Cu2ZnSnS4 nanocrystals and graphene quantum dots for photovoltaics.

Semiconductor quantum dots exhibit great potential for applications in next generation high efficiency, low cost solar cells because of their unique optoelectronic properties. Cu(2)ZnSnS(4) (CZTS) nanocrystals and graphene quantum dots (GQDs) have recently received much attention as building blocks for use in solar energy conversion due to their outstanding properties and advantageous characteristics, including high optical absorptivity, tunable bandgap, and earth abundant chemical composition. In this Feature Article, recent advances in the synthesis and utilization of CZTS nanocrystals and colloidal GQDs for photovoltaics are highlighted, followed by an outlook on the future research efforts in these areas. This journal is © The Royal Society of Chemistry 2011