| Literature DB >> 21740024 |
Gerrit Wienhöfer1, Iván Sorribes, Albert Boddien, Felix Westerhaus, Kathrin Junge, Henrik Junge, Rosa Llusar, Matthias Beller.
Abstract
The first well-defined iron-based catalyst system for the reduction of nitroarenes to anilines has been developed applying formic acid as reducing agent. A broad range of substrates including other reducible functional groups were converted to the corresponding anilines in good to excellent yields at mild conditions. Notably, the process constitutes a rare example of base-free transfer hydrogenations.Entities:
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Year: 2011 PMID： 21740024 DOI： 10.1021/ja2061038
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419