4,4',5,5'-Tetra-kis(benzyl-sulfan-yl)tetra-thia-fulvalene.

The asymmetric unit of the title compound, C(34)H(28)S(8), contains two crystallographically independent half-mol-ecules. The mol-ecules lie on centers of inversion. The four benzene rings of each mol-ecule are substantially twisted from the planes of the 1,3-dithiole rings, forming dihedral angles of 43.6 (2) and 61.4 (1)° in one mol-ecule and 54.2 (1) and 65.2 (1)° in the other.

Related literature

For related structures, see: Abashev et al. (2003 ▶); Wang et al. (1997 ▶). For the synthesis of 4,5-bis­(3-picolyl­thio)-1,3-dithiole-2-thione, see: see: Jia et al. (2001 ▶). For tetra­thia­fulvalene derivatives, see: Shibaeva & Yagubskii (2004 ▶); Varma et al. (1987 ▶); Williams et al. (1984 ▶). For bond-length data, see: Allen et al. (1987 ▶).

Experimental

Crystal data

C34H28S8

M = 693.04

Triclinic,

a = 5.7450 (7) Å

b = 17.052 (2) Å

c = 18.701 (3) Å

α = 115.199 (2)°

β = 95.238 (2)°

γ = 95.922 (2)°

V = 1630.1 (4) Å3

Z = 2

Mo Kα radiation

μ = 0.57 mm−1

T = 296 K

0.3 × 0.2 × 0.1 mm

Data collection

Bruker SMART APEXII diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2000 ▶) T min = 0.871, T max = 0.944

11631 measured reflections

5688 independent reflections

3518 reflections with I > 2σ(I)

R int = 0.033

Refinement

R[F 2 > 2σ(F 2)] = 0.048

wR(F 2) = 0.157

S = 1.06

5688 reflections

379 parameters

H-atom parameters constrained

Δρmax = 0.32 e Å−3

Δρmin = −0.33 e Å−3

Data collection: APEX2 (Bruker, 2004 ▶); cell refinement: SAINT (Bruker, 2004 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: SHELXL97 and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablocks I, New_Global_Publ_Block. DOI: 10.1107/S1600536811007823/zq2088sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811007823/zq2088Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C34H28S8	V = 1630.1 (4) Å3
Mr = 693.04	Z = 2
Triclinic, P1	F(000) = 720
Hall symbol: -P 1	Dx = 1.412 Mg m−3
a = 5.7450 (7) Å	Mo Kα radiation, λ = 0.71073 Å
b = 17.052 (2) Å	θ = 1.2–25.0°
c = 18.701 (3) Å	µ = 0.57 mm−1
α = 115.199 (2)°	T = 296 K
β = 95.238 (2)°	Needle, red
γ = 95.922 (2)°	0.3 × 0.2 × 0.1 mm

Bruker SMART APEXII diffractometer	5688 independent reflections
Radiation source: fine-focus sealed tube	3518 reflections with I > 2σ(I)
graphite	Rint = 0.033
Detector resolution: 10.0 pixels mm-1	θmax = 25.0°, θmin = 1.2°
ω–scan	h = −6→6
Absorption correction: multi-scan (SADABS; Bruker, 2000)	k = −19→20
Tmin = 0.871, Tmax = 0.944	l = −22→19
11631 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.048	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.157	H-atom parameters constrained
S = 1.06	w = 1/[σ2(Fo2) + (0.0745P)2] where P = (Fo2 + 2Fc2)/3
5688 reflections	(Δ/σ)max = 0.001
379 parameters	Δρmax = 0.32 e Å−3
0 restraints	Δρmin = −0.33 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
S1	0.76116 (19)	0.45649 (8)	0.06508 (7)	0.0626 (3)
S2	0.7452 (2)	0.41173 (8)	−0.10618 (7)	0.0624 (3)
S3	0.2978 (2)	0.28449 (8)	−0.15494 (7)	0.0675 (4)
S4	0.30556 (19)	0.33663 (8)	0.03726 (7)	0.0634 (3)
S5	1.18791 (19)	0.39890 (7)	0.44406 (7)	0.0604 (3)
S6	1.37020 (19)	0.51995 (7)	0.61260 (7)	0.0634 (3)
S7	0.9859 (2)	0.44729 (8)	0.67531 (7)	0.0707 (4)
S8	0.77397 (19)	0.31193 (7)	0.48536 (8)	0.0666 (4)
C1	0.8989 (7)	0.4720 (3)	−0.0086 (2)	0.0521 (10)
C2	0.5204 (7)	0.3564 (3)	−0.0793 (3)	0.0525 (10)
C3	0.5289 (7)	0.3773 (2)	−0.0010 (3)	0.0503 (10)
C4	0.4542 (9)	0.1914 (3)	−0.2040 (3)	0.0772 (14)
H4A	0.3542	0.1486	−0.2525	0.093*
H4B	0.5966	0.2120	−0.2192	0.093*
C5	0.5204 (8)	0.1480 (3)	−0.1528 (3)	0.0588 (11)
C6	0.3653 (9)	0.0843 (3)	−0.1473 (3)	0.0846 (16)
H6	0.2151	0.0674	−0.1773	0.101*
C7	0.4232 (10)	0.0452 (3)	−0.0998 (4)	0.0864 (16)
H7	0.3148	0.0020	−0.0977	0.104*
C8	0.6399 (11)	0.0697 (4)	−0.0556 (4)	0.0893 (16)
H8	0.6809	0.0432	−0.0229	0.107*
C9	0.7975 (10)	0.1321 (4)	−0.0583 (3)	0.0893 (16)
H9	0.9465	0.1485	−0.0276	0.107*
C10	0.7390 (8)	0.1713 (3)	−0.1062 (3)	0.0745 (14)
H10	0.8490	0.2146	−0.1074	0.089*
C11	0.4694 (8)	0.3179 (3)	0.1146 (3)	0.0768 (14)
H11A	0.5860	0.2803	0.0928	0.092*
H11B	0.5503	0.3730	0.1573	0.092*
C12	0.2902 (7)	0.2742 (3)	0.1453 (3)	0.0576 (11)
C13	0.2587 (10)	0.1853 (4)	0.1199 (3)	0.0823 (15)
H13	0.3578	0.1525	0.0862	0.099*
C14	0.0888 (10)	0.1439 (3)	0.1422 (3)	0.0807 (15)
H14	0.0690	0.0833	0.1236	0.097*
C15	−0.0532 (9)	0.1920 (4)	0.1922 (3)	0.0787 (15)
H15	−0.1715	0.1637	0.2078	0.094*
C16	−0.0264 (9)	0.2797 (4)	0.2199 (3)	0.0754 (14)
H16	−0.1243	0.3120	0.2544	0.090*
C17	0.1477 (9)	0.3207 (3)	0.1963 (3)	0.0734 (13)
H17	0.1684	0.3814	0.2156	0.088*
C18	1.4097 (7)	0.4832 (2)	0.5118 (2)	0.0515 (10)
C19	1.1169 (7)	0.4427 (2)	0.5933 (2)	0.0524 (10)
C20	1.0339 (7)	0.3877 (2)	0.5165 (3)	0.0519 (10)
C21	1.1842 (9)	0.3938 (3)	0.7156 (3)	0.0731 (13)
H21A	1.3445	0.4247	0.7265	0.088*
H21B	1.1398	0.3982	0.7658	0.088*
C22	1.1795 (7)	0.2990 (3)	0.6602 (2)	0.0538 (10)
C23	1.3551 (8)	0.2731 (3)	0.6152 (3)	0.0731 (13)
H23	1.4791	0.3147	0.6185	0.088*
C24	1.3509 (10)	0.1866 (4)	0.5652 (3)	0.0910 (17)
H24	1.4714	0.1696	0.5345	0.109*
C25	1.1736 (12)	0.1262 (3)	0.5603 (3)	0.0902 (18)
H25	1.1743	0.0673	0.5269	0.108*
C26	0.9954 (9)	0.1488 (3)	0.6025 (3)	0.0768 (15)
H26	0.8715	0.1065	0.5979	0.092*
C27	0.9989 (8)	0.2348 (3)	0.6522 (3)	0.0738 (14)
H27	0.8756	0.2508	0.6817	0.089*
C28	0.8508 (9)	0.2203 (3)	0.4031 (3)	0.0909 (18)
H28A	0.8838	0.2367	0.3610	0.109*
H28B	0.9915	0.2024	0.4206	0.109*
C29	0.6469 (8)	0.1459 (3)	0.3725 (3)	0.0634 (12)
C30	0.4469 (9)	0.1446 (3)	0.3250 (3)	0.0723 (13)
H30	0.4372	0.1901	0.3104	0.087*
C31	0.2629 (8)	0.0768 (3)	0.2992 (3)	0.0754 (14)
H31	0.1279	0.0763	0.2674	0.090*
C32	0.2775 (9)	0.0106 (3)	0.3199 (3)	0.0768 (14)
H32	0.1516	−0.0353	0.3024	0.092*
C33	0.4706 (9)	0.0101 (3)	0.3652 (3)	0.0744 (14)
H33	0.4786	−0.0358	0.3792	0.089*
C34	0.6527 (9)	0.0760 (3)	0.3904 (3)	0.0784 (14)
H34	0.7873	0.0743	0.4210	0.094*

	U11	U22	U33	U12	U13	U23
S1	0.0595 (7)	0.0670 (7)	0.0542 (7)	−0.0072 (5)	0.0140 (5)	0.0227 (6)
S2	0.0632 (7)	0.0664 (7)	0.0577 (7)	−0.0015 (6)	0.0148 (5)	0.0287 (6)
S3	0.0635 (7)	0.0725 (8)	0.0667 (8)	−0.0025 (6)	−0.0086 (6)	0.0371 (7)
S4	0.0483 (6)	0.0828 (8)	0.0765 (8)	0.0003 (6)	0.0072 (5)	0.0541 (7)
S5	0.0561 (7)	0.0603 (7)	0.0583 (7)	−0.0096 (5)	0.0001 (5)	0.0257 (6)
S6	0.0623 (7)	0.0568 (7)	0.0607 (7)	−0.0053 (5)	−0.0011 (6)	0.0214 (6)
S7	0.0860 (9)	0.0560 (7)	0.0689 (8)	0.0178 (6)	0.0295 (7)	0.0214 (6)
S8	0.0556 (7)	0.0486 (6)	0.0825 (8)	−0.0014 (5)	0.0199 (6)	0.0167 (6)
C1	0.051 (2)	0.051 (2)	0.056 (3)	0.0040 (18)	0.014 (2)	0.025 (2)
C2	0.049 (2)	0.054 (2)	0.062 (3)	0.0076 (19)	0.010 (2)	0.032 (2)
C3	0.046 (2)	0.050 (2)	0.060 (3)	0.0034 (18)	0.0080 (19)	0.029 (2)
C4	0.092 (4)	0.070 (3)	0.055 (3)	0.000 (3)	0.001 (3)	0.019 (3)
C5	0.066 (3)	0.048 (2)	0.055 (3)	0.003 (2)	0.011 (2)	0.017 (2)
C6	0.068 (3)	0.069 (3)	0.105 (4)	−0.006 (3)	0.008 (3)	0.032 (3)
C7	0.092 (4)	0.063 (3)	0.118 (5)	0.002 (3)	0.027 (4)	0.053 (3)
C8	0.097 (4)	0.082 (4)	0.103 (4)	0.027 (3)	0.025 (4)	0.050 (3)
C9	0.074 (4)	0.100 (4)	0.103 (4)	0.015 (3)	0.005 (3)	0.055 (4)
C10	0.060 (3)	0.073 (3)	0.088 (4)	−0.002 (2)	0.012 (3)	0.035 (3)
C11	0.063 (3)	0.105 (4)	0.085 (4)	0.009 (3)	0.006 (3)	0.065 (3)
C12	0.057 (3)	0.072 (3)	0.055 (3)	0.014 (2)	0.009 (2)	0.038 (2)
C13	0.104 (4)	0.085 (4)	0.081 (4)	0.036 (3)	0.042 (3)	0.047 (3)
C14	0.116 (4)	0.058 (3)	0.083 (4)	0.019 (3)	0.038 (3)	0.040 (3)
C15	0.085 (4)	0.096 (4)	0.079 (4)	0.006 (3)	0.020 (3)	0.060 (3)
C16	0.086 (4)	0.094 (4)	0.063 (3)	0.032 (3)	0.032 (3)	0.043 (3)
C17	0.091 (4)	0.065 (3)	0.063 (3)	0.012 (3)	0.007 (3)	0.028 (3)
C18	0.054 (2)	0.044 (2)	0.060 (3)	0.0030 (18)	0.001 (2)	0.028 (2)
C19	0.057 (2)	0.043 (2)	0.057 (3)	0.0114 (19)	0.011 (2)	0.021 (2)
C20	0.052 (2)	0.043 (2)	0.061 (3)	0.0092 (18)	0.011 (2)	0.023 (2)
C21	0.101 (4)	0.065 (3)	0.049 (3)	0.011 (3)	0.011 (2)	0.021 (2)
C22	0.064 (3)	0.060 (3)	0.041 (2)	0.008 (2)	0.005 (2)	0.027 (2)
C23	0.066 (3)	0.073 (3)	0.076 (3)	0.003 (3)	0.017 (3)	0.030 (3)
C24	0.092 (4)	0.086 (4)	0.089 (4)	0.035 (3)	0.029 (3)	0.026 (3)
C25	0.104 (5)	0.059 (3)	0.092 (4)	0.009 (3)	−0.021 (4)	0.026 (3)
C26	0.067 (3)	0.064 (3)	0.096 (4)	−0.017 (3)	−0.010 (3)	0.043 (3)
C27	0.062 (3)	0.093 (4)	0.076 (3)	0.003 (3)	0.011 (2)	0.048 (3)
C28	0.074 (3)	0.074 (3)	0.082 (4)	−0.020 (3)	0.026 (3)	−0.001 (3)
C29	0.060 (3)	0.060 (3)	0.049 (3)	−0.004 (2)	0.015 (2)	0.006 (2)
C30	0.084 (3)	0.060 (3)	0.077 (3)	0.009 (3)	0.009 (3)	0.035 (3)
C31	0.061 (3)	0.066 (3)	0.088 (4)	0.003 (2)	−0.008 (3)	0.028 (3)
C32	0.075 (3)	0.059 (3)	0.080 (4)	−0.006 (2)	0.001 (3)	0.021 (3)
C33	0.089 (4)	0.053 (3)	0.074 (3)	0.001 (3)	−0.005 (3)	0.027 (3)
C34	0.074 (3)	0.079 (4)	0.069 (3)	0.012 (3)	−0.004 (3)	0.022 (3)

S1—C3	1.742 (4)	C13—H13	0.9300
S1—C1	1.750 (4)	C14—C15	1.356 (7)
S2—C2	1.756 (4)	C14—H14	0.9300
S2—C1	1.757 (4)	C15—C16	1.344 (7)
S3—C2	1.735 (4)	C15—H15	0.9300
S3—C4	1.837 (5)	C16—C17	1.372 (6)
S4—C3	1.745 (4)	C16—H16	0.9300
S4—C11	1.813 (4)	C17—H17	0.9300
S5—C20	1.749 (4)	C18—C18ii	1.333 (7)
S5—C18	1.752 (4)	C19—C20	1.344 (6)
S6—C19	1.757 (4)	C21—C22	1.499 (6)
S6—C18	1.761 (4)	C21—H21A	0.9700
S7—C19	1.745 (4)	C21—H21B	0.9700
S7—C21	1.827 (5)	C22—C23	1.360 (6)
S8—C20	1.744 (4)	C22—C27	1.376 (6)
S8—C28	1.794 (5)	C23—C24	1.366 (7)
C1—C1i	1.343 (7)	C23—H23	0.9300
C2—C3	1.347 (6)	C24—C25	1.339 (7)
C4—C5	1.486 (6)	C24—H24	0.9300
C4—H4A	0.9700	C25—C26	1.337 (7)
C4—H4B	0.9700	C25—H25	0.9300
C5—C6	1.377 (6)	C26—C27	1.358 (7)
C5—C10	1.378 (6)	C26—H26	0.9300
C6—C7	1.356 (7)	C27—H27	0.9300
C6—H6	0.9300	C28—C29	1.505 (6)
C7—C8	1.349 (7)	C28—H28A	0.9700
C7—H7	0.9300	C28—H28B	0.9700
C8—C9	1.345 (7)	C29—C34	1.371 (7)
C8—H8	0.9300	C29—C30	1.379 (6)
C9—C10	1.365 (7)	C30—C31	1.366 (6)
C9—H9	0.9300	C30—H30	0.9300
C10—H10	0.9300	C31—C32	1.348 (6)
C11—C12	1.503 (6)	C31—H31	0.9300
C11—H11A	0.9700	C32—C33	1.336 (6)
C11—H11B	0.9700	C32—H32	0.9300
C12—C17	1.357 (6)	C33—C34	1.340 (6)
C12—C13	1.368 (6)	C33—H33	0.9300
C13—C14	1.345 (6)	C34—H34	0.9300
C3—S1—C1	95.58 (19)	C17—C16—H16	120.5
C2—S2—C1	95.26 (19)	C12—C17—C16	121.1 (5)
C2—S3—C4	100.3 (2)	C12—C17—H17	119.4
C3—S4—C11	102.9 (2)	C16—C17—H17	119.4
C20—S5—C18	95.82 (19)	C18ii—C18—S5	122.4 (4)
C19—S6—C18	95.26 (18)	C18ii—C18—S6	123.4 (4)
C19—S7—C21	101.0 (2)	S5—C18—S6	114.2 (2)
C20—S8—C28	102.0 (2)	C20—C19—S7	125.4 (3)
C1i—C1—S1	122.5 (4)	C20—C19—S6	117.4 (3)
C1i—C1—S2	122.9 (4)	S7—C19—S6	117.1 (2)
S1—C1—S2	114.5 (2)	C19—C20—S8	123.9 (3)
C3—C2—S3	125.7 (3)	C19—C20—S5	117.2 (3)
C3—C2—S2	116.9 (3)	S8—C20—S5	118.8 (2)
S3—C2—S2	117.3 (2)	C22—C21—S7	113.2 (3)
C2—C3—S1	117.6 (3)	C22—C21—H21A	108.9
C2—C3—S4	123.0 (3)	S7—C21—H21A	108.9
S1—C3—S4	119.1 (2)	C22—C21—H21B	108.9
C5—C4—S3	113.3 (3)	S7—C21—H21B	108.9
C5—C4—H4A	108.9	H21A—C21—H21B	107.8
S3—C4—H4A	108.9	C23—C22—C27	117.2 (4)
C5—C4—H4B	108.9	C23—C22—C21	120.8 (4)
S3—C4—H4B	108.9	C27—C22—C21	122.0 (4)
H4A—C4—H4B	107.7	C22—C23—C24	120.6 (5)
C6—C5—C10	116.2 (5)	C22—C23—H23	119.7
C6—C5—C4	122.2 (4)	C24—C23—H23	119.7
C10—C5—C4	121.5 (4)	C25—C24—C23	120.1 (5)
C7—C6—C5	122.6 (5)	C25—C24—H24	120.0
C7—C6—H6	118.7	C23—C24—H24	120.0
C5—C6—H6	118.7	C26—C25—C24	121.3 (5)
C8—C7—C6	119.2 (5)	C26—C25—H25	119.3
C8—C7—H7	120.4	C24—C25—H25	119.3
C6—C7—H7	120.4	C25—C26—C27	118.7 (5)
C9—C8—C7	120.7 (6)	C25—C26—H26	120.7
C9—C8—H8	119.7	C27—C26—H26	120.7
C7—C8—H8	119.7	C26—C27—C22	122.0 (5)
C8—C9—C10	120.1 (5)	C26—C27—H27	119.0
C8—C9—H9	120.0	C22—C27—H27	119.0
C10—C9—H9	120.0	C29—C28—S8	108.6 (3)
C9—C10—C5	121.3 (5)	C29—C28—H28A	110.0
C9—C10—H10	119.3	S8—C28—H28A	110.0
C5—C10—H10	119.3	C29—C28—H28B	110.0
C12—C11—S4	106.2 (3)	S8—C28—H28B	110.0
C12—C11—H11A	110.5	H28A—C28—H28B	108.3
S4—C11—H11A	110.5	C34—C29—C30	117.1 (4)
C12—C11—H11B	110.5	C34—C29—C28	121.2 (5)
S4—C11—H11B	110.5	C30—C29—C28	121.7 (5)
H11A—C11—H11B	108.7	C31—C30—C29	120.3 (5)
C17—C12—C13	117.8 (4)	C31—C30—H30	119.9
C17—C12—C11	121.4 (4)	C29—C30—H30	119.9
C13—C12—C11	120.7 (4)	C32—C31—C30	119.9 (5)
C14—C13—C12	121.9 (5)	C32—C31—H31	120.1
C14—C13—H13	119.0	C30—C31—H31	120.1
C12—C13—H13	119.0	C33—C32—C31	120.8 (5)
C13—C14—C15	118.9 (5)	C33—C32—H32	119.6
C13—C14—H14	120.5	C31—C32—H32	119.6
C15—C14—H14	120.5	C32—C33—C34	119.9 (5)
C16—C15—C14	121.3 (5)	C32—C33—H33	120.1
C16—C15—H15	119.4	C34—C33—H33	120.1
C14—C15—H15	119.4	C33—C34—C29	122.1 (5)
C15—C16—C17	118.9 (5)	C33—C34—H34	119.0
C15—C16—H16	120.5	C29—C34—H34	119.0
C3—S1—C1—C1i	−178.8 (5)	C20—S5—C18—C18ii	177.2 (5)
C3—S1—C1—S2	3.6 (3)	C20—S5—C18—S6	−3.6 (3)
C2—S2—C1—C1i	178.7 (5)	C19—S6—C18—C18ii	−177.2 (5)
C2—S2—C1—S1	−3.7 (3)	C19—S6—C18—S5	3.6 (3)
C4—S3—C2—C3	−108.3 (4)	C21—S7—C19—C20	104.9 (4)
C4—S3—C2—S2	75.8 (3)	C21—S7—C19—S6	−78.2 (3)
C1—S2—C2—C3	2.3 (4)	C18—S6—C19—C20	−2.2 (4)
C1—S2—C2—S3	178.6 (2)	C18—S6—C19—S7	−179.4 (2)
S3—C2—C3—S1	−176.1 (2)	S7—C19—C20—S8	1.4 (6)
S2—C2—C3—S1	−0.2 (5)	S6—C19—C20—S8	−175.4 (2)
S3—C2—C3—S4	−2.2 (6)	S7—C19—C20—S5	176.9 (2)
S2—C2—C3—S4	173.7 (2)	S6—C19—C20—S5	0.1 (5)
C1—S1—C3—C2	−2.1 (4)	C28—S8—C20—C19	−143.4 (4)
C1—S1—C3—S4	−176.2 (2)	C28—S8—C20—S5	41.1 (3)
C11—S4—C3—C2	141.7 (4)	C18—S5—C20—C19	2.1 (4)
C11—S4—C3—S1	−44.4 (3)	C18—S5—C20—S8	177.9 (2)
C2—S3—C4—C5	65.9 (4)	C19—S7—C21—C22	−65.1 (4)
S3—C4—C5—C6	84.5 (5)	S7—C21—C22—C23	101.7 (5)
S3—C4—C5—C10	−93.5 (5)	S7—C21—C22—C27	−78.0 (5)
C10—C5—C6—C7	−0.9 (8)	C27—C22—C23—C24	−0.7 (7)
C4—C5—C6—C7	−179.0 (5)	C21—C22—C23—C24	179.6 (4)
C5—C6—C7—C8	0.5 (9)	C22—C23—C24—C25	−0.3 (8)
C6—C7—C8—C9	0.0 (9)	C23—C24—C25—C26	1.3 (9)
C7—C8—C9—C10	0.0 (9)	C24—C25—C26—C27	−1.2 (8)
C8—C9—C10—C5	−0.4 (8)	C25—C26—C27—C22	0.2 (7)
C6—C5—C10—C9	0.9 (7)	C23—C22—C27—C26	0.8 (7)
C4—C5—C10—C9	179.0 (5)	C21—C22—C27—C26	−179.5 (4)
C3—S4—C11—C12	−174.6 (3)	C20—S8—C28—C29	176.3 (4)
S4—C11—C12—C17	−77.4 (5)	S8—C28—C29—C34	−103.0 (5)
S4—C11—C12—C13	99.8 (5)	S8—C28—C29—C30	77.3 (5)
C17—C12—C13—C14	1.9 (7)	C34—C29—C30—C31	1.4 (7)
C11—C12—C13—C14	−175.4 (5)	C28—C29—C30—C31	−178.9 (4)
C12—C13—C14—C15	−0.9 (8)	C29—C30—C31—C32	−0.4 (8)
C13—C14—C15—C16	−0.2 (8)	C30—C31—C32—C33	−0.3 (8)
C14—C15—C16—C17	0.3 (8)	C31—C32—C33—C34	−0.1 (8)
C13—C12—C17—C16	−1.7 (7)	C32—C33—C34—C29	1.3 (8)
C11—C12—C17—C16	175.5 (4)	C30—C29—C34—C33	−1.9 (7)
C15—C16—C17—C12	0.7 (7)	C28—C29—C34—C33	178.4 (4)