Literature DB >> 21739983

A Co4O4 "cubane" water oxidation catalyst inspired by photosynthesis.

Nicholas S McCool1, David M Robinson, John E Sheats, G Charles Dismukes.   

Abstract

Herein we describe the molecular Co(4)O(4) cubane complex Co(4)O(4)(OAc)(4)(py)(4) (1), which catalyzes efficient water oxidizing activity when powered by a standard photochemical oxidation source or electrochemical oxidation. The pH dependence of catalysis, the turnover frequency, and in situ monitoring of catalytic species have revealed the intrinsic capabilities of this core type. The catalytic activity of complex 1 and analogous Mn(4)O(4) cubane complexes is attributed to the cubical core topology, which is analogous to that of nature's water oxidation catalyst, a cubical CaMn(4)O(5) cluster.

Entities:  

Year:  2011        PMID： 21739983     DOI： 10.1021/ja203877y

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

1.  Tetranuclear Manganese Models of the OEC Displaying Hydrogen Bonding Interactions: Application to Electrocatalytic Water Oxidation to Hydrogen Peroxide.

Authors:  Zhiji Han; Kyle T Horak; Heui Beom Lee; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2017-06-27       Impact factor: 15.419

2.  Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation.

Authors:  Zoel Codolà; Laura Gómez; Scott T Kleespies; Lawrence Que; Miquel Costas; Julio Lloret-Fillol
Journal:  Nat Commun       Date:  2015-01-22       Impact factor: 14.919

Review 3.  Polymer Photoelectrodes for Solar Fuel Production: Progress and Challenges.

Authors:  Madasamy Thangamuthu; Qiushi Ruan; Peter Osei Ohemeng; Bing Luo; Dengwei Jing; Robert Godin; Junwang Tang
Journal:  Chem Rev       Date:  2022-06-14       Impact factor: 72.087

4.  A novel ruthenium(II)-cobaloxime supramolecular complex for photocatalytic H2 evolution: synthesis, characterisation and mechanistic studies.

Authors:  Donald M Cropek; Anja Metz; Astrid M Müller; Harry B Gray; Toyketa Horne; Dorothy C Horton; Oleg Poluektov; David M Tiede; Ralph T Weber; William L Jarrett; Joshua D Phillips; Alvin A Holder
Journal:  Dalton Trans       Date:  2012-11-14       Impact factor: 4.390

5.  Importance of trivalency and the e(g)(1) configuration in the photocatalytic oxidation of water by Mn and Co oxides.

Authors:  Urmimala Maitra; B S Naidu; A Govindaraj; C N R Rao
Journal:  Proc Natl Acad Sci U S A       Date:  2013-07-01       Impact factor: 11.205

6.  Water oxidation catalysis by Co(II) impurities in Co(III)4O4 cubanes.

Authors:  Andrew M Ullman; Yi Liu; Michael Huynh; D Kwabena Bediako; Hongsen Wang; Bryce L Anderson; David C Powers; John J Breen; Héctor D Abruña; Daniel G Nocera
Journal:  J Am Chem Soc       Date:  2014-12-04       Impact factor: 15.419

7.  Crystal structure of bis-(μ-4-nitro-benzoato-κ2O:O')bis-[bis-(4-methyl-pyridine-κN)(4-nitro-benzoato-κ2O,O')manganese(II)].

Authors:  Sourav J Bharali; Sanchay J Bora; Birinchi K Das
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-10-11

8.  Synthetic control and empirical prediction of redox potentials for Co4O4 cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation.

Authors:  Andy I Nguyen; Jianing Wang; Daniel S Levine; Micah S Ziegler; T Don Tilley
Journal:  Chem Sci       Date:  2017-04-07       Impact factor: 9.825

9.  Photoinduced Oxygen Evolution Catalysis Promoted by Polyoxometalate Salts of Cationic Photosensitizers.

Authors:  Joaquín Soriano-López; Fangyuan Song; Greta R Patzke; J R Galan-Mascaros
Journal:  Front Chem       Date:  2018-08-14       Impact factor: 5.221

Review 10.  Computational Modeling of Cobalt-Based Water Oxidation: Current Status and Future Challenges.

Authors:  Mauro Schilling; Sandra Luber
Journal:  Front Chem       Date:  2018-04-18       Impact factor: 5.221
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