Literature DB >> 21644565

Efficient tuning of LUMO levels of 2,5,8,11-substituted perylenediimides via copper catalyzed reactions.

Glauco Battagliarin1, Yanfei Zhao, Chen Li, Klaus Müllen.   

Abstract

Via one-step copper catalyzed procedures it was possible to synthesize 2,5,8,11-tetrabromo, tetrachloro, and tetracyano derivatives of perylenediimides. Characterization of optical and electrochemical properties of these materials proves substantial enhancement of the electron affinity, with a LUMO level as low as -4.4 eV in the case of the tetracyano perylenediimide.

Entities:  

Year:  2011        PMID： 21644565     DOI： 10.1021/ol201144w

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  An ambient stable core-substituted perylene bisimide dianion: isolation and single crystal structure analysis.

Authors:  Sabine Seifert; David Schmidt; Frank Würthner
Journal:  Chem Sci       Date:  2015-01-16       Impact factor: 9.825

2.  Synthesis and Self-Assembly of Bay-Substituted Perylene Diimide Gemini-Type Surfactants as Off-On Fluorescent Probes for Lipid Bilayers.

Authors:  Jurgen Schill; Sam van Dun; Maarten J Pouderoijen; Henk M Janssen; Lech-Gustav Milroy; Albertus P H J Schenning; Luc Brunsveld
Journal:  Chemistry       Date:  2018-05-03       Impact factor: 5.236

3.  Synthesis, Photophysical and Electronic Properties of Mono-, Di-, and Tri-Amino-Substituted Ortho-Perylenes, and Comparison to the Tetra-Substituted Derivative.

Authors:  Julia Merz; Lena Dietrich; Jörn Nitsch; Ivo Krummenacher; Holger Braunschweig; Michael Moos; David Mims; Christoph Lambert; Todd B Marder
Journal:  Chemistry       Date:  2020-08-18       Impact factor: 5.020
  3 in total

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