| Literature DB >> 21709859 |
Jana Juan-Alcañiz1, Maarten Goesten, Alberto Martinez-Joaristi, Eli Stavitski, Andrei V Petukhov, Jorge Gascon, Freek Kapteijn.
Abstract
The templating effect of the Keggin polyanion derived from phosphotungstic acid (PTA) during the synthesis of NH(2)-MIL-101(Al) has been investigated by means of in situ SAXS/WAXS. Kinetic analysis and structural observations demonstrate that PTA acts as a nucleation site and that it stabilizes the precursor phase NH(2)-MOF-235(Al). Surprisingly kinetics of formation are little changed. This journal is © The Royal Society of Chemistry 2011Entities:
Year: 2011 PMID： 21709859 DOI： 10.1039/c1cc12213d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222