| Literature DB >> 2171765 |
Y Ito1, T Ogawa, M Numata, M Sugimoto.
Abstract
A new method for the activation of thioglycosides was developed by use of benzeneselenenyl triflate (PhSeOTf), which, upon reaction with either a primary or secondary sugar HO-group, afforded O-glycosides under extremely mild reaction conditions. The reaction was applicable to various l-thiohexosides 2-6 as well as to a 2-thioglycoside 20 derived from N-acetylneuraminic acid (NeuAc).Entities:
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Year: 1990 PMID： 2171765 DOI： 10.1016/0008-6215(90)84078-9
Source DB: PubMed Journal: Carbohydr Res ISSN： 0008-6215 Impact factor: 2.104