Literature DB >> 21656696

Ru(II) -mediated hydrogen transfer from aqueous glycerol to CO2: from waste to value-added products.

Angela Dibenedetto1, Paolo Stufano, Francesco Nocito, Michele Aresta.   

Abstract

Aqueous glycerol was used as the hydrogen source for the reduction of CO(2) to the hydrogen carrier formic acid in the presence of the catalyst [RuCl(2)(PPh(3))(3)]. All intermediates were identified and characterized. Glycerol was converted into glycolic acid, HO-CH(2)-COOH, that was identified by using (1)H and (13)C NMR spectroscopy.
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2011        PMID： 21656696     DOI： 10.1002/cssc.201000434

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  2 in total

1.  An integrated photocatalytic/enzymatic system for the reduction of CO2 to methanol in bioglycerol-water.

Authors:  Michele Aresta; Angela Dibenedetto; Tomasz Baran; Antonella Angelini; Przemysław Labuz; Wojciech Macyk
Journal:  Beilstein J Org Chem       Date:  2014-11-03       Impact factor: 2.883

2.  Rhodium-coordinated poly(arylene-ethynylene)-alt-poly(arylene-vinylene) copolymer acting as photocatalyst for visible-light-powered NAD⁺/NADH reduction.

Authors:  Kerstin T Oppelt; Jacek Gasiorowski; Daniel Ayuk Mbi Egbe; Jan Philipp Kollender; Markus Himmelsbach; Achim Walter Hassel; Niyazi Serdar Sariciftci; Günther Knör
Journal:  J Am Chem Soc       Date:  2014-09-02       Impact factor: 15.419
  2 in total

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