Literature DB >> 21681295

Direct, copper-catalyzed oxidation of aromatic C-H bonds with hydrogen peroxide under acid-free conditions.

Ana Conde1, M Mar Díaz-Requejo, Pedro J Pérez.   

Abstract

The direct oxidation of benzene into phenol using hydrogen peroxide has been achieved in the absence of any acid with Tp(x)Cu(NCMe) complexes as the catalysts. In the case of anthracenes as the substrates, valuable anthraquinones have been quantitatively obtained in the same manner.

Entities:  

Year:  2011        PMID： 21681295     DOI： 10.1039/c1cc12804c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Authors:  Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal:  Chem Rev       Date:  2019-01-30       Impact factor: 60.622

2.  Direct Benzene Hydroxylation with Dioxygen Induced by Copper Complexes: Uncovering the Active Species by DFT Calculations.

Authors:  Elena Borrego; Laura Tiessler-Sala; Jesus J Lázaro; Ana Caballero; Pedro J Pérez; Agustí Lledós
Journal:  Organometallics       Date:  2022-07-14       Impact factor: 3.837

3.  A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies.

Authors:  Laia Vilella; Ana Conde; David Balcells; M Mar Díaz-Requejo; Agustí Lledós; Pedro J Pérez
Journal:  Chem Sci       Date:  2017-10-05       Impact factor: 9.825
  3 in total

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