Literature DB >> 21750819

A single tripodal ligand stabilizing three different oxidation states (II, III, and IV) of manganese.

Yukinari Sunatsuki1, Yukana Kishima, Tamami Kobayashi, Tomoka Yamaguchi, Takayoshi Suzuki, Masaaki Kojima, J Krzystek, Markku R Sundberg.   

Abstract

A series of mononuclear Mn(II), Mn(III), and Mn(IV) complexes was prepared using a single tripodal ligand (H(3)L). Addition of a cation (NH(4)(+), K(+), Na(+)) to [Mn(III)L] showed a pronounced effect on the redox potentials. Different variants of Jahn-Teller distortion, axial elongation and compression, were observed in the Mn(III) complexes.

Entities:  

Year:  2011        PMID: 21750819     DOI: 10.1039/c1cc12418h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  A new member of a class of rod-like Mn12 single molecule magnets using 2-(pyridine-2-ly)propan-2-ol.

Authors:  En-Che Yang; Shi-Yi Huang; Wolfgang Wernsdorfer; Ling-Xuan Hong; Marko Damjanovic; Lukas Niekamp; Gene-Hsiang Lee
Journal:  RSC Adv       Date:  2019-11-20       Impact factor: 3.361

  1 in total

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