| Literature DB >> 21732645 |
Krishna Kishore Kukkadapu1, Aziz Ouach, Pedro Lozano, Michel Vaultier, Mathieu Pucheault.
Abstract
Three-carbon highly functionalized γ-borylated allylic acetates underwent a regio- and stereocontrolled Tsuji-Trost reaction in the presence of palladium complexes. An ipso substitution of the acetate with complete stereoretention of the chiral center was achieved, leading to vinylic boronates with enantiomeric excesses above 99%.Entities:
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Year: 2011 PMID： 21732645 DOI： 10.1021/ol201661s
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005