| Literature DB >> 21666932 |
Jing Wang1, Samantha L H Higgins, Brenda S J Winkel, Karen J Brewer.
Abstract
Many Ru and Os systems display photoactive (3)MLCT states. Systems activated by therapeutic window light in the absence of O(2) remain elusive. [(bpy)(2)Os(dpp)RhCl(2)(phen)](3+) photobinds and photocleaves DNA under red light in an oxygen independent manner, due to molecular design involving one Os chromophore coupled to a photoactive cis-Rh(III)Cl(2) moiety.Entities:
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Year: 2011 PMID： 21666932 DOI： 10.1039/c1cc11562f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222