C10—C11	1.6 (14)
C19—P1—C1—C6	156.4 (5)	C12—C11—C10—C9	−1.1 (13)
C32—C27—C28—C29	1.7 (10)	C5—C4—C3—C2	0.2 (13)
P2—C27—C28—C29	−178.2 (6)	C1—C2—C3—C4	1.5 (13)
C7—P1—C19—C20	61.5 (4)	C21—C26—C25—C24	−0.5 (11)
C1—P1—C19—C20	−179.4 (4)	C22—C23—C24—C25	−0.9 (13)
C13—P1—C19—C20	−60.1 (5)	C26—C25—C24—C23	1.6 (13)
C27—P2—C33—C34	74.2 (6)	C38—C33—C34—C35	−0.4 (10)
C21—P2—C33—C34	−44.2 (6)	P2—C33—C34—C35	−174.6 (6)
C20—P2—C33—C34	−165.6 (5)	C34—C33—C38—C37	1.0 (9)
C27—P2—C33—C38	−100.0 (5)	P2—C33—C38—C37	175.1 (5)
C21—P2—C33—C38	141.5 (5)	C18—C13—C14—C15	0.5 (10)
C20—P2—C33—C38	20.2 (6)	P1—C13—C14—C15	−174.7 (5)
P1—C19—C20—P2	136.1 (3)	C33—C38—C37—C36	0.0 (10)
C27—P2—C20—C19	−176.4 (4)	C16—C17—C18—C13	−0.5 (12)
C33—P2—C20—C19	62.5 (5)	C14—C13—C18—C17	−0.2 (10)
C21—P2—C20—C19	−58.2 (5)	P1—C13—C18—C17	175.1 (6)
C23—C22—C21—C26	2.1 (10)	C13—C14—C15—C16	0.0 (12)
C23—C22—C21—P2	−179.0 (6)	C33—C34—C35—C36	−1.2 (12)
C27—P2—C21—C26	−148.4 (5)	C14—C15—C16—C17	−0.7 (14)
C33—P2—C21—C26	−28.5 (6)	C18—C17—C16—C15	1.0 (14)
C20—P2—C21—C26	93.0 (5)	C34—C35—C36—C37	2.1 (13)
C27—P2—C21—C22	32.7 (6)	C38—C37—C36—C35	−1.6 (12)
C33—P2—C21—C22	152.6 (5)

D—H···A	D—H	H···A	D···A	D—H···A
C30—H30···O5i	0.93	2.43	3.351 (10)	172
C20—H20B···O8ii	0.97	2.38	3.338 (11)	170
C19—H19B···O4	0.97	2.44	3.397 (8)	171
C19—H19A···O7	0.97	2.30	3.135 (8)	144

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C30—H30⋯O5i	0.93	2.43	3.351 (10)	172
C20—H20B⋯O8ii	0.97	2.38	3.338 (11)	170
C19—H19B⋯O4	0.97	2.44	3.397 (8)	171
C19—H19A⋯O7	0.97	2.30	3.135 (8)	144

Symmetry codes: (i) ; (ii) .