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Literature DB >> 21643619

Palladium-catalysed hydroxylation and alkoxylation.

Abstract

The formation of oxygen-carbon bonds is one of the fundamental transformations in organic synthesis. In this regard the application of palladium-based catalysts has been extensively studied during recent years. Nowadays it is an established methodology and the success has been proven in manifold synthetic procedures. This tutorial review summarizes the advances on palladium-catalysed C-O bond formation, means hydroxylation and alkoxylation reactions. This journal is © The Royal Society of Chemistry 2011

Entities: Chemical

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Year: 2011 PMID： 21643619 DOI： 10.1039/c1cs15085e

Source DB: PubMed Journal: Chem Soc Rev ISSN： 0306-0012 Impact factor: 54.564

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Cited

26 in total

1. Efficient palladium-catalyzed cross-coupling of highly acidic substrates, nitroacetates.

Authors: Alison E Metz; Simon Berritt; Spencer D Dreher; Marisa C Kozlowski
Journal: Org Lett Date: 2012-01-20 Impact factor: 6.005

2. Improved Process for the Palladium-Catalyzed C-O Cross-Coupling of Secondary Alcohols.

Authors: Hong Zhang; Paula Ruiz-Castillo; Alexander W Schuppe; Stephen L Buchwald
Journal: Org Lett Date: 2020-06-24 Impact factor: 6.005

3. General and practical carboxyl-group-directed remote C-H oxygenation reactions of arenes.

Authors: Yang Wang; Anton V Gulevich; Vladimir Gevorgyan
Journal: Chemistry Date: 2013-10-21 Impact factor: 5.236

4. Double-fold C-H oxygenation of arenes using PyrDipSi: a general and efficient traceless/modifiable silicon-tethered directing group.

Authors: Anton V Gulevich; Ferdinand S Melkonyan; Dhruba Sarkar; Vladimir Gevorgyan
Journal: J Am Chem Soc Date: 2012-03-19 Impact factor: 15.419

5. General method for the synthesis of salicylic acids from phenols through palladium-catalyzed silanol-directed C-H carboxylation.

Authors: Yang Wang; Vladimir Gevorgyan
Journal: Angew Chem Int Ed Engl Date: 2015-01-19 Impact factor: 15.336

Palladium-catalysed hydroxylation and alkoxylation.

1. Efficient palladium-catalyzed cross-coupling of highly acidic substrates, nitroacetates.

2. Improved Process for the Palladium-Catalyzed C-O Cross-Coupling of Secondary Alcohols.

3. General and practical carboxyl-group-directed remote C-H oxygenation reactions of arenes.

4. Double-fold C-H oxygenation of arenes using PyrDipSi: a general and efficient traceless/modifiable silicon-tethered directing group.

5. General method for the synthesis of salicylic acids from phenols through palladium-catalyzed silanol-directed C-H carboxylation.

6. Synthesis of catechols from phenols via Pd-catalyzed silanol-directed C-H oxygenation.

7. Rapid heteroatom transfer to arylmetals utilizing multifunctional reagent scaffolds.

8. Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenation.

9. Purinyl N1-directed aromatic C-H oxidation in 6-arylpurines and 6-arylpurine nucleosides.

10. Oxalohydrazide Ligands for Copper-Catalyzed C-O Coupling Reactions with High Turnover Numbers.