| Literature DB >> 21678955 |
Vincent N Cavaliere1, Marco G Crestani, Balazs Pinter, Maren Pink, Chun-Hsing Chen, Mu-Hyun Baik, Daniel J Mindiola.
Abstract
The transient titanium alkylidyne, (PNP)Ti≡C(t)Bu (PNP = N[2-P(i)Pr(2)-4-methylphenyl](2)(-)), activates a C-H bond of ethane at room temperature, and a β-hydrogen of the resulting ethyl ligand is subsequently transferred to the adjacent alkylidene ligand to form an ethylene adduct of titanium. Treatment of the ethylene complex with two-electron oxidants such as organic azides results in extrusion of ethene concomitant with formation of a mononuclear titanium imido complex.Entities:
Year: 2011 PMID： 21678955 DOI： 10.1021/ja202316m
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419