| Literature DB >> 21681322 |
Matthew P McLaughlin1, Theresa M McCormick, Richard Eisenberg, Patrick L Holland.
Abstract
Light-driven H(2) production is catalyzed by [Ni(P(2)(Ph)N(2)(Ph))(2)](BF(4))(2) when irradiated with visible light in water/acetonitrile mixed solvent in the presence of a photosensitizer (PS) and ascorbate. The catalyst gives over 2700 turnovers over 150 h, and does not degrade despite photodecomposition of the PS.Entities:
Year: 2011 PMID: 21681322 DOI: 10.1039/c1cc12347e
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222