Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Nanoscale effects on thermodynamics and phase equilibria in oxide systems.

Literature DB >> 21744459

Nanoscale effects on thermodynamics and phase equilibria in oxide systems.

Abstract

Because different solid materials (phases) have different surface energies, equilibria among them will be significantly affected by particle size. This Minireview summarizes experimental (calorimetric) data for the surface energies of oxides and discusses shifts in the stability of polymorphs, the thermodynamics of hydration, and oxidation-reduction reactions in nanoscale oxide systems.

Mesh：

Substances：
Oxides

Year: 2011 PMID： 21744459 DOI： 10.1002/cphc.201100129

Source DB: PubMed Journal: Chemphyschem ISSN： 1439-4235 Impact factor: 3.102

Keyword Cloud
Cited

16 in total

1. Dissolution processes: Stuffed structures.

Authors: Paul Fenter
Journal: Nat Mater Date: 2012-02-21 Impact factor: 43.841

2. Nucleation and growth of magnetite from solution.

Authors: Jens Baumgartner; Archan Dey; Paul H H Bomans; Cécile Le Coadou; Peter Fratzl; Nico A J M Sommerdijk; Damien Faivre
Journal: Nat Mater Date: 2013-02-03 Impact factor: 43.841

3. Nucleation of metastable aragonite CaCO3 in seawater.

Authors: Wenhao Sun; Saivenkataraman Jayaraman; Wei Chen; Kristin A Persson; Gerbrand Ceder
Journal: Proc Natl Acad Sci U S A Date: 2015-03-04 Impact factor: 11.205

4. Disentangling the size-dependent redox reactivity of iron oxides using thermodynamic relationships.

Authors: Gongde Chen; Aaron Thompson; Christopher A Gorski
Journal: Proc Natl Acad Sci U S A Date: 2022-09-26 Impact factor: 12.779

5. Insights into the synthesis of layered double hydroxide (LDH) nanoparticles: Part 1. Optimization and controlled synthesis of chloride-intercalated LDH.

Authors: Xiaodi Sun; Erica Neuperger; Sandwip K Dey
Journal: J Colloid Interface Sci Date: 2015-08-05 Impact factor: 8.128

Nanoscale effects on thermodynamics and phase equilibria in oxide systems.

1. Dissolution processes: Stuffed structures.

2. Nucleation and growth of magnetite from solution.

3. Nucleation of metastable aragonite CaCO3 in seawater.

4. Disentangling the size-dependent redox reactivity of iron oxides using thermodynamic relationships.

5. Insights into the synthesis of layered double hydroxide (LDH) nanoparticles: Part 1. Optimization and controlled synthesis of chloride-intercalated LDH.

6. Energetic basis of catalytic activity of layered nanophase calcium manganese oxides for water oxidation.

7. Emptying and filling a tunnel bronze.

8. Real-time atomistic observation of structural phase transformations in individual hafnia nanorods.

9. Evaluating structure selection in the hydrothermal growth of FeS₂ pyrite and marcasite.

10. Solvation and surface effects on polymorph stabilities at the nanoscale.