| Literature DB >> 21639430 |
Denis J Evans1, Stephen R Williams, Debra J Searles.
Abstract
In 1854 Clausius proved the famous theorem that bears his name by assuming the second "law" of thermodynamics. In the present paper we give a proof that requires no such assumption. Our proof rests on the laws of mechanics, a T-mixing property, an ergodic consistency condition, and on the axiom of causality. Our result relies on some recently derived theorems, such as the Evans-Searles and the Crooks fluctuation theorems and the recently discovered relaxation and dissipation theorems.Entities:
Year: 2011 PMID: 21639430 DOI: 10.1063/1.3592531
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488