| Literature DB >> 21751792 |
Eugenio Coronado1, Carlos Giménez-Saiz, Alejandro Recuenco, Ana Tarazón, Francisco M Romero, Agustín Camón, Fernando Luis.
Abstract
The terdentate anionic picolinate-based nitronyl nitroxide (picNN) free radical forms neutral and robust homoleptic complexes with rare earth-metal ions. The nonacoordinated Tb(3+) complex Tb(picNN)(3)·6H(2)O is a single-molecule magnet with an activation energy barrier Δ = 22.8 ± 0.5 K and preexponential factor τ(0) = (5.5 ± 1.1) × 10(-9) s. It shows magnetic hysteresis below 1 K.Entities:
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Year: 2011 PMID： 21751792 DOI： 10.1021/ic2010425
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165