Literature DB >> 21715201

Multiple decoherence-free states in multi-spin systems.

H J Hogben1, P J Hore, Ilya Kuprov.   

Abstract

A numerical procedure is presented for mapping the vicinity of the null-space of the spin relaxation superoperator. The states populating this space, i.e. those with near-zero eigenvalues, of which the two-spin singlet is a well-studied example, are long-lived compared to the conventional T(1) and T(2) spin-relaxation times. The analysis of larger spin systems described herein reveals the presence of a significant number of other slowly relaxing states. A study of coupling topologies for n-spin systems (4≤n≤8) suggests the symmetry requirements for maximising the number of long-lived states.
Copyright © 2011 Elsevier Inc. All rights reserved.

Mesh:

Year:  2011        PMID: 21715201     DOI: 10.1016/j.jmr.2011.06.001

Source DB:  PubMed          Journal:  J Magn Reson        ISSN: 1090-7807            Impact factor:   2.229


  6 in total

1.  Posner qubits: spin dynamics of entangled Ca9(PO4)6 molecules and their role in neural processing.

Authors:  Thomas C Player; P J Hore
Journal:  J R Soc Interface       Date:  2018-10-31       Impact factor: 4.118

2.  Accessing long-lived nuclear singlet states between chemically equivalent spins without breaking symmetry.

Authors:  Yesu Feng; Ryan M Davis; Warren S Warren
Journal:  Nat Phys       Date:  2012-09-16       Impact factor: 20.034

3.  A nuclear singlet lifetime of more than one hour in room-temperature solution.

Authors:  Gabriele Stevanato; Joseph T Hill-Cousins; Pär Håkansson; Soumya Singha Roy; Lynda J Brown; Richard C D Brown; Giuseppe Pileio; Malcolm H Levitt
Journal:  Angew Chem Int Ed Engl       Date:  2015-01-28       Impact factor: 15.336

4.  A Nuclear Singlet Lifetime of More than One Hour in Room-Temperature Solution.

Authors:  Gabriele Stevanato; Joseph T Hill-Cousins; Pär Håkansson; Soumya Singha Roy; Lynda J Brown; Richard C D Brown; Giuseppe Pileio; Malcolm H Levitt
Journal:  Angew Chem Weinheim Bergstr Ger       Date:  2015-02-04

5.  Magnetization Lifetimes Prediction and Measurements Using Long-Lived Spin States in Endogenous Molecules.

Authors:  F Teleanu; C Tuță; A Cucoanes; S Vasilca; P R Vasos
Journal:  Molecules       Date:  2020-11-24       Impact factor: 4.411

6.  Single-Scan Selective Excitation of Individual NMR Signals in Overlapping Multiplets.

Authors:  Peter Kiraly; Nicolas Kern; Mateusz P Plesniak; Mathias Nilsson; David J Procter; Gareth A Morris; Ralph W Adams
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-09       Impact factor: 16.823

  6 in total

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