Literature DB >> 21655583

2,2'-Bipyridinyl carboranes as B,N,N-ligands in cyclometallated complexes of platinum(II).

Anton M Prokhorov1, Pavel A Slepukhin, Vladimir L Rusinov, Valery N Kalinin, Dmitry N Kozhevnikov.   

Abstract

Novel B,N,N-cyclometallated Pt(II) complexes of 2,2'-bipyridin-6-yl carboranes exhibit absorption and emission similar to relative Pt(II) complexes of aromatic C,N,N-ligands: the same transitions but lower intensities. DFT calculations suggest the former emits from the (3)MLCT state while for the latter the mixed (3)ICT-MLCT transitions should be considered.

Entities:  

Year:  2011        PMID： 21655583     DOI： 10.1039/c1cc12230d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Luminescent Metal Complexes Featuring Photophysically Innocent Boron Cluster Ligands.

Authors:  Kent O Kirlikovali; Jonathan C Axtell; Alejandra Gonzalez; Alice C Phung; Saeed I Khan; Alexander M Spokoyny
Journal:  Chem Sci       Date:  2016-04-27       Impact factor: 9.825

2.  Transition metal-free oxidative and deoxygenative C-H/C-Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes.

Authors:  Lidia A Smyshliaeva; Mikhail V Varaksin; Pavel A Slepukhin; Oleg N Chupakhin; Valery N Charushin
Journal:  Beilstein J Org Chem       Date:  2018-10-12       Impact factor: 2.883

3.  {9-Hexyl-2-[2-phenyl-6-(pyridin-2-yl)pyridin-4-yl]-9H-carbazole}di-iodido-zinc.

Authors:  Hui Wang; Xue-Song Zhao; Jun-Shan Luo; Yu-Peng Tian
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-09-21
  3 in total

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